N,N'-diethyl-heptane-1,7-diamine | 36823-75-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-diethyl-heptane-1,7-diamine
• 英文别名: N,N'-Diaethyl-1,7-heptandiamin；N,N'-Diethyl-1,7-diaminoheptan；1,7-Bis-aethyl-amino-heptan；N,N'-diethylheptane-1,7-diamine
• CAS: 36823-75-3
• 化学式: C₁₁H₂₆N₂
• 分子量: 186.341
• InChiKey: DXVRWLSEDKIGGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二氯乙酰氯 、 N,N'-diethyl-heptane-1,7-diamine 生成 1,7-Bis--heptan
  参考文献：
  名称：

  The Preparation and Biological Activity of some N,N'-Bis(haloacyl)-polymethylenediamines

  摘要：

  DOI：

  10.1021/jm50016a002
• 作为产物：
  描述：

  1,7-二氨基庚烷 在 吡啶 、 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以 乙醚 为溶剂， 生成 N,N'-diethyl-heptane-1,7-diamine
  参考文献：
  名称：

  Der [M + 11] + -Pick in Mass Masspeperen von Diaminen 38. Mitteilungübermassenspektrometrische Untersuchungen †

  摘要：

  二胺类质谱中的[M + U] + -峰

  DOI：

  10.1002/hlca.19820650521

文献信息

• N,N'-Heptamethylenebis(4-methoxybenzamide)
  申请人：Sterling Drug Inc.

  公开号：US04009208A1

  公开（公告）日：1977-02-22

  4-(Q-O)-4'-R.sub.1 -N,N'-alkylenebis(benzamides), N,N'-alkylenebis(3,4-methylenedioxybenzamides) or N,N'-alkylenebis[4-(lower-alkoxy)benzamides], having endocrinological properties, where Q is lower-alkyl, lower-alkoxyalkyl, lower-alkenyl, halo-lower-alkyl, halo-lower-alkenyl, lower-cycloalkyl, phenyl and BN-(lower-alkyl) where BN is di-(lower-alkyl)amino or a saturated N-heteromonocyclic radical having from five to seven ring atoms and alkylene has at least five carbon atoms between its two connecting linkages and R.sub.1 is Q-O-, hydrogen, lower-alkoxy, lower-alkyl, halo, benzyloxy, hydroxy, di-(lower-alkyl)amino, nitro, amino or trihalomethyl are prepared preferably by reacting the appropriate diamine or N-(aminoalkyl)-benzamide with two or one molar equivalents, respectively, of the appropriate benzoyl halide.

  4-(Q-O)-4'-R.sub.1 -N,N'-烷基亚苯二酰胺，N,N'-烷基亚苯二酰胺或N,N'-烷基亚苯二酰胺[4-(较低烷氧基)苯二酰胺]，具有内分泌学性质，其中Q为较低烷基，较低烷氧基烷基，较低烯基，卤代较低烷基，卤代较低烯基，较低环烷基，苯基和BN-(较低烷基)，其中BN为二(较低烷基)氨基或具有五至七个环原子的饱和N-杂环烷基基团，烷基在其两个连接链之间至少有五个碳原子，R.sub.1为Q-O-，氢，较低烷氧基，较低烷基，卤素，苄氧基，羟基，二(较低烷基)氨基，硝基，氨基或三卤甲基，最好通过将适当的二胺或N-(氨基烷基)-苯二酰胺与相应的苯甲酰卤反应制备两个或一个摩尔当量。
• Synthesis of N,N'-Disubstituted α,ω-Alkanediamines, Precursors of Linear<i>bis</i>Dithiocarbamates
  作者：Pascale Giboreau、Christophe Morin、Michel Vidal

  DOI：10.1080/00397919608003643

  日期：1996.2

  Abstract Linear bis dithiocarbamates are conveniently obtained from symmetrical disubstituted α,ω-alkanediamines whose preparation is reported.

  摘要 线性双二硫代氨基甲酸酯可方便地从对称双取代的 α,ω-链烷二胺获得，其制备方法已有报道。
• Internal release agent, composition including internal release agent, and process for producing a plastic lens using same composition
  申请人：MITSUI CHEMICALS, INC.

  公开号：US10239239B2

  公开（公告）日：2019-03-26

  An internal release agent includes at least one phosphodiester represented by the following general formula (1). In the formula, R1 and R2 independently represent a hydrocarbon group having 1 to 30 carbon atoms, which is optionally substituted with at least one hydroxyl group, and R3 represents an alkylene group having 2 to 4 carbon atoms. A plurality of R3's may be the same as or different from each other. M represents a hydrogen atom, an ammonium ion, an alkali metal ion, or a monovalent/divalent alkali earth metal ion, and n is an integer of 1 to 60.

