methyl 10-(thiophen-2-yl)-8-(methylsulfanyl)fluoranthene-7-carboxylate | 1225222-92-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: methyl 10-(thiophen-2-yl)-8-(methylsulfanyl)fluoranthene-7-carboxylate
• 英文别名: Methyl 8-methylsulfanyl-10-thiophen-2-ylfluoranthene-7-carboxylate
• CAS: 1225222-92-3
• 化学式: C₂₃H₁₆O₂S₂
• 分子量: 388.511
• InChiKey: UBRYFRCNWQXIOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  79.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  6-(2-thienyl)-3-methoxycarbonyl-4-methylsulfanyl-2H-pyran-2-one 、 1-苊酮 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 0.67h， 以68%的产率得到methyl 10-(thiophen-2-yl)-8-(methylsulfanyl)fluoranthene-7-carboxylate
  参考文献：
  名称：

  Synthesis, Electrochemical and Optical Properties of Stable Yellow Fluorescent Fluoranthenes

  摘要：

  A novel series of thermally stable yellow light emitting fluoranthenes with an amine donor and a nitrite acceptor was prepared from a ketene-S,S-acetal under mild conditions without using an organometal catalyst. The organic light emitting device of yellow fluoranthene 10b exhibited substantially low turn-on voltage (2.6 V) and maximum brightness of 470 Cd/m(2) with luminance efficiency of 2.0 Cd/A without using any dopant.

  DOI：

  10.1021/jo100420x

文献信息

• Synthesis, Electrochemical and Optical Properties of Stable Yellow Fluorescent Fluoranthenes
  作者：Atul Goel、Vijay Kumar、Sumit Chaurasia、Madhu Rawat、Ramesh Prasad、R. S. Anand

  DOI：10.1021/jo100420x

  日期：2010.6.4

  A novel series of thermally stable yellow light emitting fluoranthenes with an amine donor and a nitrite acceptor was prepared from a ketene-S,S-acetal under mild conditions without using an organometal catalyst. The organic light emitting device of yellow fluoranthene 10b exhibited substantially low turn-on voltage (2.6 V) and maximum brightness of 470 Cd/m(2) with luminance efficiency of 2.0 Cd/A without using any dopant.