1,3-Dihydro-3,3-dimethyl-1-benzylspiro[2H-indole-2,3'-3H-naphtho[2,1-b][1,4]oxazine] | 102224-43-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: 1,3-Dihydro-3,3-dimethyl-1-benzylspiro[2H-indole-2,3'-3H-naphtho[2,1-b][1,4]oxazine]
• 英文别名: 1-benzyl-3,3-dimethylspiro [indoline-2,3'-[3H]-naphtho[2,1-b](1,4)-oxazine]；1-benzyl-3,3-dimethylspiro[indoline-2,3'-naphtho[2,1-b](1,4)-oxazine]；1'-Benzyl-3',3'-dimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]
• CAS: 102224-43-1
• 化学式: C₂₈H₂₄N₂O
• 分子量: 404.511
• InChiKey: YVYVCXOQZYPIOP-UHFFFAOYSA-N

物化性质

• 沸点：
  617.7±55.0 °C(Predicted)
• 密度：
  1.17±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  24.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,3-Dihydro-3,3-dimethyl-1-benzylspiro[2H-indole-2,3'-3H-naphtho[2,1-b][1,4]oxazine] 以 甲苯 为溶剂， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Gautron, Rene; Eloy, Dominique; Escaffre, Pascale, Bulletin des Societes Chimiques Belges, 1991, vol. 100, # 4, p. 315 - 328

  摘要：

  DOI：
• 作为产物：
  描述：

  在 樟脑醌 作用下， 以 甲苯 为溶剂， 生成 1,3-Dihydro-3,3-dimethyl-1-benzylspiro[2H-indole-2,3'-3H-naphtho[2,1-b][1,4]oxazine]
  参考文献：
  名称：

  Eloy, D.; Escaffre, P.; Gautron, R., Journal de Chimie Physique et de Physico-Chimie Biologique, 1992, vol. 89, # 4, p. 897 - 914

  摘要：

  DOI：

文献信息

• Spiro-oxazine compounds and preparation thereof and photochromic shaped
  申请人：Toray Industries, Inc.

  公开号：US04784474A1

  公开（公告）日：1988-11-15

  A novel spiro-oxazine compound of the formula (A): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently represent hydrogen, (C1 or 2) alkyl, halogenated (C1 or 2) alkyl, (C1 or 2) alkoxy, halogen or nitro, R is unsubstituted or substituted phenyl or naphthyl, and n is 1 to 5. The spiro-oxazine compound is prepared by reacting a precursor of the spiro-oxazine compound of the formula (A), which has a substituent of the formula: --(CH.sub.2).sub.n R in the nitrogen atom of the indoline nucleus, with an .alpha.-nitroso-.beta.-naphthol. The spiro-oxazine compound is valuable as a photochromic material and exhibits enhanced fatigue resistance in photocolorability.

  一种新颖的螺环氧噁啉化合物，化学式为(A)：##STR1## 其中R.sup.1、R.sup.2、R.sup.3、R.sup.4、R.sup.5、R.sup.6和R.sup.7独立地表示氢、(C1或2)烷基、卤代(C1或2)烷基、(C1或2)烷氧基、卤素或硝基，R为未取代或取代的苯基或萘基，n为1至5。该螺环氧噁啉化合物通过将具有配体的螺环氧噁啉化合物的前体（具有式：--(CH.sub.2).sub.n R的氮原子的吲哚核）与α-亚硝基-β-萘酚反应制备而成。该螺环氧噁啉化合物作为一种光致变色材料具有价值，并且在光色可变性中表现出增强的耐疲劳性。
• Spiro-oxazine compounds and preparation thereof and photochromic shaped article
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0171909A1

  公开（公告）日：1986-02-19

  A spiro-oxazine compound of the formula (A): wherein R1, R2, R3, R4, R5, R6 and R7 independently represent hydrogen, (C1 or 2) alkyl, halogenated C1-2 alkyl, C1-2 alkoxy, halogen or nitro, R is unsubstituted or substituted phenyl or naphthyl, and n is 1 to 5, is valuable as a photochromic material and exhibits enhanced fatigue resistance in photocolorability. The spiro-oxazine compound is prepared by reacting a precursor of the spiro-oxazine compound of the formula (A), which has a substituent of the formula: -(CH2)n- R in the nitrogen atom of the indoline nucleus, with an α-nitroso-β-naphthol.

