N,N,N-triethyl-hydrazinium; chloride | 1185-54-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-triethyl-hydrazinium; chloride
• 英文别名: N,N,N-Triaethyl-hydrazinium; Chlorid；1,1,1-triethylhydrazinium chloride；1,1,1-Triethylhydrazin-1-ium chloride；amino(triethyl)azanium;chloride
• CAS: 1185-54-2
• 化学式: C₆H₁₇N₂*Cl
• 分子量: 152.667
• InChiKey: FPUKQVMBQBURED-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.26
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2928000090

反应信息

• 作为产物：
  描述：

  三乙胺 在 氯胺 作用下， 生成 N,N,N-triethyl-hydrazinium; chloride
  参考文献：
  名称：

  The Reaction of Chloramine with Tertiary Amines.¹ 1,1,1-Trisubstituted Hydrazinium Salts²

  摘要：

  DOI：

  10.1021/ja01587a033

文献信息

• Vicarious nucleophilic substitution to prepare
  申请人：The Regents of the University of California

  公开号：US05569783A1

  公开（公告）日：1996-10-29

  The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,-trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0.degree. and 50.degree. C. for between about 0.1 and 24 hr, a trinitroaromatic compound of structure V: ##STR1## wherein X, Y, and Z are each independently selected from --H, or --NH.sub.2, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen, with an amount effective to produce DATB or TATB of 1,1,1-trialkylhydrazinium halide wherein alkyl is selected from methyl, ethyl, propyl or butyl and halide is selected from chloride, bromide or iodide. in the presence of a strong base selected from sodium butoxide, potassium butoxide, potassium propoxide, sodium propoxide, sodium ethoxide, potassium ethoxide, sodium methoxide, potassium methoxide, and combinations thereof; in a solvent selected from the group consisting of methanol, ethanol, propanol, butanol, dimethylsulphoxide, N-methylpyrrolidone, hexamethylphosphoramide, dimethylformide, dimethylacetamide and mixtures thereof, provided that when alcohols are present primarily DATB and picramide is formed; and (b) isolating the DATB or TATB produced. DATB and TATB are useful specialty explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  本发明涉及一种生产1,3-二氨基-2,4,6-三硝基苯（DATB）或1,3,5-三氨基-2,4,6-三硝基苯（TATB）的方法，包括：（a）在常压下，温度在0℃至50℃之间，反应式V的三硝基芳香化合物： 其中X、Y和Z分别独立地选自--H或--NH2，但至少1或2个X、Y和Z是氢，与一定量的1,1,1-三烷基肼卤化物反应，其中烷基选自甲基、乙基、丙基或丁基，卤化物选自氯化物、溴化物或碘化物，同时存在强碱，所述强碱选自丁氧基钾、丁氧基钠、丙氧基钾、丙氧基钠、乙氧基钠、乙氧基钾、甲氧基钠、甲氧基钾和它们的组合物，在所选溶剂中进行反应，所选溶剂选自甲醇、乙醇、丙醇、丁醇、二甲基亚砜、N-甲基吡咯烷酮、六甲基膦酰胺、二甲基甲酰胺和它们的混合物，当存在醇时主要形成DATB和苦味酰胺；（b）分离所生产的DATB或TATB。DATB和TATB是有用的专用炸药。TATB也用于制备苯并六胺，这是合成新材料（光学成像设备、液晶、铁磁性化合物）的起始材料。
• Amination of electrophilic aromatic compounds by vicarious nucleophilic
  申请人：The Regents of the University of California

  公开号：US06069277A1

  公开（公告）日：2000-05-30

  The present invention relates to a process to aminate electrophilic aromatic compounds by vicarious nucleophilic substitution of hydrogen using quaternary hydrazinium salts. The use of trialkylhydrazinium halide, e.g., trimethylhydrazinium iodide, as well as hydroxylamine, alkoxylamines, and 4-amino-1,2,4-triazole to produce aminated aromatic structures, such as 1,3-diamino-2,4,6-trinitrobenzene (DATB), 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) and 3,5-diamino-2,4,6-trinitrotoluene (DATNT), is described. DATB and TATB are useful insensitive high explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  本发明涉及一种使用季铵盐对电子亲和性芳香化合物进行邻位亲核取代氢的胺化过程。使用三烷基肼卤化物（例如碘化三甲基肼）以及羟胺，烷氧肼和4-氨基-1,2,4-三唑来生成胺基芳香结构，例如1,3-二氨基-2,4,6-三硝基苯（DATB），1,3,5-三氨基-2,4,6-三硝基苯（TATB）和3,5-二氨基-2,4,6-三硝基甲苯（DATNT）。DATB和TATB是有用的不敏感高爆炸物。TATB也用于制备苯基六胺，这是合成新材料（光学成像设备，液晶，铁磁化合物）的起始材料。
• Goesl; Meuwsen, Chemische Berichte, 1959, vol. 92, p. 2521,2527
  作者：Goesl、Meuwsen

  DOI：——

  日期：——
• The Reaction of Chloramine with Tertiary Amines.¹ 1,1,1-Trisubstituted Hydrazinium Salts²
  作者：George M. Omietanski、Harry H. Sisler

  DOI：10.1021/ja01587a033

  日期：1956.3
• SISLER, H. H.;BARRICK, J. C., POLYHEDRON, 1982, 1, N 6, 535-537
  作者：SISLER, H. H.、BARRICK, J. C.

  DOI：——

  日期：——