  内部释放剂至少包括一个由以下一般式（1）表示的磷酸二酯。在该式中，R1和R2分别表示具有1至30个碳原子的烃基，该烃基可以选择性地取代至少一个羟基，而R3表示具有2至4个碳原子的烷基基团。多个R3可以相同或者彼此不同。M代表氢原子、铵离子、碱金属离子或者一价/二价碱土金属离子，n为1至60的整数。
• Polymerizable composition and process for producing optical resin comprising the same
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1058133A2

  公开（公告）日：2000-12-06

  A polymerizable composition according to the present invention is characterized by that it comprises a compound (a) having at least one structure represented by the following formula (1): wherein R1 is a divalent hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each independently represents a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom; X stands for an S or O atom and the average number of S atom is at least 50% based on the total number of S and O atoms which consist of the three membered ring; and X' is -S- or -O-, at least two compounds (b) having a tertiary amino group substituted with aliphatic and/or aromatic group(s), which are each different in catalytic activity as a polymerization catalyst, with the proviso that the ratio of the total of the tertiary amino groups in the at least two compounds (b) to the episulfide groups in compound (a) is in the range of 0.0001 to 0.02 in terms of a molar ratio of amino/episulfide functional group.

  根据本发明的一种可聚合组合物，其特征在于它包括至少一种具有下式（1）所代表结构的化合物（a）： 其中 R1 是具有 1 至 10 个碳原子的二价烃基，R2、R3 和 R4 各自独立地代表具有 1 至 10 个碳原子的烃基或氢原子；X 代表 S 原子或 O 原子，S 原子的平均数目至少占组成三元环的 S 原子和 O 原子总数的 50%；X'是-S-或-O-、 至少两种具有被脂肪族和/或芳香族基团取代的叔氨基的化合物 (b)，它们作为聚合催化剂的催化活性各不相同、 但以氨基/环硫官能团的摩尔比计，至少两种化合物（b）中的叔氨基与化合物（a）中的环硫官能团的总和之比范围为 0.0001 至 0.02。
• THIOEPOXY BASED POLYMERIZABLE COMPOSITION AND METHOD FOR PRODUCTION THEREOF
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1484352A1

  公开（公告）日：2004-12-08

  A polymerizable composition and a manufacturing method thereof are provided, in which the composition is capable of meeting requirements of overcoming decrease in production yield of a resin composed of a thioepoxy compound, the decrease being caused by variations in refractive index, hue, and optical strain. In a polymerizable composition containing a compound having at least one structure represented by the above formula (where R1 represents a hydrocarbon having 1 to 10 carbon atoms, R2, R3, and R4 each represent a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom.), the total of a thioepoxy compound A, which has at least one structure represented by formula (2) and at least one structure represented by formula (3), and a thioepoxy compound B, which has at least one structure represented by formula (4) and at least one structure represented by formula (3), is 4 mass percent or less with respect to the total mass of the polymerizable composition. A polymerizable composition and a manufacturing method thereof are provided, in which the composition is capable of meeting requirements of overcoming decrease in production yield of a resin composed of a thioepoxy compound, the decrease being caused by variations in refractive index, hue, and optical strain. In a polymerisable composition containing a compound having at least one structure represented by the above formula (where R1 represents a hydrocarbon having 1 to 10 carbon atoms, R2, R3, and R4 each represent a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom.), the total of a thioepoxy compound A, which has at least one structure represented by formula (2) and at least one structure represented by formula (3), and a thioepoxy compound B, which has at least one structure represented by formula (4) and at least one structure respresented by formula (3), is 4 mass precent or less with respect to the total mass of the polymerizable composition.

  本发明提供了一种可聚合组合物及其制造方法，其中的组合物能够满足克服由硫环氧化合物组成的树脂产量下降的要求，这种下降是由折射率、色调和光学应变的变化引起的。 在含有至少一种具有上式结构的化合物的可聚合组合物中（其中 R1 代表具有 1 至 10 个碳原子的烃，R2、R3 和 R4 分别代表具有 1 至 10 个碳原子的烃基或氢原子。)，硫环氧化合物 A（至少具有一种由式（2）表示的结构和至少一种由式（3）表示的结构）和硫环氧化合物 B（至少具有一种由式（4）表示的结构和至少一种由式（3）表示的结构）的总质量占可聚合组合物总质量的 4%或更少。 本发明提供了一种可聚合组合物及其制造方法，其中的组合物能够满足克服由硫环氧化合物组成的树脂产量下降的要求，这种下降是由折射率、色调和光学应变的变化引起的。 在含有至少一种具有上式结构的化合物的可聚合组合物中（其中 R1 代表具有 1 至 10 个碳原子的烃，R2、R3 和 R4 分别代表具有 1 至 10 个碳原子的烃基或氢原子。)，硫环氧化合物 A（至少具有一种由式（2）表示的结构和至少一种由式（3）表示的结构）和硫环氧化合物 B（至少具有一种由式（4）表示的结构和至少一种由式（3）表示的结构）的总质量占可聚合组合物总质量的 4%或更少。