2-氨基-3-苯基-萘 | 875822-75-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-氨基-3-苯基-萘
• 英文名称: 3-phenyl-2-aminonaphthalene
• 英文别名: 2-amino-3-phenylnaphthalene；3-Phenyl-2-naphthylamin；2-Amino-3-phenyl-naphthalin；3-phenyl-naphthalen-2-ylamine；3-Phenylnaphthalen-2-amine
• CAS: 875822-75-6
• 化学式: C₁₆H₁₃N
• 分子量: 219.286
• InChiKey: JYMKGFYNWLWJEZ-UHFFFAOYSA-N

物化性质

• 沸点：
  391.7±11.0 °C(Predicted)
• 密度：
  1.147±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-氨基-3-苯基-萘 在 吡啶 、 六氟异丙醇 、 碘苯二乙酸 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 N-2-(pyridyl)sulfonyl-5H-benzo[b]carbazole
  参考文献：
  名称：

  Pd^II-Catalyzed Di-o-olefination of Carbazoles Directed by the Protecting N-(2-Pyridyl)sulfonyl Group

  摘要：

  Despite the significance of carbazole in pharmacy and material science, examples of the direct C-H functionalization of this privileged unit are quite rare. The N-(2-pyridyl)sulfonyl group enables the Pd-II-catalyzed ortho-olefination of carbazoles and related systems, acting as both a directing and readily removable protecting group. This method features ample structural versatility, affording typically the double ortho-olefination products (at Cl and C8) in satisfactory yields and complete regiocontrol. The application of this procedure to related heterocyclic systems, such as indoline, is also described.

  DOI：

  10.1021/ol400206k
• 作为产物：
  描述：

  3-phenyl-2-naphthoic acid 生成 2-氨基-3-苯基-萘
  参考文献：
  名称：

  755.核间环化。第十七部分。一些N-甲基苯并蒽醌的独立合成及其通过核间环化反应的形成

  摘要：

  DOI：

  10.1039/jr9610003873

文献信息

• Sequential C−H Borylation and N‐Demethylation of 1,1′‐Biphenylamines: Alternative Route to Polycyclic BN‐Heteroarenes
  作者：Jianbo Zhang、Hoimin Jung、Dongwook Kim、Sehoon Park、Sukbok Chang

  DOI：10.1002/anie.201902499

  日期：2019.5.27

  sequential borane‐mediated C(sp2)−H borylation and intramolecular N‐demethylation. The conveniently in situ generated Piers’ borane from a borinic acid reacts with a series of N,N‐dimethyl‐1,1′‐biphenyl‐2‐amines in the presence of PhSiH3 to afford six‐membered amine‐borane adducts bearing a C(sp2)−B bond at the C2′‐position. These species undergo an intramolecular N‐demethylation with a B(C6F5)3 catalyst to

  本文描述了通过连续的硼烷介导的C（sp 2）-H硼化和分子内N-去甲基化从1,1'-联苯胺获得BN-多芳族化合物的空前途径。在PhSiH 3存在下，由硼酸方便地就地生成的Piers'硼烷与一系列N，N-二甲基-1,1'-联苯-2-胺反应，得到六元胺-硼烷加合物在C2'位置的C（sp 2）-B键。这些物种通过B（C 6 F 5）3进行分子内N-去甲基化提供多芳族化合物的BN-等排体的催化剂。根据计算研究，提出了逐步的离子途径。所产生的BN-杂芳烃的光物理特征表明它们与全碳类似物具有显着差异。
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011115378A1

  公开（公告）日：2011-09-22

  Disclosed are organic electroluminescent compounds and organic electroluminescent devices employing said compounds. The organic electroluminescent compounds of the invention are defined by chemical formula [1], Chemical Formula 1 The compounds, when used in an electron transport layer of an organic electroluminescent device, reduce power consumption and operation voltage of said device. Provided are novel organic electroluminescent compounds and an organic electroluminescent device using the same. Since the organic electroluminescent compound exhibits good luminous efficiency and excellent life property, it may be used to manufacture OLED devices having very superior operation life and consuming less power due to improved power efficiency.

  本发明涉及有机电致发光化合物和采用该化合物的有机电致发光器件。该发明的有机电致发光化合物由化学式[1]定义，化学式1。当该化合物用于有机电致发光器件的电子传输层时，可降低该器件的功耗和操作电压。本发明提供了新型有机电致发光化合物和采用该化合物的有机电致发光器件。由于该有机电致发光化合物表现出良好的发光效率和优异的寿命特性，因此可以用于制造具有非常优越的操作寿命和改进功率效率的OLED器件。
• Ligand-controlled regiodivergent Ni-catalyzed <i>trans</i>-hydroboration/carboboration of internal alkynes with B₂pin₂
  作者：Zunsheng Chen、Biao Nie、Xiaoning Li、Teng Liu、Chunsheng Li、Jiuzhong Huang

  DOI：10.1039/d3sc04184k

  日期：——

  Unprecedented regioselective trans-hydroboration and carboboration of unbiased electronically internal alkynes were realized via a nickel catalysis system with the aid of the directing group strategy. Furthermore, the excellent α- and β-regioselectivity could be accurately switched by the nitrogen ligand (terpy) and phosphine ligand (Xantphos). Mechanistic studies provided an insight into the rational

  在导向基团策略的帮助下，通过镍催化系统实现了无偏电子内部炔烃的前所未有的区域选择性反式硼氢化和碳硼化。此外，优异的α-和β-区域选择性可以通过氮配体（terpy）和膦配体（Xantphos）精确切换。机理研究提供了对烯基镍物种顺式-反式异构化的合理反应过程的深入了解。这种转变不仅扩大了过渡金属催化的内部炔烃硼化反应的范围，而且更特别地描绘了导向基团策略在未活化炔烃选择性官能化方面的广阔前景。
• Regiospecific Synthesis of Novel Cyclic Nitrostyrenes and 3-Substituted 2-Nitronaphthalenes
  作者：László Kürti、Craig Keene

  DOI：10.1055/s-0033-1338867

  日期：——

  A two-step, practical, regiospecific, and readily scalable benzannulation protocol for the preparation of novel 3-alkyl- and 3-aryl-substituted 2-nitronaphthalenes is disclosed. Addition of a beta-nitrostyrene or nitroalkene to a solution of freshly prepared lithiated o-tolualdehyde tert-butyl imine first leads to the formation of a nitronate, via rapid 1,4-addition, then an intramolecular aza-Henry reaction takes place to afford a six-membered carbocycle. Subsequent treatment of the reaction mixture with aqueous acid affords novel substituted cyclic nitrostyrenes that can be conveniently aromatized via a one-pot radical-induced bromination and elimination sequence to furnish the corresponding 3-alkyl- or 3-aryl-2-nitronaphthalenes in excellent yields. The straightforward syntheses of 2-aminonaphthalenes, substituted BINAMs, 2-naphthols as well as tricyclic fused 1,2,3-triazoles are also described.
• <b>New Heteroaromatic Compounds. XVIII.</b>¹ <b>Boron-Containing Analogs of Benz[a]anthracene</b>²
  作者：Michael J. S. Dewar、Werner H. Poesche

  DOI：10.1021/ja00898a014

  日期：1963.8