tris(benzothieno)<2,3:2',3':2'',3''>benzene | 199-14-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: tris(benzothieno)<2,3:2',3':2'',3''>benzene
• 英文别名: tris-(benzothiopheno)benzene；tribenzo[d,d',d'']benzo[1,2-b;3,4-b';5,6-b'']trithiophene；Tribenzo[d,d',d'']benzo[1,2-b;3,4-b';5,6-b'']trithiophen；9,18,27-Trithiaheptacyclo[18.7.0.02,10.03,8.011,19.012,17.021,26]heptacosa-1(20),2(10),3,5,7,11(19),12,14,16,21,23,25-dodecaene
• CAS: 199-14-4
• 化学式: C₂₄H₁₂S₃
• 分子量: 396.557
• InChiKey: OCCAWLBDLIRDGP-UHFFFAOYSA-N

物化性质

• 熔点：
  422 °C
• 沸点：
  677.1±35.0 °C(Predicted)
• 密度：
  1.510±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  27
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tris(benzothieno)<2,3:2',3':2'',3''>benzene 在 镍 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以38%的产率得到1,3,5-三苯基苯
  参考文献：
  名称：

  Cyclocondensation of 3(2H)-benzo[b]thiophenone and oxidation products obtained during these reactions

  摘要：

  DOI：

  10.1016/s0040-4020(01)87484-6
• 作为产物：
  描述：

  苯并[b]噻吩-3-基乙酸酯 在 三氟乙酸 作用下， 反应 3.0h， 以25%的产率得到tris(benzothieno)<2,3:2',3':2'',3''>benzene
  参考文献：
  名称：

  三吲哚苯及其相关化合物的合成与研究

  摘要：

  不对称的N，N，N-三甲基三吲哚苯3已经通过几种途径合成，包括吲哚的O-乙酸酯的环三聚。该冷凝涉及原位形成的前体的3→2重排。类似的Wagner-Meerwein重排在LAH还原3,3-二吲哚基羟吲哚中也很普遍。

  DOI：

  10.1016/0040-4020(80)85060-5

文献信息

• ORGANIC OPTOELECTRONIC MATERIAL AND USE THEREOF
  申请人：YEN FENG-WEN

  公开号：US20160233427A1

  公开（公告）日：2016-08-11

  The present invention generally discloses an organic optoelectronic material and organic electroluminescent (herein referred to as organic EL) device, organic photovoltaics (herein referred to as OPV) device and organic thin-film transistor (herein referred to as OTFT) device using the organic optoelectronic material. More specifically, the present invention relates to the organic optoelectronic material formula (1), and an organic EL device, OPV device and OTFT device employing the organic optoelectronic material can improve performance.

  本发明通常公开了一种有机光电材料和有机电致发光（以下简称为有机EL）器件，有机光伏（以下简称为OPV）器件和有机薄膜晶体管（以下简称为OTFT）器件使用该有机光电材料。更具体地，本发明涉及有机光电材料的化学式（1），以及采用该有机光电材料的有机EL器件、OPV器件和OTFT器件可以提高性能。
• THERMALLY CONDUCTIVE MATERIAL, DEVICE PROVIDED WITH THERMALLY CONDUCTIVE LAYER, THERMALLY CONDUCTIVE MATERIAL FORMATION COMPOSITION, DISC-SHAPED LIQUID CRYSTAL COMPOUND
  申请人：FUJIFILM Corporation

  公开号：EP3653660A1

  公开（公告）日：2020-05-20

  The present invention provides a thermally conductive material having excellent thermal conductivity. Furthermore, the present invention provides a device with a thermally conductive layer that has a thermally conductive layer containing the thermally conductive material and a composition for forming a thermally conductive material that is used for forming the thermally conductive material. The thermally conductive material according to an embodiment of the present invention contains a cured substance of a disk-like compound, which has one or more reactive functional groups selected from the group consisting of a hydroxyl group, a carboxylic acid group, a carboxylic acid anhydride group, an amino group, a cyanate ester group, and a thiol group, and a crosslinking compound which has a group reacting with the reactive functional groups.

  本发明提供了一种具有优异导热性能的导热材料。此外，本发明还提供了一种具有导热层的设备，该设备具有包含该导热材料的导热层和用于形成导热材料的导热材料组合物。根据本发明一个实施例的导热材料含有盘状化合物的固化物，该固化物具有一个或多个反应性官能团，这些反应性官能团选自由羟基、羧酸基、羧酸酐基、氨基、氰酸酯基和硫醇基组成的组，以及具有与反应性官能团反应的基团的交联化合物。
• COMPOSITION, THERMALLY CONDUCTIVE MATERIAL, DEVICE HAVING THERMAL CONDUCTION LAYER, AND METHOD OF PRODUCING THERMALLY CONDUCTIVE MATERIAL
  申请人：Fujifilm Corporation

  公开号：EP3733730A1

  公开（公告）日：2020-11-04

  A first object of the present invention is to provide a composition capable of forming a cured product (thermally conductive material) having excellent thermal conductivity. In addition, a second object of the present invention is to provide a thermally conductive material formed from the composition and a device with a thermally conductive layer. In addition, a third object of the present invention is to provide a method for manufacturing a thermally conductive material using the composition. The composition of the present invention includes a curing agent including an active hydrogen-containing functional group, and a main agent including a reactive group which reacts with the active hydrogen-containing functional group, in which the main agent and the curing agent respectively exhibit liquid crystallinity in a single state at a temperature of 150°C or lower.

  本发明的第一个目的是提供一种能够形成具有优异导热性的固化产品（导热材料）的组合物。此外，本发明的第二个目的是提供一种由该组合物形成的导热材料和一种带有导热层的装置。此外，本发明的第三个目的是提供一种使用该组合物制造导热材料的方法。 本发明的组合物包括含活性含氢官能团的固化剂和含与活性含氢官能团反应的活性基团的主剂，其中主剂和固化剂在 150°C 或更低的温度下分别表现出单一状态下的液态结晶性。
• 237. The comparative reactivity of the carbonyl groups in the thionaphthenquinones. Part II. The influence of substituent groups in the thionaphthenquinones
  作者：Charles E. Dalgliesh、Frederick G. Mann

  DOI：10.1039/jr9450000893

  日期：——
• BERGMAN J.; EKLUND N., TETRAHEDRON, 1980, 36, NO 10, 1445-1450
  作者：BERGMAN J.、 EKLUND N.

  DOI：——

  日期：——