benzil-bis-(O-methyl-seqtrans-oxime ) | 97767-22-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: benzil-bis-(O-methyl-seqtrans-oxime )
• 英文别名: benzil-bis-(O-methyl oxime )；Benzil-bis-(O-methyl-seqtrans-oxim)；Benzil-bis-(O-methyl-oxim)；Benzildioxim-dimethylether；(E)-N,N'-dimethoxy-1,2-diphenylethane-1,2-diimine
• CAS: 97767-22-1
• 化学式: C₁₆H₁₆N₂O₂
• 分子量: 268.315
• InChiKey: IUKKYBJRHHLYIR-YTEMWHBBSA-N

物化性质

• 沸点：
  367.5±25.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  benzil-bis-(O-methyl-seqtrans-oxime ) 、 氢碘酸 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1,2-二苯乙烷
  参考文献：
  名称：

  Auwers; Meyer,V., Chemische Berichte, 1888, vol. 21, p. 3517,3520

  摘要：

  DOI：
• 作为产物：
  描述：

  anti-benzildioxime-O-methylether 在 盐酸 、 乙醚 、 苯胺 、 silver(l) oxide 作用下， 生成 benzil-bis-(O-methyl-seqtrans-oxime )
  参考文献：
  名称：

  XXXI.—苯甲肟的甲基化。第二部分 苯甲二肟的单甲醚

  摘要：

  DOI：

  10.1039/jr9300000216

文献信息

• Alkyl Cobalt (III) Dioximates and process for forming the same
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP1221447A2

  公开（公告）日：2002-07-10

  This invention is directed to alkyl cobalt (III) dioximates and methods for making these dioximates. The alkyl cobalt (III) dioximate has the following structural formula: wherein R1, and R2 are individually selected from the following group: H, alkyl having at least 2 carbon atoms, substituted alkyl, aryl, substituted aryl, COOR5, C0NR6R7, SR7, SO2R7, SO2NR5R6, SOR5, SO3R5, halogen, CCl3, CF3, COR5, CHO, CR6R7OR5, CH(OR5)(OR6), CR5(OR6)(OR7); where R5, R6, and R7 are independently selected from the following group: H, alkyl, substituted alkyl, aryl or substituted aryl and A is a substituted alkyl derived from an olefinic component and B is a component of a Lewis base and where the substituents of the substituted alkyl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, aryl, SO2-alkyl, sulfamido, and amino groups and the substituents for the substituted aryl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, alkyl, SO2-alkyl, sulfamido, and amino groups.

  本发明涉及烷基钴(III)二恶英盐和制造这些二恶英盐的方法。烷基钴（III）二噁英酸盐具有以下结构式： 其中 R1 和 R2 分别选自下组：H、至少有 2 个碳原子的烷基、取代的烷基、芳基、取代的芳基、COOR5、C0NR6R7、SR7、SO2R7、SO2NR5R6、SOR5、SO3R5、卤素、CCl3、CF3、COR5、CHO、CR6R7OR5、CH(OR5)(OR6)、CR5(OR6)(OR7)；其中 R5、R6 和 R7 独立地选自以下组别：H、烷基、取代烷基、芳基或取代芳基，A 是衍生自烯烃组分的取代烷基，B 是路易斯碱组分，其中取代烷基的取代基各自选自酯、醚、酰胺、卤素、酮、烷基或取代烷基、酰胺、卤素、酮、羟基、芳基、SO2-烷基、氨基磺酰基和氨基，取代芳基的取代基分别选自酯、醚、酰胺、卤素、酮、羟基、烷基、SO2-烷基、氨基磺酰基和氨基。
• Alkyl cobalt (III) dioximates and process for forming the same
  申请人：——

  公开号：US20020087006A1

  公开（公告）日：2002-07-04

  This invention is directed to alkyl cobalt (III) dioximates and methods for making these dioximates. The alkyl cobalt (III) dioximate has the following structural formula: 1 wherein R 1 , and R 2 are individually selected from the following group: H, alkyl having at least 2 carbon atoms, substituted alkyl, aryl, substituted aryl, COOR 5 , CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 , halogen, CCl 3 , CF 3 , COR 5 , CHO, CR 6 R 7 OR 5 , CH(OR 5 )(OR 6 ), CR 5 (OR 6 )(OR 7 ); where R 5 , R 6 , and R 7 are independently selected from the following group: H, alkyl, substituted alkyl, aryl or substituted aryl and A is a substituted alkyl derived from an olefinic component and B is a component of a Lewis base and where the substituents of the substituted alkyl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, aryl, SO 2 -alkyl, sulfamido, and amino groups and the substituents for the substituted aryl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, alkyl, SO 2 -alkyl, sulfamido, and amino groups.

