pentachloroethanesulfenyl chloride | 5940-94-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: pentachloroethanesulfenyl chloride
• 英文别名: pentachloroethanesulphenyl chloride；chloro-pentachloroethyl-sulfane；1,1-Dichloro-2,2,2-trichloroethane sulphenyl chloride；1,1,2,2,2-pentachloroethyl thiohypochlorite
• CAS: 5940-94-3
• 化学式: C₂Cl₆S
• 分子量: 268.806
• InChiKey: YDWKWNIVLRQNDZ-UHFFFAOYSA-N

物化性质

• 熔点：
  73-75 °C
• 沸点：
  80 °C(Press: 0.25 Torr)
• 密度：
  1.804 g/cm3(Temp: 23 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  pentachloroethanesulfenyl chloride 在 五羰基铁 作用下， 以 四氢呋喃 为溶剂， 生成 bis-trichlorovinyl-disulfane
  参考文献：
  名称：

  Lindner,E.; Vitzthum,G., Angewandte Chemie, 1969, vol. 81, p. 532 - 533

  摘要：

  DOI：

文献信息

• Synthesis, structure, and reactions of thiocarbonic acid derivatives new pentathiodipercarbonates, (RSS)2 CS, α,α,α-tris(disulfides), and the first α,α,α-tris(trisulfide)
  作者：Holger C. Hansen、Alexander Senning、Rita G. Hazell

  DOI：10.1016/s0040-4020(01)96759-6

  日期：1985.1

  Novel bis(perhaloalkyl) pentathiodipercarbonates have been synthesized by reaction of sulfenyl chlorides with metal trithiocarbonates, and the heptathio analog was prepared similarly. Lenthionine is the main product when diiodomethane is treated with sodium tetrathiopercarbonate. A rearrangement of bis(alkyldithio)chloromethanesulfenyl chlorides to alkyldithio) (alkyltrithio)dichloromethanes has been

  通过亚磺酰氯与金属三硫代碳酸酯的反应合成了新型的双（全卤代烷基）五硫代二过碳酸酯，并且类似地制备了七硫代类似物。当用四硫代过碳酸钠处理二碘甲烷时，硫代赖氨酸是主要产物。已经观察到双（烷基二硫代）氯甲烷亚磺酰氯重排为烷基二硫代）（烷基三硫代）二氯甲烷。将亚硫酰氯和硫代亚硫酰氯加到硫代羰基化合物中，并在乙腈中实现。第一结晶五硫代二过碳酸盐和α，α，α-三（二硫化物）的结构以及首次报道的α，α，α-三（三硫化物）的结构 已经通过X射线晶体学确定。
• Generation and selected reactions of chlorinated thiocarbonyl <i>S</i>-imides
  作者：Grzegorz Mlostoń、Paulina Pipiak、Jürgen Voss、Dirk Buddensiek、Alexander Senning

  DOI：10.1080/17415993.2017.1325892

  日期：2017.9.3

  1-trichloromethanesulfenamides yield the corresponding sulfur N,N′-diaryldiimides via a multi-step reaction, whereas the less crowded 2-methylphenyl and 4-methylphenyl derivatives undergo a regioselective ‘head-to-head’ dimerization leading to 5,5,6,6-tetrachloro-1,4,2,3-dithiadiazinanes in high yields. An identical reaction course is observed in the case of the 4-methoxy- and 4-bromoaniline derivatives. A diradical

  摘要 N-Aryl-1,1,1-trichloromethanesulfenamides ArNH-SCCl3 在乙醇溶液中用氢氧化钾处理后很容易发生脱氯化氢。由此形成的中间体硫代羰基S-酰亚胺根据N-芳基的类型而表现不同。空间拥挤的 N-(2,6-二甲基苯基)-和-N-(2,4,6-三甲基苯基)-1,1,1-三氯甲亚磺酰胺通过多步反应生成相应的硫 N,N'-二芳基二亚胺，而不太拥挤的 2-甲基苯基和 4-甲基苯基衍生物经过区域选择性的“头对头”二聚化，导致高产率的 5,5,6,6-四氯-1,4,2,3-二噻二嗪。在4-甲氧基-和4-溴苯胺衍生物的情况下观察到相同的反应过程。假设有一种双自由基机制来解释“头对头”二聚化途径。
• Pesticidal compositions and processes for treating plants
  申请人：Imperial Chemical Industries Limited

  公开号：US04307098A1

  公开（公告）日：1981-12-22

  A method and pesticidal composition for the preventative, protectant, prophylactic and eradicant treatment of plant fungi and bacteria comprises applying an effective amount to plants or seeds of a pesticidal composition containing in an inert carrier a compound of the formula ##STR1## wherein R is hydrogen, methyl or ethyl; R.sup.1 is polyhaloalkyl or polyhalovinyl; R.sup.2 is lower alkyl, lower alkoxy, bromo, chloro, fluoro, lower haloalkyl, cyano, nitro, lower alkylthio, lower alkylcarbonyl, lower alkoxycarbonyl or cycloalkyl; R.sup.3 is hydrogen or independently selected from the values of R.sup.2 ; R.sup.4 is hydrogen or independently selected from the values of R.sup.2 ; X is hydrogen, carbamoyl or cyano; and y is zero, one or two.

