N,N'-Di-2-naphthylethylendiamin | 75188-95-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-Di-2-naphthylethylendiamin
• 英文别名: N,N'-Dinaphth-2-yl-ethylendiamin；N,N'-di-[2]naphthyl-ethylenediamine；N,N'-Di-[2]naphthyl-aethylendiamin；N.N'-Di-β-naphthyl-aethylendiamin；NoName_3921；N,N'-dinaphthalen-2-ylethane-1,2-diamine
• CAS: 75188-95-3
• 化学式: C₂₂H₂₀N₂
• 分子量: 312.414
• InChiKey: UQNYJPVIIOGVSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-溴丁酰溴 、 N,N'-Di-2-naphthylethylendiamin 在 苯 作用下， 生成 1,2-bis-[(2-bromo-butyryl)-[2]naphthyl-amino]-ethane
  参考文献：
  名称：

  Bischoff; Hausdoerfer, Chemische Berichte, 1892, vol. 25, p. 3255

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二溴乙烷 、 2-萘胺 在 sodium carbonate 作用下， 生成 N,N'-Di-2-naphthylethylendiamin 、 N,N'-di(2-naphthyl)piperazine
  参考文献：
  名称：

  Bischoff; Hausdoerfer, Chemische Berichte, 1890, vol. 23, p. 1998

  摘要：

  DOI：

文献信息

• Crown architecture in Quercus petraea and Q. robur: the fate of buds and shoots in relation to age, position and environmental perturbation
  作者：G.H. Bicl-Sorlin

  DOI：10.1093/forestry/73.4.331

  日期：2000.4.1

  Shoot and bud dynamics of peripheral crown portions of mature pedunculate and sessile oak trees ( Quercus robur L., Q. petraea (Matt.) Liebl.) were monitored over almost three vegetation periods. The formation and shedding of buds and extension units (eus) was mapped in the form of simplified drawings. Branches were additionally subjected to manipulative treatments simulating herbivore (defoliation at different times, loss of certain bud types) and abiotic damage (artificial acid rain) and the effects on branch architecture analysed. Branch characteristics, such as branching order and age structure, had a large influence on the growth and dynamics of peripheral branch portions, even greater than that of the manipulative treatments, with the exception of spring defoliation and shoot tip removal, which led to increased shoot shedding. In order to quantify the observed changes in crown structure with time, new measures were introduced: the shedding ratio corresponds to the number of shed eus divided by the total number of eus present and produced since a given starting point. The vitality ratio was defined as the total number of eus produced in 1 year, divided by the total number of eus shed during the same time. The vitality ratio could thus be – on a small scale – the quantitative measure of Roloff's vitality classes (Roloff, 1987, 1988, 1989).

  成熟的白栎（Quercus robur L.）和山栎（Q. petraea (Matt.) Liebl.）树木周边树冠部分的抽枝和芽动态在近三个生长季内进行了监测。芽的形成和脱落以及延伸单位（eu）的变化以简化的图形形式进行了记录。枝条还受到模拟 herbivore（在不同时间进行的落叶、某些芽类型的丧失）和非生物损伤（人工酸雨）的操作性处理，并分析了对枝条结构的影响。枝条特征，如分枝顺序和年龄结构，对周边枝条部分的生长和动态有很大影响，甚至超过了操作性处理的影响，春季落叶和顶芽去除除外，这两者导致了芽的脱落增加。为了定量观察到的树冠结构随时间变化的新措施被提出：脱落比率对应于脱落的eu数量与自给定起点以来存在和产生的eu总数的比值。活力比率被定义为在1年内产生的eu总数除以同一时间内脱落的eu总数。因此，活力比率可以在小范围内作为Roloff的活力等级的定量衡量标准（Roloff, 1987, 1988, 1989）。
• Bischoff, Chemische Berichte, 1898, vol. 31, p. 3246
  作者：Bischoff

  DOI：——

  日期：——
• 201. Some compounds related to the aromatic “nitrogen mustards.”
  作者：George A. R. Kon、John J. Roberts

  DOI：10.1039/jr9500000978

  日期：——
• Bischoff; Trapesonzjanz, Chemische Berichte, 1892, vol. 25, p. 2932
  作者：Bischoff、Trapesonzjanz

  DOI：——

  日期：——
• Schoenberg, Alexander; Singer, Erich; Eckert, Philipp, Chemische Berichte, 1980, vol. 113, # 8, p. 2823 - 2826
  作者：Schoenberg, Alexander、Singer, Erich、Eckert, Philipp

  DOI：——

  日期：——