2-氯甲基降冰片-2-烯 | 74039-13-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 2-氯甲基降冰片-2-烯
• 英文名称: 2-Chloromethyl-2-norbornene
• 英文别名: 2-(chloromethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 74039-13-7
• 化学式: C₈H₁₁Cl
• 分子量: 142.62
• InChiKey: RDTFZLYUPAZUOE-UHFFFAOYSA-N

物化性质

• 沸点：
  173.6±19.0 °C(Predicted)
• 密度：
  1.106±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Metal complexes useful in metathesis and other reactions
  申请人：Walter Francis

  公开号：US20050043541A1

  公开（公告）日：2005-02-24

  This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

  本发明提供了金属配合物，可用作交换反应中的催化剂组分，以及涉及将原子或基团转移至乙烯基或乙炔基不饱和化合物或其他反应底物的反应中，并且针对其亚类别，用于α-烯烃和可选的共轭二烯的聚合，具有在中等温度下高活性。它还提供了通过活性反应获得非常窄的分子量分布的聚合物的方法。它还提供了制备该金属配合物和涉及这种方法的新型中间体的方法。它还提供了该金属配合物的衍生物，适用于与载体进行共价键合，该共价键合的产物可用作异相催化反应的支持催化剂。它还提供了从双烯基化合物直接合成吡咯、呋喃和噻吩化合物的一步法。
• Functional norbornenes and polymeric derivatives and fabrication thereof
  申请人：Liaw Der-Jang

  公开号：US20070173608A1

  公开（公告）日：2007-07-26

  The invention relates to functional norbornenes as initiators for radical polymerization, its polymer and fabrication method thereof. More particularly, the functional norbornenes can be selectively polymerized by ring-opening metathesis polymerization or radical polymerization to obtain various polynorbornene derivatives or grafted copolymer materials. The polynorbornene derivatives and grafted copolymer materials not only exhibit excellent functional properties but also enhanced physical and chemical properties after modification. The polynorbornene derivatives and grafted copolymer materials disclosed in the invention exhibit excellent heat resistance, transparency and water resistance. The invention also deals with a process for producing such derivatives and materials having controllable molecular weight with narrow molecular weight distribution.

  本发明涉及功能性诺伯烯作为自由基聚合引发剂、其聚合物及其制备方法。更具体地说，这些功能性诺伯烯可以通过环开开环重聚合或自由基聚合选择性地聚合，以获得各种聚诺伯烯衍生物或接枝共聚物材料。这些聚诺伯烯衍生物和接枝共聚物材料不仅表现出优异的功能性能，而且在改性后还表现出增强的物理和化学性能。本发明所披露的聚诺伯烯衍生物和接枝共聚物材料表现出极佳的耐热性、透明度和耐水性。本发明还涉及一种生产这些衍生物和材料的方法，该方法具有可控的分子量和窄分子量分布。
• GATE INSULATOR LAYER FOR ORGANIC ELECTRONIC DEVICES
  申请人：Mueller David Christoph

  公开号：US20120056183A1

  公开（公告）日：2012-03-08

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as gate insulator layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin gate insulator and processes for preparing such polycycloolefin gate insulator layers and electronic devices encompassing such layers.

  本发明实施例提供了在电子设备中使用多环烯烃的方法，更具体地，提供了使用此类多环烯烃作为电子设备制造中用于制造栅绝缘层的栅绝缘层的方法，以及包括此类多环烯烃栅绝缘层的电子设备和制备此类多环烯烃栅绝缘层和包括此类层的电子设备的工艺。
• INTERLAYER FOR ELECTRONIC DEVICES
  申请人：Mueller David Christoph

  公开号：US20120056249A1

  公开（公告）日：2012-03-08

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as interlayers applied to fluoropolymer layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin interlayers and processes for preparing such polycycloolefin interlayers and electronic devices.

  本发明的实施例提供了在电子设备中使用多环氧烷烃的方法，更具体地，是将这种多环氧烷烃用作在制造电子设备时应用于氟聚合物层的中间层，包括这种多环氧烷烃中间层的电子设备以及制备这种多环氧烷烃中间层和电子设备的方法。
• Co-polymer-bound amine antioxidants
  申请人：HERCULES INCORPORATED

  公开号：EP0331074A2

  公开（公告）日：1989-09-06

  An improved amine-containing antioxidant compound for stabilizing the polymeric products of ring-opening metathesis-catalyst-polymerization of the norbornene-type monomer reactions described above, and that effectively delays degradation by olefin oxidation of physical properties as well as avoiding discoloration of such polymeric products and discoloration of surface coatings applied for aesthetic purposes, and its use as a comonomer in a ring-opening metathesis-catalyst-polymerization of a norbornene-type monomer that undergoes ring-opening polymerization in the presence of a metathesis catalyst are disclosed.

  一种改进的含胺抗氧化剂化合物，用于稳定上述降冰片烯类单体反应的开环偏聚催化剂聚合反应的聚合物产物，并能有效延缓物理性能因烯烃氧化而降解，以及避免此类聚合物产物变色和为美观目的而使用的表面涂层变色、本发明还公开了其在降冰片烯类单体的开环偏合成催化剂聚合反应中作为共聚单体的用途，该单体在偏合成催化剂存在下进行开环聚合反应。