1-chloro-1,2-diphenylpropane | 92551-16-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-chloro-1,2-diphenylpropane
• 英文别名: 1-chloro-1,2-diphenyl-propane；1-Chlor-1,2-diphenyl-propan；(1-Chloro-2-phenylpropyl)benzene；(1-chloro-1-phenylpropan-2-yl)benzene
• CAS: 92551-16-1
• 化学式: C₁₅H₁₅Cl
• 分子量: 230.737
• InChiKey: ZGMJJKKKBGMBGK-UHFFFAOYSA-N

物化性质

• 熔点：
  139-140 °C
• 沸点：
  301.2±11.0 °C(Predicted)
• 密度：
  1.086±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-chloro-1,2-diphenylpropane 在 氢氧化钾 、 氢溴酸 、 溶剂黄146 作用下， 生成 (E)-1-甲基-1,2二苯基乙烯
  参考文献：
  名称：

  The Coupling Action of the Grignard Reagent. V. The Influence of the Halogen Atom of the Reagent

  摘要：

  DOI：

  10.1021/ja01334a057
• 作为产物：
  描述：

  phenylmagnesium bromide 在 五氯化磷 作用下， 生成 1-chloro-1,2-diphenylpropane
  参考文献：
  名称：

  Tiffeneau, Annales de Chimie (Cachan, France), 1907, vol. <8> 10, p. 359

  摘要：

  DOI：

文献信息

• Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene
  作者：Michael P. Doyle、Jack Taunton、Su-Min Oon、Michael T.H. Liu、N. Soundararajan、Matthew S. Platz、James E. Jackson

  DOI：10.1016/s0040-4039(00)82210-8

  日期：1988.1

  Reactivities for intermolecular C-H/Si-H/Sn-H insertion reactions of chlorophenylcarbene follow the order tri-n-butyltin hydride⪢diphenylsilanetriethylsilane⪢ cumenethylbenzene⪢toluene, and these reactions are competitive with addition to the double bond of α,β-unsaturated esters.

  对于chlorophenylcarbene的分子间的CH /的Si-H /锡-H插入反应的反应性按照顺序三Ñ -butyltinhydride⪢diphenylsilanetriethylsilane⪢cumenethylbenzene⪢toluene，并且这些反应是竞争性与除了α，β不饱和酯的双键。
• Salicylic acid copolymers and their metal salts, production process thereof, color-developing agents comprising metal salts of the copolymers and color-developing sheets employing the agents
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0268878A2

  公开（公告）日：1988-06-01

  Disclosed herein are salicylic acid copolymers having a weight average molecular weight of 500 10,000 and obtained (a) by condensing salicylic acid (i) with a benzyl alcohol (ii) and/or benzyl ether (iii) or a benzyl halide (iv) in the presence of an acid catalyst or (b) by reacting a co-condensation resin of (i) and (ii) and/or (iii) with (iv) or (c) by reacting a co-condensation resin of (i) and (ii) and/or (iii) or (iv) with a styrene derivative in the presence of an acid catalyst; multivalent metal salts of the salicylic acid copolymers; color-developing agents comprising the multivalent metal salts; and color-developing sheets suited for pressure-sensitive copying paper and comprising the color-developing agents. Their production processes are also disclosed.

  本文公开了水杨酸共聚物，其重量平均分子量为 500 10、000 的水杨酸共聚物；(a)在酸催化剂存在下，将水杨酸(i)与苄醇(ii)和/或苄醚(iii)或苄基卤化物(iv)缩合而得，或(b)将(i)和(ii)和/或(iii)的共缩合树脂与(iv)反应而得，或(c)在酸催化剂存在下，将(i)和(ii)和/或(iii)或(iv)的共缩合树脂与苯乙烯衍生物反应而得；水杨酸共聚物的多价金属盐；由多价金属盐组成的显色剂；以及由显色剂组成的适用于压敏复印纸的显色薄片。此外，还公开了它们的生产工艺。
• Indium-Catalyzed Direct Chlorination of Alcohols Using Chlorodimethylsilane−Benzil as a Selective and Mild System
  作者：Makoto Yasuda、Satoshi Yamasaki、Yoshiyuki Onishi、Akio Baba

  DOI：10.1021/ja048688t

  日期：2004.6.1

  The InCl3-catalyzed reaction of alcohols with chlorodimethylsilane (HSiMe2Cl) in the presence of benzil gave the corresponding organic chlorides under mild conditions. Benzil significantly changes the reaction course because the reducing product through dehydroxyhydration was obtained in the absence of benzil. The secondary or tertiary alcohols were effectively chlorinated. The substrates bearing acid-sensitive functional groups were also applied to this system. The highly selective chlorination of the tertiary site was observed in the competitive reaction between tertiary and primary alcohols. The highly coordinated hydrosilane generated from benzil and HSiMe2Cl is an important intermediate.
• Kayser, Annales de Chimie (Cachan, France), 1936, vol. <11> 6, p. 145,176
  作者：Kayser

  DOI：——

  日期：——
• DOYLE, MICHAEL P.;TAUNTON, JACK;QON, SU-MIN;LIU, MICHAEL T. H.;SOUNDARARA+, TETRAHEDRON LETT., 29,(1988) N 46, C. 5863-5866
  作者：DOYLE, MICHAEL P.、TAUNTON, JACK、QON, SU-MIN、LIU, MICHAEL T. H.、SOUNDARARA+

  DOI：——

  日期：——