triisopropyl trithiophosphite | 3862-19-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: triisopropyl trithiophosphite
• 英文别名: Tris(propan-2-ylsulfanyl)phosphane
• CAS: 3862-19-9
• 化学式: C₉H₂₁PS₃
• 分子量: 256.438
• InChiKey: HXIGSBXJYCKKPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  triisopropyl trithiophosphite 以 正己烷 、 乙腈 为溶剂， 生成 (triisopropyl trithiophosphite)(acetonitrile)bromocopper(I)
  参考文献：
  名称：

  A New Type of Coordination in Copper(I) Complexes with Trivalent Phosphorus Compounds Containing Phosphorus-Sulfur Bonds

  摘要：

  A series of copper(I) complexes with trialkyl trithiophosphite ligands have been prepared and crystallographically characterized to investigate possible binding modes of potentially tetradentate ligands: (EtS)(3)P . CuHal with Hal Cl, Br, and I; (i-PrS)(3)P . CuBr . CH3CN. Complexes of copper(I) monohalides with triethyl trithiophosphite appeared to be isostructural, exhibiting a bidentate coordination mode via the phosphorus atom of one thiophosphite molecule and the sulfur atom of another, with formation of polymeric chains along the x-axis. In the complex of copper monobromide with triisopropyl trithiophosphite and acetonitrile monodentate coordination via-the phosphorus atom is observed. Crystal data [space group, a, b, c, alpha, beta, gamma, Z (only undefined cell parameters are listed)]: (EtS)(3)P CuCl, monoclinic P2(1)/c, 7.377(2) Angstrom, 14.522(4) Angstrom, 12.275(4) Angstrom, 100.28(2)degrees, 4; (i-PrS)(3)P . CuBr . CHsCN(3)-triclinic P (1) over bar, 8.612(5) Angstrom, 9.401(5) Angstrom, 13.254(5) Angstrom, 81.49(4)degrees, 86.66(4)degrees, 63.24(5)degrees 2.

  DOI：

  10.1021/ic00125a014
• 作为产物：
  描述：

  异丙硫醇 在 三氯化磷 作用下， 以 乙醚 为溶剂， 反应 1.5h， 以55%的产率得到triisopropyl trithiophosphite
  参考文献：
  名称：

  一些亚磷酸酯、硫代亚磷酸酯和酰氨基亚磷酸铜 (I) 卤化物配合物的合成和晶体结构

  摘要：

  一些基于 P(III) 酸酯的 Cu(I) 卤化物络合物，{[(RE)3PCuBr]（其中 E = O、N、S）；获得 R = n-Pr、i-Pr、Et2N}，并使用 IR、31P NMR 光谱和单晶 X 射线衍射对其进行表征。分析了具有各种供体原子 (E = O, N, S) 的配合物的比较结构特征。© 2008 Wiley Periodicals, Inc. 杂原子化学 19:483–489, 2008; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20459

  DOI：

  10.1002/hc.20459

文献信息

• Synthesis and X-ray crystal structure of complexes Cp(CO)2MnP(SR)3 (R = Pri, Ph)
  作者：O. G. Sinyashin、I. Yu. Gorshunov、V. A. Milukov、E. S. Batyeva、I. A. Litvinov、O. N. Kataeva、A. G. Ginzburg、V. I. Sokolov

  DOI：10.1007/bf01558079

  日期：1994.6

  Cp(CO)2Mn · THF reacts in THF with thiosters of phosphorus acid, P(SR)3, to give new complexes Cp(CO)2MnP(SR)3 in which the manganese atom is coordinated to the phosphorus atom. The X-ray crystal structure of compounds with R = Pri and Ph was established. The metal atom has a coordination enviroment of the three-legged “piano stool” type. The bond angles OC-Mn-CO and OC-Mn-P are 90.6–95.9(4)°. Bond

  Cp(CO)2Mn · THF 在 THF 中与磷酸的硫酯 P(SR)3 反应生成新的复合物 Cp(CO)2MnP(SR)3，其中锰原子与磷原子配位。建立了具有 R = Pri 和 Ph 的化合物的 X 射线晶体结构。金属原子具有三足“钢琴凳”式的配位环境。OC-Mn-CO 和 OC-Mn-P 的键角为 90.6–95.9(4)°。键距为：Mn-P 2.188(2) 和 2.171(2) E，PS 2.097(3)-2.137(3) E。
• Milyukov; Zverev; Podlesnov, Russian Journal of General Chemistry, 2000, vol. 70, # 5, p. 698 - 703
  作者：Milyukov、Zverev、Podlesnov、Krivolapov、Litvinov、Gubaidullin、Kataeva、Ginzburg、Sinyashin

  DOI：——

  日期：——
• Triisopropyl Phosphorotrithioite as a Monodantate and a Tridentate Ligand in Complexes with Copper(I) Halides
  作者：L. I. Kursheva、O. N. Kataeva、A. T. Gubaidullin、F. S. Khasyanzyanova、E. V. Vakhitov、D. B. Krivolapov、E. S. Batyeva

  DOI：10.1023/b:rugc.0000016013.38120.58

  日期：2003.10

  Triisopropyl phosphorotrithioite reacts with copper(I) halides to form complexes (i-PrS)(3)(PCuX)-Cu-. (X = I, Br, Cl) of a cubic structure with monodentate coordination by the (CuP)-P-... bond. The complex [(i-PrS)(3)P(.)4Cul](n) is formed by disproportionation of diisopropyl phosphorochloridodithioite and has an unusual structure comprising a two-dimensional net of (CuCl)(8) clusters bridged by triisopropyl phosphorotrithioite ligands; a tridentate coordination by one P(III) and two S(II) atoms was first observed in the complex.
• NIZAMOV, ILYAS S.;BATYEVA, ELVIRA S.;ALFONSOV, LADIMIR A.;MUSIN, RASHID Z+, PHOSPH., SULFUR AND SILICON AND RELAT. ELEM., 55,(1991) N-4, C. 229-237
  作者：NIZAMOV, ILYAS S.、BATYEVA, ELVIRA S.、ALFONSOV, LADIMIR A.、MUSIN, RASHID Z+

  DOI：——

  日期：——
• TAMANO, MICHIKO;IKEDA, TOSHIYUKI;KOKETSU, JUGO, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1984, N 7, 1158-1163
  作者：TAMANO, MICHIKO、IKEDA, TOSHIYUKI、KOKETSU, JUGO

  DOI：——

  日期：——