trimethylpropylammonium hydroxide | 37755-10-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trimethylpropylammonium hydroxide
• 英文别名: N,N,N-trimethyl-N-propylammonium hydroxide；Trimethyl-propyl-ammonium; Hydroxid；1-Propanaminium, N,N,N-trimethyl-, hydroxide；trimethyl(propyl)azanium;hydroxide
• CAS: 37755-10-5
• 化学式: C₆H₁₆N*HO
• 分子量: 119.207
• InChiKey: OLNCQUXQEJCISO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.93
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trimethylpropylammonium hydroxide 生成 N,N-二甲基丙胺
  参考文献：
  名称：

  Hanhart; Ingold, Journal of the Chemical Society, 1927, p. 1014

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N,N-trimethylpropanaminium iodide 在 silver(l) oxide 作用下， 生成 trimethylpropylammonium hydroxide
  参考文献：
  名称：

  Langeli, Gazzetta Chimica Italiana, 1886, vol. 16, p. 385

  摘要：

  DOI：

文献信息

• ONIUM SALT, LIQUID COMPOSITION CONTAINING SAID ONIUM SALT AND CELLULOSE, AND CELLULOSE RECOVERY METHOD
  申请人：KOEI CHEMICAL COMPANY, LIMITED

  公开号：US20160009669A1

  公开（公告）日：2016-01-14

  The invention relates to an onium salt, a liquid composition containing the onium salt and cellulose, and a method for recovering cellulose. The invention makes it possible to provide an onium salt having an extremely high ability to dissolve cellulose at temperatures of 100° C. or lower. It also makes it possible to provide a liquid composition containing this onium salt and cellulose, as a composition suitable for the recovery of cellulose, and a method for recovering cellulose efficiently by using such a liquid composition containing the onium salt and cellulose.

  该发明涉及一种含有onium盐和纤维素的液体组合物以及一种恢复纤维素的方法。该发明使得能够在100°C或更低温度下提供具有极高溶解纤维素能力的onium盐成为可能。它还使得能够提供一种含有该onium盐和纤维素的液体组合物，作为适用于纤维素恢复的组合物，并通过使用含有onium盐和纤维素的这种液体组合物高效地恢复纤维素的方法成为可能。
• Syntheses, structure solutions, and catalytic performance of two novel layered silicates
  作者：Jie Liang、Jie Su、Yanping Chen、Zhaofei Li、Kuo Li、Hao Zhang、Xiaodong Zou、Fuhui Liao、Yingxia Wang、Jianhua Lin

  DOI：10.1039/c5dt00487j

  日期：——

  Two novel layered silicates, PKU-13 and PKU-13a, were hydrothermally synthesized by using trimethylpropylammonium hydroxide as the structure directing agent (SDA). Their structures were solved by using powder X-ray diffraction data in combination with electron diffraction technique and NMR spectroscopy. These two silicates are built from the same r52 layer in different stacking modes: the adjacent

  以三甲基丙基氢氧化铵为结构导向剂（SDA），水热合成了两种新型的层状硅酸盐PKU-13和PKU-13a。通过使用粉末X射线衍射数据结合电子衍射技术和NMR光谱来解析其结构。这两种硅酸盐是由相同的r52层以不同的堆叠方式构建而成的：PKU-13a中相邻的r52层的0.5 b + 0.68 c与PKU-13相比有很大的变化。差异是由于SDA阳离子位于两层之间。SDA阳离子在PKU-13的结构中以单层形式存在，并通过库仑作用与强氢键结合而连接相邻的层。在PKU-13a中，存在于双层中的SDA阳离子扩大了层之间的距离并破坏了层间氢键。用乙酸溶液处理后，PKU-13a可以转化为PKU-13。PKU-13中层内氢键的共存会干扰其缩合为有序的晶体微孔骨架。作为Knoevenagel缩合反应中的基础催化剂，PKU-13和PKU-13a均显示出良好的催化活性。
• PRODUCTION PROCESS FOR FLUOROSULFONYLIMIDE AMMONIUM SALT
  申请人：Tsubokura Shiro

  公开号：US20130331609A1

  公开（公告）日：2013-12-12

  A compound [II] such as ammonium N,N-di(fluorosulfonyl)imide is obtained by reacting a compound [I] such as N,N-di(chlorosulfonyl)imide and NH 4 F (HF) p . A compound [IV] such as an N,N-di(fluorosulfonyl)imide alkali metal salt is obtained by reacting the obtained compound [II] and an alkali metal compound or the like.

  通过将化合物[I]，如N,N-二(氯磺酰)亚胺和NH4F (HF)p反应，可以得到类似氨基N,N-二(氟磺酰)亚胺的化合物[II]。通过将得到的化合物[II]与碱金属化合物等反应，可以得到类似N,N-二(氟磺酰)亚胺碱金属盐的化合物[IV]。
• Dual functional catalyst for selective opening of cyclic paraffins and process for using the catalyst
  申请人：Galperin B. Leonid

  公开号：US20050101819A1

  公开（公告）日：2005-05-12

  A catalyst for selectively opening cyclic paraffins has been developed. The catalyst comprises a Group VIII metal, such as platinum, a modifier component, such as niobium or ytterbium, a molecular sieve, such as UZM-16 and a refractory inorganic oxide such as alumina. The Group VIII metal and modifier component are preferably deposited on the refractory inorganic oxide. A process for using the catalyst is also disclosed.

  已经开发出一种用于选择性开启环烷烃的催化剂。该催化剂包括第VIII族金属，如铂，修饰剂组分，如铌或镱，分子筛，如UZM-16，以及耐火无机氧化物，如氧化铝。第VIII族金属和修饰剂组分最好沉积在耐火无机氧化物上。还公开了使用该催化剂的方法。
• Crystalline aluminosilicate zeolitic composition: UZM-15
  申请人：——

  公开号：US20040186337A1

  公开（公告）日：2004-09-23

  An aluminosilicate zeolite and substituted versions designated UZM-15 have been synthesized. These zeolites are prepared using an organo-ammonium cation as a template in which at least one organic group has at least 2 carbon atoms. An example of such a cation is diethyldimethyl-ammonium cation. The template can optionally comprise other organoammonium cations, alkali metals and alkaline earth metals. These UZM-15 materials can be dealuminated by various processes to provide UZM-15HS compositions. Both the UZM-15 and UZM-15HS compositions are useful as catalysts or catalyst supports in various process such as the conversion of cyclic hydrocarbons to non-cyclic hydrocarbons and olefin oligomerization.

  已合成一种含铝硅酸盐沸石及其取代版本，命名为UZM-15。这些沸石是使用有机铵阳离子作为模板制备的，其中至少有一个有机基含有至少2个碳原子。这种阳离子的一个例子是二乙基二甲基铵阳离子。模板可以选择性地包括其他有机铵阳离子、碱金属和碱土金属。这些UZM-15材料可以通过各种方法脱铝，得到UZM-15HS组成物。UZM-15和UZM-15HS组成物在各种过程中作为催化剂或催化剂载体是有用的，例如将环烃转化为非环烃和烯烃寡聚化。