7-methoxy-2-trifluoromethyl-10H-phenothiazine | 792-70-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 7-methoxy-2-trifluoromethyl-10H-phenothiazine
• 英文别名: 7-methoxy-2-trifluoromethyl-phenothiazine；7-Methoxy-2-trifluormethyl-phenothiazin；2-Trifluormethyl-7-methoxy-phenothiazin；3-Methoxy-8-trifluormethyl-phenothiazin；7-Methoxy-2-trifluormethylphenothiazin；7-Methoxy-2-(trifluoromethyl)-10H-phenothiazine；7-methoxy-2-(trifluoromethyl)-10H-phenothiazine
• CAS: 792-70-1
• 化学式: C₁₄H₁₀F₃NOS
• 分子量: 297.301
• InChiKey: ZZPLFRDQLGPMQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  46.6
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,6-bis(4-(p-tolyloxy)phenyl)-4H-pyran-4-one 、 7-methoxy-2-trifluoromethyl-10H-phenothiazine 在 三氯氧磷 作用下， 生成
  参考文献：
  名称：

  Functional Aromatic Polyethers: Polymers with Tunable Chromogenic and Fluorogenic Properties

  摘要：

  This paper describes the preparation and chemical modification of pyranone-based aromatic polyethers to yield polymers that contain pyrylium rings, which permit the design of high performance materials with "a la carte" chromogenic and fluorescence behavior. These materials can be used for innovative applications such as luminescent converter (LUCO) materials for hybrid light-emitting diodes (LEDs) or the preparation of selective chromogenic and fluorogenic sensing materials for the preparation of sensing devices. The fluorescence emission maxima of polyether films ranged from 514 to 561 nm, allowing the future development of LUCO-LED devices. Moreover, the interaction of polyether films with different amines leads to color changes and variations in the intensity and emission maxima of fluorescence, which permits the development of amine sensing materials.

  DOI：

  10.1021/ma101106a
• 作为产物：
  描述：

  3-三氟甲基-4'-甲氧基二苯基胺 在 sulfur 作用下， 生成 7-methoxy-2-trifluoromethyl-10H-phenothiazine
  参考文献：
  名称：

  Notes - New Trifluoromethylphenothiazine Derivatives

  摘要：

  DOI：

  10.1021/jo01357a618

文献信息

• Functional Aromatic Polyethers: Polymers with Tunable Chromogenic and Fluorogenic Properties
  作者：Ana Gómez-Valdemoro、Ramón Martínez-Máñez、Félix Sancenón、Félix Clemente García、José Miguel García

  DOI：10.1021/ma101106a

  日期：2010.9.14

  This paper describes the preparation and chemical modification of pyranone-based aromatic polyethers to yield polymers that contain pyrylium rings, which permit the design of high performance materials with "a la carte" chromogenic and fluorescence behavior. These materials can be used for innovative applications such as luminescent converter (LUCO) materials for hybrid light-emitting diodes (LEDs) or the preparation of selective chromogenic and fluorogenic sensing materials for the preparation of sensing devices. The fluorescence emission maxima of polyether films ranged from 514 to 561 nm, allowing the future development of LUCO-LED devices. Moreover, the interaction of polyether films with different amines leads to color changes and variations in the intensity and emission maxima of fluorescence, which permits the development of amine sensing materials.
• Notes - New Trifluoromethylphenothiazine Derivatives
  作者：Paul Craig、Edward Nodiff、John Lafferty、Glenn Ullyot

  DOI：10.1021/jo01357a618

  日期：1957.6