N-tetradecylaniline | 872265-64-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-tetradecylaniline
• 英文别名: N-tridecyl-aniline；N-Tridecyl-anilin；N-tridecylaniline
• CAS: 872265-64-0
• 化学式: C₁₉H₃₃N
• 分子量: 275.478
• InChiKey: QANXKUOOYFKWAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-tetradecylaniline 在 硫酸 、 sodium nitrite 作用下， 生成 N-nitroso-N-tridecyl-aniline
  参考文献：
  名称：

  Le Sueur, Journal of the Chemical Society, 1910, vol. 97, p. 2439

  摘要：

  DOI：
• 作为产物：
  描述：

  2-anilino-tetradecanoic acid 生成 N-tetradecylaniline
  参考文献：
  名称：

  Le Sueur, Journal of the Chemical Society, 1910, vol. 97, p. 2439

  摘要：

  DOI：

文献信息

• A BEt₃-Base Catalyst for Amide Reduction with Silane
  作者：Wubing Yao、Huaquan Fang、Qiaoxing He、Dongjie Peng、Guixia Liu、Zheng Huang

  DOI：10.1021/acs.joc.9b00277

  日期：2019.5.17

  herein is the development of a simple but practical catalytic system for the selective reduction of amides with hydrosilane or hydrosiloxane. Low-cost and readily available triethylborane (1.0 M in THF), in combination with a catalytic amount of an alkali metal base, was found to catalyze the reduction of all three amide classes (tertiary, secondary, and primary amides) to form amines under mild conditions

  本文报道了一种简单但实用的催化体系的开发，该体系用于用氢硅烷或氢硅氧烷选择性还原酰胺。发现低成本且易于获得的三乙基硼烷（在THF中为1.0 M）与催化量的碱金属碱结合，可催化所有三种酰胺类别（叔，仲和伯酰胺）的还原反应，从而在室温下形成胺。温和的条件。另外，还可以通过使用BEt 3和碱的适当组合来实现将仲酰胺选择性转化为醛亚胺和将伯酰胺选择性转化为腈。这些赌注3的范围碱催化的酰胺氢化硅烷化反应已被深入研究。机理研究的初步结果表明，经过改进的Piers硅烷Si–H···B活化方式，其中BEt 3提取氢化物的过程是通过烷氧基或氢氧根阴离子与Si中心的配位来促进的。
• Novel perfluoropolyether derivatives, and lubricants and magnetic recording medium using the same
  申请人：SONY CORPORATION

  公开号：EP0519406A2

  公开（公告）日：1992-12-23

  Novel perfluoropolyether derivatives are described which are obtained from perfluoropolyethers having a carboxyl group at one or both ends and monoamines or diamines. The derivative is useful as a lubricant owing to its significantly improved lubricity. The lubricity is shown under severe high or low temperature and humidity conditions over a long term. The derivative is especially useful as a lubricant for magnetic recording mediums of the coating and metal thin film types.

  本文描述了新型全氟聚醚衍生物，该衍生物由一端或两端带有羧基的全氟聚醚和单胺或二胺制成。这种衍生物的润滑性能显著提高，可用作润滑剂。这种润滑性可在严酷的高温或低温和潮湿条件下长期保持。该衍生物特别适用于涂层型和金属薄膜型磁记录介质的润滑剂。
• THERMOPLASTIC RESIN COMPOSITION AND PROCESS FOR MOLDING THE SAME
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0657497A1

  公开（公告）日：1995-06-14

  A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 0.1-100 parts by weight of an imide compound prepared by, for example, condensation of 1,2,3,4-butanetetracarboxylic acid or a mono- or dianhydride thereof with a primary amine; and a process for molding the composition.

  一种热塑性树脂组合物，包括 100 重量份的热塑性树脂和 0.1-100 重量份的亚胺化合物，亚胺化合物是由 1，2，3，4-丁烷四羧酸或其单酸酐或二酸酐与伯胺缩合而成；以及一种成型该组合物的工艺。
• LUBRICATING OIL ADDITIVE AND LUBRICATING OIL COMPOSITION CONTAINING SAME
  申请人：Adeka Corporation

  公开号：EP1717298A1

  公开（公告）日：2006-11-02

  The present invention provides a lubricating oil additive with excellent cleaning performance which does not include metal components such as calcium or magnesium, and a lubricating oil composition containing the same. The lubricating oil additive according to the present invention is characterized by containing a quaternary ammonium salt having a base number of at least 10 mgKOH/g. Examples of such a quaternary ammonium salt include quaternary ammonium salts obtained by subjecting counter anions in cationic surfactants such as tetraalkylammonium chloride and tetraalkylammonium sulfate to salt-exchange.

  本发明提供了一种不含诸如钙或镁等金属成分的具有优异清洁性能的润滑油添加剂，以及含有该添加剂的润滑油组合物。根据本发明的润滑油添加剂的特点是含有碱基数至少为 10 mgKOH/g 的季铵盐。这种季铵盐的例子包括通过对阳离子表面活性剂（如氯化四烷基铵和硫酸四烷基铵）中的反阴离子进行盐交换而得到的季铵盐。
• (POLY)ALKYLENE GLYCOL-CONTAINING COMPOUND
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP3892666A1

  公开（公告）日：2021-10-13

  The present invention provides a (poly)alkylene glycol-containing compound having higher detergency for composite stains of hydrophilic stains and hydrophobic stains than conventional (poly)alkylene glycol-containing compounds. The present invention relates to a (poly)alkylene glycol-containing compound including: a hydrophobic structural moiety (A); a (poly)alkylene glycol moiety (B); and one lactam ring-containing structural unit (C), in its structure, the hydrophobic structural moiety (A) being present in a proportion of 2.5 to 60% by mass in 100% by mass of the (poly)alkylene glycol-containing compound.

  本发明提供了一种含(聚)亚烷基二醇的化合物，与传统的含(聚)亚烷基二醇的化合物相比，该化合物对亲水性污渍和疏水性污渍的复合污渍具有更高的去污力。本发明涉及一种含（聚）亚烷基二醇的化合物，在其结构中包括：一个疏水结构分子（A）；一个（聚）亚烷基二醇分子（B）；和一个含内酰胺环的结构单元（C），其中疏水结构分子（A）在含（聚）亚烷基二醇的化合物中的存在比例为 2.5%至 60%（以质量计）。