  本发明涉及烷基钴(III)二恶英盐和制造这些二恶英盐的方法。烷基钴（III）二噁英酸盐的结构式如下： 1 其中 R 1 和 R 2 分别选自以下组别：H、至少有 2 个碳原子的烷基、取代的烷基、芳基、取代的芳基、 COOR 5 、CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 卤素、CCl 3 、CF 3 COR 5 CHO, CR 6 R 7 OR 5 , CH(OR 5 ）(OR 6 ）、CR 5 (OR 6 ）（或 7 ）；其中 R 5 , R 6 和 R 7 独立地选自以下基团：H、烷基、取代的烷基、芳基或取代的芳基，A 是衍生自烯烃组分的取代的烷基，B 是路易斯碱的组分，其中取代的烷基的取代基独立地选自酯、醚、酰胺、卤素、酮、羟基、芳基、SO 2 -烷基、氨基磺酰基和氨基，而取代芳基的取代基则分别选自酯、醚、酰胺、卤素、酮、羟基、烷基、SO 2 -烷基、氨基磺酰基和氨基。
• Alkyl cobalt(III) dioximates and process for forming the same
  申请人：——

  公开号：US20030135054A1

  公开（公告）日：2003-07-17

  This invention is directed to alkyl cobalt (III) dioximates and methods for making these dioximates. The alkyl cobalt (III) dioximate has the following structural formula: 1 wherein R 1 , and R 2 are individually selected from the following group: H, alkyl having at least 2 carbon atoms, substituted alkyl, aryl, substituted aryl, COOR 5 , CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 , halogen, CCl 3 , CF 3 , COR 5 , CHO, CR 6 R 7 OR 5 , CH(OR 5 )(OR 6 ), CR 5 (OR 6 )(OR 7 ); where R 5 , R 6 , and R 7 are independently selected from the following group: H, alkyl, substituted alkyl, aryl or substituted aryl and A is a substituted alkyl derived from an olefinic component and B is a component of a Lewis base and where the substituents of the substituted alkyl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, aryl, SO 2 -alkyl, sulfamido, and amino groups and the substituents for the substituted aryl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, alkyl, SO 2 -alkyl, sulfamido, and amino groups.

  本发明涉及烷基钴(III)二恶英盐和制造这些二恶英盐的方法。烷基钴（III）二噁英酸盐的结构式如下： 1 其中 R 1 和 R 2 分别选自以下组别：H、至少有 2 个碳原子的烷基、取代的烷基、芳基、取代的芳基、 COOR 5 、CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 卤素、CCl 3 、CF 3 COR 5 CHO, CR 6 R 7 OR 5 , CH(OR 5 ）(OR 6 ）、CR 5 (OR 6 ）（或 7 ）；其中 R 5 , R 6 和 R 7 独立地选自以下基团：H、烷基、取代的烷基、芳基或取代的芳基，A 是衍生自烯烃组分的取代的烷基，B 是路易斯碱的组分，其中取代的烷基的取代基独立地选自酯、醚、酰胺、卤素、酮、羟基、芳基、SO 2 -烷基、氨基磺酰基和氨基，而取代芳基的取代基则分别选自酯、醚、酰胺、卤素、酮、羟基、烷基、SO 2 -烷基、氨基磺酰基和氨基。
• Reduction of oximes, oxime ethers, and oxime esters with diborane. Novel synthesis of amines
  作者：Henry Feuer、D. M. Braunstein

  DOI：10.1021/jo01258a062

  日期：1969.6
• Brady; Perry, Journal of the Chemical Society, 1925, vol. 127, p. 2876
  作者：Brady、Perry

  DOI：——

  日期：——