tris(2-(diethylamino)ethyl)amine | 4432-88-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(2-(diethylamino)ethyl)amine
• 英文别名: tris(2-diethylaminoethane)amine；tris-(2-diethylaminoethyl)amine；tris-(2-diethylamino-ethyl)-amine；Tris-(2-diaethylamino-aethyl)-amin；Tris(2-diethylaminoethyl)amine；N',N'-bis[2-(diethylamino)ethyl]-N,N-diethylethane-1,2-diamine
• CAS: 4432-88-6
• 化学式: C₁₈H₄₂N₄
• 分子量: 314.558
• InChiKey: URKRYOHZWVRTIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris(2-(diethylamino)ethyl)amine 、 碘甲烷 生成 tris-[2-(diethyl-methyl-ammonio)-ethyl]-amine; tris iodide
  参考文献：
  名称：

  Polyamine Salts with Autonomic Blocking Properties¹

  摘要：

  DOI：

  10.1021/ja01638a034
• 作为产物：
  描述：

  N,N,N′,N′-四乙基二乙烯三胺 、 2-二乙氨基氯乙烷盐酸盐 以 乙醇 为溶剂， 反应 2.0h， 以34%的产率得到tris(2-(diethylamino)ethyl)amine
  参考文献：
  名称：

  New Amine-Based Tripodal Copper Catalysts for Atom Transfer Radical Polymerization

  摘要：

  Three new amine-based tripodal copper complexes-tris(2-(diethylamino)ethyl)amine/CuBr (Et6TREN/CuBr), 2,4-dimethyl-6-bis(2-(dimethylamino)ethyl)aminomethylphenoxy (N-tetramethyltriaminephenoxy) (Me(4)TAPH/Cu-II), and N,N-bis[(2-pyridyl)methyl]-2-aminomethylpyrrolide (BPPY/Cu-1)were prepared and investigated as ATRP catalysts in order to understand the effect of steric hindrance and the presence of a charged anionic group on the performance of catalysts based on branched tetradentate amine ligands in ATRP. Catalysts based on these ligands were evaluated for n-butyl acrylate (BA) polymerization, and their performance was compared with those of known analogues: Me6TREN and N-tetraethyltriaminephenoxy (Et(4)TAPH) copper complexes. When compared to Me6TREN/CuBr-mediated polymerization, the more sterically hindered Et6TREN/CuBr catalyst complex promoted a much slower and less controlled BA polymerization. This indicates that bulkiness around the metal center had a strong effect on the ATRP equilibrium. The Me(4)TAPH copper(II) complex was also synthesized and used as an ATRP catalyst in a simultaneous reverse and normal initiation system. The rate of propagation was slightly lower, and control over the polymerization was poorer, than in a Me6TREN-mediated polymerization. However, its catalytic performance was much better than the N-tetraethyl analogue, Et(4)TAPH, copper complex. The much less hindered BPPY copper(l) complex promoted faster BA polymerization in DMF than Me6TREN/CuBr-mediated polymerization, but the control over the polymerization was poor. These results indicate that steric hindrance is an important factor for developing new catalyst complexes for both high activity and control over ATRP. Selected complexes with charged ligands demonstrated enhanced ATRP activity.

  DOI：

  10.1021/ma049874m

文献信息

• [EN] URAZOLE COMPOUNDS<br/>[FR] COMPOSÉS URAZOLE
  申请人：UNIV GENT

  公开号：WO2015018928A1

  公开（公告）日：2015-02-12

  The present invention relates to a compound of formula (I) or a stereoisomer, enantiomer, racemic, or tautomer thereof, (I) wherein R1, R2, R3, R4, R5, R6, R7, L1 and Q1 have the meaning defined in the claims and the description. The present invention also relates to a process for the preparation of the compound of formula (I). The present invention also relates to the use of a compound of formula (I) as an in situ precursor of a triazolinedione reagent for the functionalization of enes, dienes, aryl and heteroaryl systems via the ene reactions, Diels-Alder reactions, and electrophilic aromatic substitution reactions of said reagent. The present invention also relates to the use of a compound of formula (I) in polymers, membranes, adhesives, foams, sealants, molded articles, films, extruded articles, fibers, elastomers, polymer based additives, pharmaceutical and biomedical products, varnishes, paints, coatings, inks, composite material, organic LEDs, organic semiconductors, conducting organic polymers, or 3D printed articles. The present invention also relates to article comprising said compound of formula (I) and to a process for reshaping and/or repairing said article.

  本发明涉及式(I)的化合物或其立体异构体、对映异构体、消旋体或互变异构体，其中R1、R2、R3、R4、R5、R6、R7、L1和Q1在权利要求和说明书中定义的含义。本发明还涉及制备式(I)化合物的方法。本发明还涉及将式(I)化合物用作三唑烯二酮试剂的原位前体，用于通过烯反应、迪尔斯-阿尔德反应和该试剂的亲电芳烃取代反应对烯烃、二烯烃、芳基和杂环芳基体系进行官能化。本发明还涉及将式(I)化合物用于聚合物、膜、粘合剂、泡沫、密封剂、成型制品、薄膜、挤出制品、纤维、弹性体、基于聚合物的添加剂、药用和生物医学产品、清漆、油漆、涂料、油墨、复合材料、有机发光二极管、有机半导体、导电有机聚合物或3D打印制品的用途。本发明还涉及包含所述式(I)化合物的物品以及对所述物品进行重塑和/或修复的方法。
• Nitritereduction by copper complexes
  作者：John G. Woollard-Shore、Jason P. Holland、Michael W. Jones、Jonathan R. Dilworth

