10-Mesitylphenothiazine 5,5-dioxide | 888009-07-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-Mesitylphenothiazine 5,5-dioxide
• 英文别名: 10-(2,4,6-Trimethylphenyl)phenothiazine 5,5-dioxide
• CAS: 888009-07-2
• 化学式: C₂₁H₁₉NO₂S
• 分子量: 349.453
• InChiKey: ZRLFZUCTNARICK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  10-mesityl-10H-phenothiazine 在 盐酸 、 间氯过氧苯甲酸 作用下， 以 氢氧化钾 、 二氯甲烷 为溶剂， 生成 10-Mesitylphenothiazine 5,5-dioxide
  参考文献：
  名称：

  Phenothiazines, S-Oxides, And S,S-Dioxides As Well As Phenoxazines As Emitters For Oleds

  摘要：

  使用苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为有机发光二极管中的发射物质，一种有机发光二极管包括一个发光层，该发光层至少包括一种苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质，以及一个包含或由上述苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质的发光层，一个包含或由上述苯氧嗪衍生物、苯噻嗪衍生物、苯噻嗪S-氧化物衍生物或苯噻嗪S,S-二氧化物衍生物的空穴和激子阻挡层，以及包含创新有机发光二极管的器件。本发明还涉及特定的苯噻嗪S,S-二氧化物衍生物、苯噻嗪S-氧化物衍生物和苯噻嗪衍生物及其生产工艺，以及它们在有机发光二极管中的使用。

  公开号：

  US20100308714A1

文献信息

• Use Of Phenothiazine-S-Oxides And Phenothiazine -S,S-Dioxides In The Form Of Matrix Materials For Organic Light-Emitting Diodes
  申请人：Gessner Thomas

  公开号：US20080018238A1

  公开（公告）日：2008-01-24

  The present invention relates to the use of phenothiazine S-oxides and S,S-dioxides as matrix materials for organic light-emitting diodes, in particular as matrix materials in the light-emitting layer of the organic light-emitting diodes, to organic light-emitting diodes comprising a light-emitting layer which comprises at least one phenothiazine S-oxide or S,S-dioxide as a matrix material and at least one further substance distributed therein as an emitter, to light-emitting layers which comprise at least one phenothiazine S-oxide or S,S-dioxide as a matrix material and at least one substance distributed therein as an emitter, to light-emitting layers which consist of one or more phenothiazine S-oxides or S,S-dioxides as a matrix material and at least one further substance distributed therein as a matrix material, to organic light-emitting diodes which comprise corresponding light-emitting layers, and to devices which comprise corresponding organic light-emitting diodes.

  本发明涉及使用苯并噻嗪S-氧化物和S,S-二氧化物作为有机发光二极管的基质材料，特别是作为有机发光二极管的发光层中的基质材料，涉及包含至少一种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为发射体的其他物质的发光层的有机发光二极管，涉及包含至少一种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为发射体的其他物质的发光层，涉及由一种或多种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为基质材料的其他物质组成的发光层，涉及包括相应发光层的有机发光二极管，以及涉及包括相应有机发光二极管的设备。
• POLYMER COMPOUND AND POLYMER LIGHT EMITTING DEVICE USING THE SAME
  申请人：Kobayashi Satoshi

  公开号：US20100286360A1

  公开（公告）日：2010-11-11

  A polymer compound comprising a residue of a compound of the following formula (1): (wherein, a ring C 1 , ring C 2 and ring C 3 represent each independently an aromatic hydrocarbon ring or hetero ring. A 1 represents a di-valent group containing one or more atoms selected from a boron atom, carbon atom, nitrogen atom, oxygen atom, phosphorus atom, sulfur atom and selenium atom. R 1 represents an alkyl group, alkoxy group, alkylthio group, aryl group, aryloxy group, arylthio group, arylalkyl group, arylalkyloxy group, arylalkylthio group, alkenyl group, alkynyl group, di-substituted amino group, tri-substituted silyl group, acyl group, acyloxy group, imine residue, amide group, acid imide group, mono-valent heterocyclic group, substituted carboxyl group, heteroaryloxy group or heteroarylthio group, or is connected to an atom adjacent to an atom on the ring C 3 to which R 1 is connected, to form a ring.).
• US8029919B2
  申请人：——

  公开号：US8029919B2

  公开（公告）日：2011-10-04
• Phenothiazines, S-Oxides, And S,S-Dioxides As Well As Phenoxazines As Emitters For Oleds
  申请人：Gessner Thomas

  公开号：US20100308714A1

  公开（公告）日：2010-12-09

  The use of phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivatives as emitter substances in organic light-emitting diodes, an organic light-emitting diode comprising a light-emitting layer, the light-emitting layer comprising at least one phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, and a light-emitting layer comprising or consisting of the aforementioned phenoxazine, phenothiazine-phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, a hole- and exciton-blocking layer comprising or consisting of the aforementioned phenoxazine derivative, phenothiazine derivative, phenothiazine S-oxide derivative or phenothiazine S,S-dioxide derivative, and a device which comprises an inventive organic light-emitting diode. The present invention further relates to specific phenothiazine S,S-dioxide derivatives, phenothiazine S-oxide derivatives and phenothiazine derivatives and production processes thereof, and to their use in organic light-emitting diodes.

  使用苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为有机发光二极管中的发射物质，一种有机发光二极管包括一个发光层，该发光层至少包括一种苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质，以及一个包含或由上述苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质的发光层，一个包含或由上述苯氧嗪衍生物、苯噻嗪衍生物、苯噻嗪S-氧化物衍生物或苯噻嗪S,S-二氧化物衍生物的空穴和激子阻挡层，以及包含创新有机发光二极管的器件。本发明还涉及特定的苯噻嗪S,S-二氧化物衍生物、苯噻嗪S-氧化物衍生物和苯噻嗪衍生物及其生产工艺，以及它们在有机发光二极管中的使用。