申请人:Phillips Petroleum Company
公开号:US20030125593A1
公开(公告)日:2003-07-03
A catalyst composition and a process for hydrodealkylating a C
9
+ aromatic compound such as, for example, 1,2,4-trimethylbenzene to a C
6
to C
8
aromatic hydrocarbon such as a xylene are disclosed. The composition comprises an alumina, a metal oxide, a phosphorus oxide and optionally, an acid site modifier selected from the group consisting of silicon oxides, sulfur oxides, boron oxides, magnesium oxides, tin oxides, titanium oxides, zirconium oxides, molybdenum oxides, germanium oxides, indium oxides, lanthanum oxides, cesium oxides, and combinations of any two or more thereof. The process comprises contacting a fluid which comprises a C
9
+ aromatic compound with the catalyst composition under a condition sufficient to effect the conversion of a C
9
+ aromatic compound to a C
6
to C
8
aromatic hydrocarbon.
本发明公开了一种催化剂组合物及其用于氢解烷基化C9+芳香化合物(例如1,2,4-三甲基苯)至C6到C8芳香烃(例如二甲苯)的过程。该组合物包括氧化铝、金属氧化物、磷酸氧化物和可选的酸性位点改性剂,所述酸性位点改性剂选自硅氧化物、硫氧化物、硼氧化物、镁氧化物、锡氧化物、钛氧化物、锆氧化物、钼氧化物、锗氧化物、铟氧化物、镧氧化物、铯氧化物及其任意两种或两种以上的组合。该过程包括将包含C9+芳香化合物的流体与催化剂组合物接触,在足以使C9+芳香化合物转化为C6到C8芳香烃的条件下进行接触。