monomethylamino complex | 117178-70-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: monomethylamino complex
• 英文别名: 1-Methylaminoethylidenechromium pentacarbonyl
• CAS: 117178-70-8
• 化学式: C₈H₇CrNO₅
• 分子量: 249.143
• InChiKey: WXGVVKBFWGSBPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.29
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  17
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  monomethylamino complex 生成 N-乙基甲基胺
  参考文献：
  名称：

  消除氨基碳烯配合物

  摘要：

  DOI：

  10.1039/c1967001024a
• 作为产物：
  描述：

  (CO)5CrC(Me)(n-butylamine) 在 甲胺 作用下， 以 乙醚 为溶剂， 以30%的产率得到monomethylamino complex
  参考文献：
  名称：

  Übergangsmetall-Carben-Komplexe：IX。黚模具顺-反式-isomerisierung冯[ Ñ甲氨基） - methylcarben] pentacarbonylchrom（0）mittels BASEN

  摘要：

  [顺式-（N-甲基氨基）甲基卡宾]五羰基铬（0）与碱的反应产生顺式和反式异构体的混合物。可逆异构化可能通过阴离子进行，该阴离子是由质子从氮原子中提取而来的。

  DOI：

  10.1016/s0022-328x(00)86334-2

文献信息

• Hydrazinolysis of Fischer-type oxacarbenes made efficient: a new and easy entry to alkyl and aryl hydrazinocarbene complexes
  作者：Emanuela Licandro、Stefano Maiorana、Antonio Papagni、Dario Perdicchia、Raffaella Manzotti

  DOI：10.1039/a900166b

  日期：——

  Hydrazinolysis of the pentacarbonyl[alkyl- or aryl-(methoxy)carbene] complexes of W0 and Cr0 with both 1,1- and 1,2-disubstituted hydrazines affords the corresponding new hydrazinocarbenes 15–18, 21 and 22, and the presence of LiCl in the reaction medium greatly increases their yields.

  五碳基[烷基或芳基-(甲氧基)碳烯]的W0和Cr0复合物与1,1-和1,2-取代的肼进行氢肼解反应，得到相应的新肼基碳烯15-18、21和22，并且在反应介质中加入LiCl显著提高了它们的产率。
• Gold acyls and imidoyls prepared from anionic Fischer-type carbene complexes
  作者：Helgard G. Raubenheimer、Matthias W. Esterhuysen、Catharine Esterhuysen

  DOI：10.1016/j.ica.2005.03.029

  日期：2005.11

  Reaction of [(CO) 5 WC(O)Ph]Li or [(CO) 5 WC(O)Ph]NBu 4 with Ph 3 PAuCl affords acyl complexes of gold. In the latter conversion, both the crystalline products [(CO) 5 WCl]NBu 4 ( 2 ) and Ph 3 PAuC(O)Ph ( 3 ) have been isolated and fully characterised. Similarly, imidoyl gold compounds ( 4 – 8 ) result from deprotonated aminocarbene complexes, [(CO) 5 MC(NR 2 )R 1 ]Li (M = Cr, W; R 1 = Ph, Me; R 2

  [（CO）5 WC（O）Ph] Li或[（CO）5 WC（O）Ph] NBu 4与Ph 3 PAuCl反应得到金的酰基络合物。在后一种转化中，晶体产物[（CO）5 WCl] NBu 4（2）和Ph 3 PAuC（O）Ph（3）均已分离并充分表征。同样，亚氨基金化合物（[– CO] 5 MC（NR 2）R 1] Li（M = Cr，W; R 1 = Ph，Me; R 2 = H，Me ）和Ph 3 PAuCl。双核[Ph 3 PAuC（NH）Ph]·Cr（CO）5（6）的晶体和分子结构测定表明，羰基铬单元的N-配位选择性地提供了Z-异构体。
• Reaction of aminocarbene complexes of chromium with alkynes. 1. Formation and rearrangement of ketene and nitrogen ylide complexes
  作者：Evelyne Chelain、Regis Goumont、Louis Hamon、Andree Parlier、Michele Rudler、Henri Rudler、Jean Claude Daran、Jacqueline Vaissermann

  DOI：10.1021/ja00047a018

  日期：1992.10

  The title reactions of chromium-containing carbene complexes (CO)5Cr=C(R1)N(R2R3) (R1 = H, Me, Ph; R2 = Me; R3 = Me, C3H5, CH2C3H5; R2R3 = (CH2)5) 8 and (CO)5Cr=C[(CH2)3C=CPh]N(R1R2) (R1 = R2 = Me; R1R2 = (CH2)5; R1R2 = (CH2)4) 9, bearing alkyl groups of low migratory aptitude on nitrogen, have been examined. In contrast to complexes in which nitrogen bears either an alkyl and an allyl or a benzyl group or is part of a strained cycle, which give heterocycles upon alkyne/CO insertions followed by nitrogen-to-carbon migrations (e.g., 1 --> 7), complexes 8 and 9 lead to stable nitrogen ylides, which could be fully characterized by X-ray crystallography in the case of 8a and 9a. Moreover, in the case of complexes of the general structure 9, ketene precursors of the ylides could either be detected (R1 = Me; R2 = CH2Ph) or isolated and characterized (R2R3 = (CH2)5). The new ylide complexes undergo, upon moderate heating, Stevens-type rearrangements to the expected heterocyclic compounds as a result of nitrogen-to-carbon migrations of various alkyl groups, and upon treatment with dimethyldioxirane, they undergo oxidation to lactone complexes.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cr: Org.Verb., 1.1.2.3.3.1, page 106 - 112
  作者：

  DOI：——

  日期：——
• Kreiter, C. G., 4th Intern. Conf. Organometal. Chem., Bristol 1969, S. B 19
  作者：Kreiter, C. G.

  DOI：——

  日期：——