3',6'-Bis(ethylamino)-2',7'-dimethyl-2-(methylamino)spiro[isoindole-3,9'-xanthene]-1-one | 1151831-69-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 3',6'-Bis(ethylamino)-2',7'-dimethyl-2-(methylamino)spiro[isoindole-3,9'-xanthene]-1-one
• 英文别名: 3',6'-bis(ethylamino)-2',7'-dimethyl-2-(methylamino)spiro[isoindole-3,9'-xanthene]-1-one
• CAS: 1151831-69-4
• 化学式: C₂₇H₃₀N₄O₂
• 分子量: 442.561
• InChiKey: XWVMSHQTWNANLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  33
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  65.6
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  rhodamine 6G 、 甲基肼 以 乙醇 为溶剂， 反应 12.0h， 以78%的产率得到3',6'-Bis(ethylamino)-2',7'-dimethyl-2-(methylamino)spiro[isoindole-3,9'-xanthene]-1-one
  参考文献：
  名称：

  Fluorescent and colorimetric detection of acid vapors by using solid-supported rhodamine hydrazides

  摘要：

  Rhodamine hydrazide-based chemosensors that can detect volatile acidic gases in solid state have been developed. The rhodamine hydrazide probes adsorbed on filter paper respond fluorescently and colorimetrically only to volatile acidic gases but nor to organic bases nor to other volatile organic compounds (VOCs). Diethyl chlorophosphate (DCP), one of model compounds used for the studies of chemical Warfare Agent (CWA), could also be detected by using this method. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.087

文献信息

• Fluorescent and colorimetric detection of acid vapors by using solid-supported rhodamine hydrazides
  作者：Shincheol Kang、Sungwook Kim、Young-Keun Yang、Shinhyo Bae、Jinsung Tae

  DOI：10.1016/j.tetlet.2009.02.087

  日期：2009.4

  Rhodamine hydrazide-based chemosensors that can detect volatile acidic gases in solid state have been developed. The rhodamine hydrazide probes adsorbed on filter paper respond fluorescently and colorimetrically only to volatile acidic gases but nor to organic bases nor to other volatile organic compounds (VOCs). Diethyl chlorophosphate (DCP), one of model compounds used for the studies of chemical Warfare Agent (CWA), could also be detected by using this method. (C) 2009 Elsevier Ltd. All rights reserved.