  DOI：10.1039/b913463h

  日期：——

  nitrogen atoms, catalytic studies on the conversion of NO2− anions into NO and N2O gases revealed an excellent correlation between the initial rate of conversion and the experimental reduction potential as measured by cyclic voltammetry. Initial catalytic investigations reveal that these simple model complexes display a wide range of catalytic turnover rates, conversion yields and product gas compositions

  一系列 铜 已合成了配合物作为催化还原苯的潜在试剂。 亚硝酸盐阴离子。配体和相应的铜通过使用一系列技术（包括X射线晶体学，NMR，微分析，质谱，红外光谱，电化学研究和密度泛函理论计算）对复合物进行了表征。对于具有接合到赤道施主氮原子简单脂族取代基，对NO的转化催化研究复合物2 -阴离子成不N 2 O气体显示出初始转化率与通过循环伏安法测得的实验还原电位之间具有极好的相关性。初步的催化研究表明，这些简单的模型络合物显示出广泛的催化转化率，转化率和产物气体组成。总体而言，结果表明，需要进一步研究设计和使用铜 配合物作为亚硝酸盐还原催化剂是必要的。
• URAZOLE COMPOUNDS
  申请人：UNIVERSITEIT GENT

  公开号：US20160200707A1

  公开（公告）日：2016-07-14

  The present invention relates to a compound of formula (I) or a stereoisomer, enantiomer, racemic, or tautomer thereof, (I) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , L 1 and Q 1 have the meaning defined in the claims and the description. The present invention also relates to a process for the preparation of the compound of formula (I). The present invention also relates to the use of a compound of formula (I) as an in situ precursor of a triazolinedione reagent for the functionalization of enes, dienes, aryl and heteroaryl systems via the ene reactions, Diels-Alder reactions, and electrophilic aromatic substitution reactions of said reagent. The present invention also relates to the use of a compound of formula (I) in polymers, membranes, adhesives, foams, sealants, molded articles, films, extruded articles, fibers, elastomers, polymer based additives, pharmaceutical and biomedical products, varnishes, paints, coatings, inks, composite material, organic LEDs, organic semiconductors, conducting organic polymers, or 3D printed articles. The present invention also relates to article comprising said compound of formula (I) and to a process for reshaping and/or repairing said article.

  本发明涉及式（I）的化合物或其立体异构体，对映异构体，消旋体或互变异构体，其中R1，R2，R3，R4，R5，R6，R7，L1和Q1具有权利要求书和说明中定义的含义。本发明还涉及制备式（I）化合物的方法。本发明还涉及使用式（I）化合物作为三唑环二酮试剂的原位前体，通过该试剂的烯烃反应，Diels-Alder反应和电子亲和性芳香取代反应来实现烯烃，二烯，芳基和杂环芳基体系的官能化。本发明还涉及将式（I）化合物用于聚合物，膜，粘合剂，泡沫，密封剂，模塑件，薄膜，挤出件，纤维，弹性体，基于聚合物的添加剂，制药和生物医学产品，清漆，油漆，涂料，油墨，复合材料，有机LED，有机半导体，导电有机聚合物或3D打印品的用途。本发明还涉及包含所述式（I）化合物的物品以及用于重塑和/或修复所述物品的方法。
• POLYMERIZATION METHOD
  申请人：KANEKA CORPORATION

  公开号：EP1090930A1

  公开（公告）日：2001-04-11

  This invention is related to a polymerization method    wherein an atom transfer radical polymerization of a vinyl monomer is carried out under at least one condition selected from the group consisting of the following (1), (2), (3) and (4): (1) in a substantially anhydrous system; (2) in the presence of a nitrile compound; (3) addition, to the system, of a ligand to the polymerization catalyst to thereby initiate the polymerization; (4) varying a polymerization catalyst activity during polymerization to thereby control the rate of polymerization. This invention provides a method which allows the terminal halogen atom to remain at a high rate in atom transfer radical polymerization, solve such problems as the difficulty in polymerization rate control as caused by catalyst precipitation and wide variation in catalyst amount, provide a simple and safe method of polymerization initiation as well as a method of controlling the rate of polymerization, and indicate a method of improving the polymerization procedure.

  本发明涉及一种聚合方法 其中，乙烯基单体的原子转移自由基聚合在至少一种选自以下(1)、(2)、(3)和(4)组成的条件下进行： (1) 在基本上无水的体系中； (2) 在有腈化合物存在的情况下 (3) 在体系中向聚合催化剂添加配位体，从而启动聚合反应； (4) 在聚合过程中改变聚合催化剂的活性，从而控制聚合速率。 本发明提供了一种可使末端卤原子在原子转移自由基聚合中保持较高聚合速率的方法，解决了因催化剂沉淀和催化剂用量变化大而导致聚合速率难以控制等问题，提供了一种简单安全的聚合引发方法和聚合速率控制方法，并指出了一种改进聚合程序的方法。
• Reaktionsharz-Zusammensetzung und deren Verwendung
  申请人：HILTI Aktiengesellschaft

  公开号：EP2824155A1

  公开（公告）日：2015-01-14

  Es wird eine Reaktionsharz-Zusammensetzung mit einem Harzbestandteil, der eine radikalisch polymerisierbare Verbindung enthält, und einem Initiatorsystem, das einen α-Halogencarbonsäureester und ein Katalysatorsystem, welches ein Kupfer(I)salz und wenigstens einen Stickstoff-enthaltenden Liganden umfasst, enthält und deren Verwendung für bauliche Zwecke beschrieben.

  描述了一种活性树脂组合物，该组合物由含有可自由基聚合的化合物的树脂成分和由α-卤代羧酸酯组成的引发剂体系以及由铜（I）盐和至少一种含氮配体组成的催化剂体系构成，并可用于建筑目的。