  一种用于预防、保护、预防和根除植物真菌和细菌的方法和杀虫剂组合物，包括将含有公式##STR1## 中化合物的惰性载体的杀虫剂组合物的有效量应用于植物或种子上，其中R为氢、甲基或乙基；R.sup.1为多卤代烷基或多卤代乙烯基；R.sup.2为较低的烷基、较低的烷氧基、溴、氯、氟、较低的卤代烷基、氰基、硝基、较低的烷基硫基、较低的烷基羰基、较低的烷氧羰基或环烷基；R.sup.3为氢或独立于R.sup.2的值选择；R.sup.4为氢或独立于R.sup.2的值选择；X为氢、氨基甲酰基或氰基；y为零、一或二。
• 1-Phenyl-3-polyhaloalkyl(vinyl)sulfenyl uracils
  申请人：Zoecon Corporation

  公开号：US04358591A1

  公开（公告）日：1982-11-09

  Novel 1-phenyl-3-polyhaloalkyl or polyhalovinyl uracils, and synthesis thereof, which are useful biological agents.

  这是一篇关于合成新型1-苯基-3-多卤代烷基或多卤代乙烯基尿嘧啶类化合物的论文，这些化合物具有生物学活性。
• Novel sulfenylated acylhydrazones, compositions containing them, methods of making them and their use
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0172031A1

  公开（公告）日：1986-02-19

  57 Sulfenylated acylhydrazones having the formula wherein R' is hydrogen, cyano, straight or branched chain lower (C1-C4) alkyl optionally substituted with imidazolyl, triazolyl or one or more of the same or different halo; or phenyl optionally substituted with one or more of the same or different halo, nitro, cyano, (C1-C4)-alkyl or (C1-C4)-alkoxy: R2 is hydrogen; straight or branched chain (C1-C11)-alkyl optionally substituted with imidazolyl. triazolyl, or one or more of the same or different halo; (C1-C4)-alkoxy; (C1-C4)-thioalkyl; (C2-Ce)-alkenyl optionally substituted with one or more of the same or different halo; heterocyclic optionally substituted with one or more of the same of different halo or nitro: phenyl optionally substituted with one or more of the same or different halo; (C1-C4)-alkyl, (C1-C4)-alkoxy or nitro; or phenalkyl where the alkyl moiety contains one to four carbon atoms and the phenyl ring is optionally substituted with one or more of the same or different halo (chloro, fluoro, bromo or iodo), cyano, nitro, (C1-C4)-alkyl, (C1-C4)-alkoxy, or (C1-C4)-haloalkyl; Z is (C1-C4)-haloalkyl; and A is phenyl optionally substituted with one or more of the same or different halo, nitro, cyano, hydroxy, (C1-C8)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-thioalkyl, (C1-C6)-alkoxy, (C,-Ce)-carbalkoxy, allyloxy, (C1-C6)-alkenoyloxy, (C1-C6)-alkylamino, (C1-C6)-dialkylamino or benzyloxy; thiorphenyl optionally substituted with one or more of the same or different nitro or halo; furyl optionally substituted with one or more of the same or different nitro or halo; pyridyl; or naphthyl; and compositions containing these compounds exhibit biocidal and plant fungicidal activity.

  57 亚磺酰基酰肼，其式为 其中 R'是氢、氰基、任选被咪唑基、三唑基或一个或多个相同或不同卤素取代的直链或支链低级 (C1-C4) 烷基；或任选被一个或多个相同或不同卤素、硝基、氰基、(C1-C4)-烷基或 (C1-C4)- 烷氧基取代的苯基：R2 是氢；直链或支链（C1-C11）-烷基，可选择被咪唑基、三唑基、或一个或多个相同或不同的卤素、硝基、氰基、（C1-C4）-烷氧基取代。(C1-C4)-烷氧基；(C1-C4)-硫代烷基；可选择被一个或多个相同或不同卤素取代的(C2-Ce)-烯基；可选择被一个或多个相同或不同卤素或硝基取代的杂环：苯基可选择被一个或多个相同或不同的卤素取代；(C1-C4)-烷基、(C1-C4)-烷氧基或硝基；或苯基，其中烷基含有一至四个碳原子，苯基环可选择被一个或多个相同或不同的卤素（氯、氟、溴或碘）、氰基、硝基、(C1-C4)-烷基、(C1-C4)-烷氧基或(C1-C4)-卤代烷基取代；Z 为(C1-C4)-卤代烷基；以及 A 是被一个或多个相同或不同的卤代、硝基、氰基、羟基、(C1-C8)-烷基、(C1-C6)-卤代烷基、(C1-C6)-硫代烷基、(C1-C6)-烷氧基、(C,-Ce)-烷氧基、烯丙氧基、(C1-C6)-烯酰氧基、(C1-C6)-烷基氨基、(C1-C6)-二烷基氨基或苄氧基任选取代的苯基； 可选择被一个或多个相同或不同的硝基或卤素取代的硫代苯基； 可选择被一个或多个相同或不同的硝基或卤素取代的呋喃基； 吡啶基；或萘基；含有这些化合物的组合物具有生物杀灭和植物杀菌活性。