Aziridin-2-ylmethyl-diethyl-amine | 88419-34-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Aziridin-2-ylmethyl-diethyl-amine
• 英文别名: N-[(Aziridin-2-yl)methyl]-N-ethylethanamine；N-(aziridin-2-ylmethyl)-N-ethylethanamine
• CAS: 88419-34-5
• 化学式: C₇H₁₆N₂
• 分子量: 128.217
• InChiKey: QUDGZNRNVGBOPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,N-diethylaziridine-2-carboxamide 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 30.0h， 以75%的产率得到Aziridin-2-ylmethyl-diethyl-amine
  参考文献：
  名称：

  Synthesis and reduction of derivatives of aziridinemono- and-dicarboxylic acids

  摘要：

  DOI：

  10.1007/bf00506885

文献信息

• BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS
  申请人：EVONIK DEGUSSA GMBH

  公开号：US20170240691A1

  公开（公告）日：2017-08-24

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R 1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R 2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein R A is substituted or unsubstituted benzyl; R B is each independently R A , or a hydrogen atom, or a group selected from C 1 -C 16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C 2 -C 10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  含有苄基曼尼希碱基组分的组合物和固化剂。所述苄基曼尼希碱基组分包括以下反应产物：(a)至少具有一个取代基的取代酚化合物，所述取代基的公式为(I)：其中R1各自独立地是具有1到4个碳原子的线性或支链烷基，R2是氢、甲基、乙基或苯基；(b)苄基化的聚烯烃聚醚胺(II)：其中RA是取代或未取代的苄基，RB各自独立地是RA或氢原子，或选自C1-C16线性、环状和支链烷基、烯基和烷基芳基基团；X、Y和Z各自独立地选自C2-C10烷基和环状烷基基团；y是0到7的整数，z是0到4的整数；可选地，(c)多功能胺。还公开了胺-环氧组合物和由这些组合物制成的物品。
• Benzylated mannich base curing agents, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10669370B2

  公开（公告）日：2020-06-02

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1-C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  包含苄化曼尼希基组合物的组合物和固化剂。苄化曼尼希基组合物包括以下物质的反应产物：(a) 具有至少一个式 (I) 取代基的取代酚化合物： 其中 R1 各自独立地为具有 1 至 4 个碳原子的直链或支链烷基，R2 为氢、甲基、乙基或苯基，与(b)苄化聚亚烷基多胺(II)的反应产物： 其中 RA 是取代或未取代的苄基；RB 各自独立地是 RA，或氢原子，或选自 C1-C16 直链、环链和支链烷基、烯基和芳烷基的基团；X、Y 和 Z 独立地选自 C2-C10 亚烷基和环亚烷基；y 是 0 至 7 的整数，z 是 0 至 4 的整数；以及，任选地，(c) 多官能胺。此外，还公开了胺环氧组合物和由这些组合物生产的物品。
• TRAPENTSIER, P. T.;KALVINSH, I. YA.;LIEPINSH, EH. EH.;LUKEVITS, EH., XIMIYA GETEROTSIKL. SOEDIN., 1983, N 9, 1227-1235
  作者：TRAPENTSIER, P. T.、KALVINSH, I. YA.、LIEPINSH, EH. EH.、LUKEVITS, EH.

  DOI：——

  日期：——
• [EN] BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS<br/>[FR] AGENTS DURCISSEURS DE TYPE BASE DE MANNICH BENZYLÉS, COMPOSITIONS ET PROCÉDÉS
  申请人：EVONIK DEGUSSA GMBH

  公开号：WO2017147138A1

  公开（公告）日：2017-08-31

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): (I) wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): (II) wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1 - C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.
• Synthesis and reduction of derivatives of aziridinemono- and-dicarboxylic acids
  作者：P. T. Trapentsier、I. Ya. Kalvin'sh、�. �. Liepin'sh、�. Lukevits

  DOI：10.1007/bf00506885

  日期：1983.9