butane-1,4-dimesylate | 7040-87-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: butane-1,4-dimesylate
• 英文别名: 1,4-bis-methanesulfonyl-butane；1.4-Bis-(methylsulfonyl)-butan；1.4-Bis-methylsulfonyl-butan；1,4-Bis(methylsulfonyl)butane
• CAS: 7040-87-1
• 化学式: C₆H₁₄O₄S₂
• 分子量: 214.307
• InChiKey: PBIMIEGCHKDDMF-UHFFFAOYSA-N

物化性质

• 熔点：
  200-201 °C
• 沸点：
  473.4±28.0 °C(Predicted)
• 密度：
  1.263±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  85
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  butane-1,4-dimesylate 、 tetrahydroxy cavitand 、 叠氮苯 在 六甲基磷酰三胺 、 caesium carbonate 作用下， 反应 96.0h， 以91%的产率得到
  参考文献：
  名称：

  The Phenylnitrene Rearrangement in the Inner Phase of a Hemicarcerand

  摘要：

  The photochemistry of phenyl azide 1 and 13C-labeled phenyl azide 13C-1 incarcerated inside a hemicarcerand 4 was investigated. Low-temperature photolysis of hemicarceplex 41 and 413C-1 yields incarcerated 1-azacyclohepta-1,2,4,6-tetraene 42 and 413C-2 (18-50%), respectively, which were characterized by low-temperature FT-IR and 1H NMR and 13C NMR spectroscopy. After correction for the hemicarcerand-induced upfield shift, the 13C chemical shifts of incarcerated 13C-2 compare very well (Deltadelta

  DOI：

  10.1021/ja044557g
• 作为产物：
  描述：

  2,7-二硫代辛烷 在 双氧水 、 溶剂黄146 作用下， 生成 butane-1,4-dimesylate
  参考文献：
  名称：

  The Mechanism of Action of Bisalkylating Agents in Cancer Chemotherapy. II. The Reaction of Myleran with Mercaptans¹

  摘要：

  DOI：

  10.1021/jo01064a064

文献信息

• Method for synthesizing spiro quartenary ammonium systems
  申请人：Siggel Alfred

  公开号：US20070049750A1

  公开（公告）日：2007-03-01

  A method for preparing a spiro quaternary ammonium system and electrolytes containing spiro quaternary ammonium cations, comprising a synthesizing step wherein a spiro ammonium system is formed in a medium that can serve as both the reaction solvent and as an electrolyte solvent.

  一种制备螺环季铵体系和含有螺环季铵阳离子的电解质的方法，包括合成步骤，其中在既可作为反应溶剂又可作为电解质溶剂的介质中形成螺环铵体系。
• Process for the preparation of 1-aminopyrrolidine
  申请人：OTSUKA CHEMICAL COMPANY, LIMITED

  公开号：EP0894788A1

  公开（公告）日：1999-02-03

  1-Aminopyrrolidine which is obtained by reacting hydrazine hydrate with a compound represented by the following formula (I):         X1-C4H8-X2     (I) wherein X1 and X2 are the same or different, and each represents a leaving group, in methanol; and a process for producing 1-aminopyrrolidine, comprising the step of reacting hydrazine hydrate with the above compound represented by formula (I) in methanol.

  1-氨基吡咯烷，由肼水合物与下式（I）所代表的化合物反应而得： X1-C4H8-X2 (I) 其中 X1 和 X2 相同或不同，各自代表一个离去基团，在甲醇中反应；以及一种生产 1-氨基吡咯烷的工艺，包括使肼水合物与上述式 (I) 所代表的化合物在甲醇中反应的步骤。
• MIZHIRITSKIJ M. D.; REJXSFELD V. O., ZH. OBSHCH. XIMII, 56,(1986) N 7, 1547-1558
  作者：MIZHIRITSKIJ M. D.、 REJXSFELD V. O.

  DOI：——

  日期：——
• METHOD FOR SYNTHESIZING QUATERNARY AMMONIUM SYSTEMS
  申请人：Honeywell International Inc.

  公开号：US20130264510A1

  公开（公告）日：2013-10-10

  A method for preparing a spiro quaternary ammonium system and electrolytes containing spiro quaternary ammonium cations, comprising a synthesizing step wherein a spiro ammonium system is formed in a medium that can serve as both the reaction solvent and as an electrolyte solvent.
• US5981764A
  申请人：——

  公开号：US5981764A

  公开（公告）日：1999-11-09