N,N,N'-trimethyl-N'-octylethylenediamine | 117685-18-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N'-trimethyl-N'-octylethylenediamine
• 英文别名: N,N,N'-trimethyl-N'-octyl-ethylenediamine；N,N,N'-Trimethyl-N'-octyl-aethylendiamin；N,N,N'-trimethyl-N'-octylethane-1,2-diamine
• CAS: 117685-18-4
• 化学式: C₁₃H₃₀N₂
• 分子量: 214.395
• InChiKey: HELDNTCRGHWURW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 N,N,N'-trimethyl-N'-octylethylenediamine 以 二氯甲烷 为溶剂， 以52%的产率得到[PdCl2(N,N,N'-trimethyl-N'-octylethylenediamine)]
  参考文献：
  名称：

  Preparation of palladium(II) complexes with long alkyl chain ligand incorporated in micelle

  摘要：

  Three palladium(II) complexes with a bidentate nitrogen ligand having a long alkyl chain (1, [PdCl2(C-8-tmen)], C-8-tmen = N,N,N'-trimethyl-N'-octylethylenediamine; 2, [PdCl2(C-16-tmen)], C-16-tmen = N,N,N'-trimethyl-N'-cetylethylenediamine; 3, [PdCl2(C-8-bpy)], C-8-bpy = 4-octyl-2,2'-bipyridine) were prepared. Addition of 1 to an aqueous solution of cetyltrimethylammonium bromide gave a metallomicelle containing the Pd(II) complex (1A). The other palladium complexes (2 and 3) were not incorporated into the CTABr micelle due to the unsuitable matching between the ligand and the micelle. 1A showed good catalytic performance for Suzuki and Heck coupling reactions in water. The catalyst system for the Heck reaction in water was reusable. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.05.015
• 作为产物：
  描述：

  N-甲基辛胺 、 2-氯-N,N-二甲基乙胺 在 xylene 作用下， 生成 N,N,N'-trimethyl-N'-octylethylenediamine
  参考文献：
  名称：

  Derivatives of Dimethylaminoethanol and Dimethylaminoethylamine

  摘要：

  DOI：

  10.1021/ja01125a050

文献信息

• US4083847A
  申请人：——

  公开号：US4083847A

  公开（公告）日：1978-04-11
• US4260770A
  申请人：——

  公开号：US4260770A

  公开（公告）日：1981-04-07
• US9873694B2
  申请人：——

  公开号：US9873694B2

  公开（公告）日：2018-01-23
• Derivatives of Dimethylaminoethanol and Dimethylaminoethylamine
  作者：Godfrey F. Grail、Leon E. Tenenbaum、Alexander V. Tolstoouhov、Charles J. Duca、John F. Reinhard、Floyd E. Anderson、John V. Scudi

  DOI：10.1021/ja01125a050

  日期：1952.3
• Preparation of palladium(II) complexes with long alkyl chain ligand incorporated in micelle
  作者：Takeyoshi Yagyu、Manabu Tonami、Kazuki Tsuchimoto、Chie Takahashi、Koichiro Jitsukawa

  DOI：10.1016/j.ica.2012.05.015

  日期：2012.9

  Three palladium(II) complexes with a bidentate nitrogen ligand having a long alkyl chain (1, [PdCl2(C-8-tmen)], C-8-tmen = N,N,N'-trimethyl-N'-octylethylenediamine; 2, [PdCl2(C-16-tmen)], C-16-tmen = N,N,N'-trimethyl-N'-cetylethylenediamine; 3, [PdCl2(C-8-bpy)], C-8-bpy = 4-octyl-2,2'-bipyridine) were prepared. Addition of 1 to an aqueous solution of cetyltrimethylammonium bromide gave a metallomicelle containing the Pd(II) complex (1A). The other palladium complexes (2 and 3) were not incorporated into the CTABr micelle due to the unsuitable matching between the ligand and the micelle. 1A showed good catalytic performance for Suzuki and Heck coupling reactions in water. The catalyst system for the Heck reaction in water was reusable. (C) 2012 Elsevier B. V. All rights reserved.