  一种式（A）的螺嗪化合物： 其中 R1、R2、R3、R4、R5、R6 和 R7 独立地代表氢、（C1 或 2）烷基、卤代 C1-2 烷基、C1-2 烷氧基、卤素或硝基，R 是未取代或取代的苯基或萘基，n 是 1 至 5，该化合物作为光致变色材料非常有价值，在光致变色性方面具有更强的抗疲劳性。 螺噁嗪化合物的制备方法是将具有以下取代基的式（A）螺噁嗪化合物前体进行反应： -(CH2)n- R 的前体与 α-亚硝基-β-萘酚反应。
• Photo reactive material
  申请人：PILKINGTON PLC

  公开号：EP0600669A1

  公开（公告）日：1994-06-08

  A photo reactive material, such as a photochromic material, which has the following structure: where Ais a six membered carbocyclic or heterocyclic ring; each Ris alkyl, alkenyl, alkynyl, aryl, carbocyclic, heterocyclic, alkyl carbocyclic or alkyl heterocyclic or at least two of the R groups together form part of a carbocyclic or heterocyclic ring or one of the R groups is hydrogen with the other two being selected from the above; R*are independent of one another and are selected from branched or linear C₁-C₁₀ alkyls and carbocyclic or heterocyclic groups or both form part of a carbocyclic or heterocyclic ring; R⁺mis selected from alkyl alkoxy, amino, halogen, cyano, nitro, trifluoromethyl or aryl and m has a value between 0 and 4; R⁺nis selected from carbocyclic and heterocyclic groups which are fused to A and n has a value between 0 and 2. R'is selected from hydrogen, alkyl, alkoxy, amino, carbocylic or heterocyclic. R''is selected from hydrogen, alkyl, aryl, heteroaryl, alkenyl, alkynyl, alkoxy, aryloxy, amino, halogen, cyano, nitro, trifluoromethyl, imino, azo, carboxy ester or amide or is a carbocyclic or heterocyclic group fused to the moiety.

  光反应材料，如光致变色材料，其结构如下： 其中 A 是六分子碳环或杂环； 每个 Ris 烷基、烯基、炔基、芳基、 碳环、杂环、烷基碳环或烷基杂环 或至少两个 R 基团共同构成碳环或杂环的一部分 或其中一个 R 基团为氢，另外两个从上述基团中选出； R* 相互独立，选自支链或线性 C₁-C₁₀烷基和碳环或杂环基团，或两个基团共同构成碳环或杂环的一部分； R⁺m 选自烷基烷氧基、氨基、卤素、氰基、硝基、三氟甲基或芳基，且 m 的值在 0 至 4 之间； R⁺n 选自与 A 融合的碳环和杂环基团，n 的值在 0 和 2 之间。 R'选自氢、烷基、烷氧基、氨基、羰基或杂环。 R''选自氢、烷基、芳基、杂芳基、烯基、炔基、烷氧基、芳氧基、氨基、卤素、氰基、硝基、三氟甲基、亚氨基、偶氮、羧基酯或酰胺，或者是与分子融合的碳环或杂环基团。
• Color changing candle
  申请人：Dragoco Gerberding & Co Aktiengesellschaft

  公开号：EP1090977A2

  公开（公告）日：2001-04-11

  A candle having a selectively and reversibly variable color pattern. In one embodiment, the candle comprises a solid transparent gel with a thermochromic or photochromic pigment dispersed evenly throughout. The candle main body changes from a first color to a second color, or from colored to transparent, or from transparent to colored, in response to heat or light from the candle flame, and reverts to the original color or absence of color upon extinguishing the flame. The candle comprises (a) a solid combustible matrix, and (b) a reversible thermochromic or photochromic composition blended into said solid combustible matrix.

  一种具有可选择、可逆变色图案的蜡烛。在一个实施方案中，蜡烛由固体透明凝胶组成，凝胶中均匀地分散着热致变色或光致变色颜料。蜡烛主体在烛焰的热量或光线作用下，从第一种颜色变为第二种颜色，或从有色变为透明，或从透明变为有色，熄灭火焰后又恢复到原来的颜色或无色。蜡烛包括 (a) 固体可燃基体，和 (b) 混入所述固体可燃基体的可逆热致变色或光致变色组合物。
• A non-glaring laminated body, a coated non-glaring laminated body, a non-glaring material, and a method for producing the non-glaring material
  申请人：MGC Filsheet Co., Ltd.

  公开号：EP1916097A2

  公开（公告）日：2008-04-30

  [Problem to be solved] The present invention provides a non-glaring material having an excellent property to cut ultraviolet rays, and having an excellent appearance and optical property as well as easy producibility and processibility, and a method for producing the non-glaring material. [Means to solve the problem] A non-glaring laminated body consisting of two transparent plastic material layers, a polarizing film layer which is held between the two transparent plastic material layers, and a synthetic adhesive layer which adheres the plastic material layer to the polarizing film layer, wherein at least one of the adhesive layers includes a fluorescent whitening agent and an ultraviolet ray absorber.

  [有待解决的问题］ 本发明提供了一种具有优异的紫外线切割性能、优异的外观和光学性能以及易于生产和加工的不刺眼材料，以及生产这种不刺眼材料的方法。 [解决问题的方法］ 一种不刺眼层压体，由两层透明塑料材料层、夹在两层透明塑料材料层之间的偏光膜层和将塑料材料层粘在偏光膜层上的合成粘合剂层组成，其中至少一层粘合剂层包括荧光增白剂和紫外线吸收剂。