2-氯十一烷 | 61539-83-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 2-氯十一烷
• 英文名称: 2-chloroundecane
• 英文别名: 2-chloro-undecane；2-Chlor-undecan
• CAS: 61539-83-1
• 化学式: C₁₁H₂₃Cl
• 分子量: 190.757
• InChiKey: HQVPSRJKEWDSPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-氯十一烷 在 三乙基硅烷 、 2,6-双(2-苯并咪唑基)吡啶 、 bis(1,5-cyclooctadiene)diiridium(I) dichloride 作用下， 反应 24.0h， 以91%的产率得到十一烷
  参考文献：
  名称：

  使用铱/双（苯并咪唑-2'-基）吡啶催化剂和三乙基硅烷催化还原烷基氯的新方案

  摘要：

  研究了使用三乙基硅烷还原烷基氯。使用 [IrCl(cod)]2/2,6-双（苯并咪唑-2'-基）吡啶催化剂体系，一级、二级、三级和苄基 C-Cl 键可有效转化为 C-H 键。这种催化剂体系非常简单，因为三齿 N-配体可以很容易地从市售试剂一步制备。

  DOI：

  10.1055/a-1527-4526
• 作为产物：
  描述：

  2-十一酮 在 盐酸 、 乙醚 、 sodium 作用下， 生成 2-氯十一烷
  参考文献：
  名称：

  Houben; Boedler; Fischer, Chemische Berichte, 1936, vol. 69, p. 1782

  摘要：

  DOI：

文献信息

• Functional transformation of aldehydes and ketones via homolytic induced decomposition of unsaturated peroxy acetals and peroxy ketals
  作者：L. Moutet、D. Bonafoux、M. Degueil-Castaing、B. Maillard

  DOI：10.1039/a808418a

  日期：——

  Induced decomposition of unsaturated peroxy acetals prepared from trimethyl orthoformate, dodecanal or 2-methylundecanal and 2,3-dimethyl-2-hydroperoxybut-3-ene, in the presence of ethyl iodoacetate, CCl4 or dodecanethiol, allowed respectively their iodo-, chloro- and hydro- decarbonylation with yields of over 70%; the same reaction applied to the monoperoxy ketal or diperoxy ketal of cyclohexanone in the presence of ethyl iodoacetate resulted in its functional transformation in methyl 6-iodohexanoate or 1,5-diiodopentane with respective yields of 65 and 40%.

  通过三甲基原甲酸酯、十二醛或2-甲基十一醛和2,3-二甲基-2-羟过氧丁-3-烯在乙基碘乙酸酯、CCl4或十二硫醇的存在下引发的未饱和过氧缩醛的分解反应，分别实现了它们的碘代、氯代和羟基脱羰反应，产率均超过70%；同样的反应在乙基碘乙酸酯存在下应用于环己酮的单过氧缩酮或双过氧缩酮，分别得到了甲基6-碘己酸酯或1,5-二碘戊烷，产率分别为65%和40%。
• Intramolecular Homolytic Displacements. 30. Functional Decarbonylative Transformations of Aldehydes via Homolytically Induced Decomposition of Unsaturated Peroxyacetals
  作者：Marie Degueil-Castaing、Laurent Moutet、Bernard Maillard

  DOI：10.1021/jo9918495

  日期：2000.6.1

  Homolytically induced decompositions of unsaturated peroxyacetals, synthesized from aldehydes, gave alkoxyalkoxyl radicals that yielded alkyl radicals by rapid beta-scission. The latter radicals could react with several types of "transfer agents" to smoothly bring about homolytic decarbonylative functional group transformations of aldehydes into halides, hydrocarbons, xanthates, alkanenitriles, 2-

  由醛合成的不饱和过氧缩醛的均相诱导分解产生了烷氧基烷氧基，该烷氧基通过快速的β断裂产生了烷基。后者可以与几种类型的“转移剂”发生反应，从而平稳地将醛类的均相脱羰基官能团转化为卤化物，烃，黄原酸酯，链烷腈，2-烷基-3-氯马来酸酐，1-苯基烷-1-炔，和2-烷基丙烯酸乙酯。
• METHOD FOR PRODUCING REDUCED HALIDE COMPOUND HAVING UNDERGONE REDUCTION OF CARBON-CARBON UNSATURATED BOND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190322607A1

  公开（公告）日：2019-10-24

  A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.

  一种卤化物化合物，其具有一个或多个碳-碳不饱和键，经催化还原而几乎不发生去卤反应，以产生一个减少的卤化物化合物，其中至少一个或多个不饱和键被还原。具体提供了一种生产减少的卤化物化合物的方法，包括以下步骤：在溶剂中反应镍化合物、锌化合物和硼氢化物化合物以获得还原催化剂；并在还原催化剂存在的情况下，将具有一个或多个碳-碳不饱和键的卤化物化合物进行催化还原，以减少至少一个或多个碳-碳不饱和键，从而获得减少的卤化物化合物。
• Method for producing reduced halide compound having undergone reduction of carbon-carbon unsaturated bond
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10676417B2

  公开（公告）日：2020-06-09

  A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.

  具有一个或多个碳-碳不饱和键的卤化物化合物在催化还原过程中基本上不发生脱卤反应，从而产生一种还原型卤化物化合物，其中至少一个或多个不饱和键被还原。具体而言，提供了一种生产还原型卤化物化合物的方法，包括以下步骤：将镍化合物、锌化合物和硼氢化合物在溶剂中反应，得到还原催化剂；在还原催化剂存在下，将具有一个或多个碳碳不饱和键的卤化物化合物进行催化还原，以还原一个或多个碳碳不饱和键中的至少一个，从而得到还原型卤化物化合物。
• Compound, photocurable composition, cured product of same, printing ink, and printed matter curing the printing ink
  申请人：DIC Corporation

  公开号：US11079675B2

  公开（公告）日：2021-08-03

  A novel compound is used as a novel photopolymerization initiator, the novel compound having a molecular structure represented by general formula 1 below [R1 represents an alkyl group having 1 to 10 carbon atoms, R2 represents an alkyl group having 1 to 12 carbon atoms or the like, R3 represents an alkyl group having 1 to 12 carbon atoms or the like, R4 to R7 each independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or the like, Y1 represents an alkyl group having 3 to 19 carbon atoms or the like, Y2 represents an organic linking group, X1 represents an ethylene group or the like, X2 and X3 each represent an ethylene group or the like, Y3 represents a single bond or an alkylidene group, and n represents an integer of 1 to 3].

  一种新型化合物被用作新型光聚合引发剂，该新型化合物的分子结构如下通式 1 所示 [R1 代表具有 1 至 10 个碳原子的烷基，R2 代表具有 1 至 12 个碳原子的烷基或类似物，R3 代表具有 1 至 12 个碳原子的烷基或类似物，R4 至 R7 各自独立地代表氢原子、具有 1 至 8 个碳原子的烷基或类似物、Y1 代表具有 3 至 19 个碳原子的烷基或类似基团，Y2 代表有机连接基团，X1 代表乙烯基或类似基团，X2 和 X3 各自代表乙烯基或类似基团，Y3 代表单键或亚烷基，n 代表 1 至 3 的整数]。