dinaphtho<2,3-b:2',3'-d>thiophene | 242-53-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: dinaphtho<2,3-b:2',3'-d>thiophene
• 英文别名: dinaphtho[2,3-b:2′,3′-d]thiophene；dinaphtho[2,3-b:2',3'-d]thiophene；dinaphtho[2,3-b;2',3'-d]thiophene；Dinaphtho[2,3-b;2',3'-d]thiophen；Bisnaphthylenthiophen；Dinaphtho[2,3-b;2',3-d]thiophene；12-thiapentacyclo[11.8.0.02,11.04,9.015,20]henicosa-1(21),2,4,6,8,10,13,15,17,19-decaene
• CAS: 242-53-5
• 化学式: C₂₀H₁₂S
• 分子量: 284.381
• InChiKey: YWKFLXFRCZYQCM-UHFFFAOYSA-N

物化性质

• 熔点：
  254 °C
• 沸点：
  523.2±19.0 °C(Predicted)
• 密度：
  1.320±0.06 g/cm3(Predicted)
• 保留指数：
  495.17

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙醇 、 dinaphtho<2,3-b:2',3'-d>thiophene 、 alkaline earth salt of/the/ methylsulfuric acid 生成 2，2’-联萘酚
  参考文献：
  名称：

  Badger; Christie, Journal of the Chemical Society, 1958, p. 913

  摘要：

  DOI：
• 作为产物：
  描述：

  seriniquinone 在 氢氧化钾 、 ammonium hydroxide 、 锌 作用下， 生成 dinaphtho<2,3-b:2',3'-d>thiophene
  参考文献：
  名称：

  Wilputte; Martin, Bulletin des Societes Chimiques Belges, 1956, vol. 65, p. 874,891

  摘要：

  DOI：

文献信息

• Synthesis of Annulated Arenes and Heteroarenes by Hydriodic Acid and Red Phosphorus Mediated Reductive Cyclization of 2-(Hetero)aroylbenzoic Acids or 3-(Hetero)arylphthalides
  作者：Arasambattu Mohanakrishnan、Settu Rafiq

  DOI：10.1055/s-0036-1588337

  日期：——

  Annulated arenes and hetarenes were prepared in good to very good yields by hydriodic acid/red phosphorus mediated reductive cyclization of 3-(hetero)aryl phthalides. The reductive cyclization also proceeded successfully with 2-aroylbenzoic acids and 2-aroylnaphthoic acids.

  通过氢碘酸/红磷介导的 3-（杂）芳基苯酞的还原环化，以良好到非常好的产率制备了环化芳烃和杂环芳烃。2-芳酰基苯甲酸和2-芳酰基萘甲酸也成功地进行了还原环化。
• V-Shaped Organic Semiconductors With Solution Processability, High Mobility, and High Thermal Durability
  作者：Toshihiro Okamoto、Chikahiko Mitsui、Masakazu Yamagishi、Katsumasa Nakahara、Junshi Soeda、Yuri Hirose、Kazumoto Miwa、Hiroyasu Sato、Akihito Yamano、Takeshi Matsushita、Takafumi Uemura、Jun Takeya

  DOI：10.1002/adma.201302086

  日期：2013.11

  V‐shaped organic semiconductors have been designed and synthesized via a large‐scale applicable synthetic route. Solution‐crystallized films based on such molecules have demonstrated high‐performance transistor properties with maximum mobilities of up to 9.5 cm2 V−1 s−1 as well as pronounced thermal durability of up to 150 °C inherent in the V‐shaped cores.

  V形有机半导体已通过大规模适用的合成路线进行了设计和合成。基于这种分子的溶液结晶膜表现出高性能的晶体管特性，最大迁移率高达9.5 cm 2 V -1 s -1，V型芯固有的高达150°C的显着热耐久性。
• VISIBLE LIGHT INDUCED PHOTOGENERATION OF GROUND STATE ATOMIC OXYGEN
  申请人：Saint Louis University

  公开号：US20200346183A1

  公开（公告）日：2020-11-05

  The present invention generally relates to various polycyclic aromatic selenoxide compounds, methods for preparing these compounds, and methods of us these and other compounds to generate ground state atomic oxygen.

  本发明通常涉及各种多环芳香硒氧化物化合物，制备这些化合物的方法，以及利用这些化合物和其他化合物生成基态原子氧的方法。
• PHOTOELECTRIC CONVERSION DEVICE AND SOLAR CELL USING THE SAME
  申请人：AKIYAMA Seiji

  公开号：US20120211082A1

  公开（公告）日：2012-08-23

  There is provides a photoelectric conversion device material which can be used as an electrode buffer material for a solar cell or the like and can improve durability while maintaining the interaction with an electrode and mobility; a photoelectric conversion device using the photoelectric conversion device material; and a solar cell using the photoelectric conversion device. A photoelectric conversion device containing a buffer layer and an active layer, wherein the buffer layer contains a compound represented by the following general formula (I), the active layer contains an n-type semiconductor, and the n-type semiconductor is a compound having a solubility in toluene of 0.5% by weight or more at 25° C. and having an electron mobility of 1.0×10 −6 cm 2 /Vs or more.

  提供了一种光电转换器件材料，可用作太阳能电池或类似器件的电极缓冲材料，可以提高耐久性，同时保持与电极的相互作用和移动性；使用该光电转换器件材料的光电转换器件；以及使用该光电转换器件的太阳能电池。光电转换器件包含缓冲层和活性层，其中缓冲层包含由下列通式（I）表示的化合物，活性层包含n型半导体，且该n型半导体在25℃时在甲苯中的溶解度为0.5%或更高，并具有1.0×10−6cm2/Vs或更高的电子迁移率。
• FUSED THIOPHENE MOLECULE AND p-TYPE SEMICONDUCTOR FILM AND ELECTRONIC DEVICE
  申请人：Panasonic Intellectual Property Management Co., Ltd.

  公开号：US20210371428A1

  公开（公告）日：2021-12-02

  To provide a fused thiophene molecule having further sufficiently high hole mobility. Disclosed is a fused thiophene molecule that has seven aromatic rings containing three thiophene rings in one molecule and in which the seven aromatic rings have one or two naphthalene structures. And, semiconductor devices including a layer using the fused thiophene molecule are disclosed.

  提供一种具有更高空穴迁移率的融合噻吩分子。公开了一种融合噻吩分子，其中包含七个芳香环，其中三个噻吩环在一个分子中，并且七个芳香环具有一个或两个萘结构。此外，还公开了包括使用融合噻吩分子的层的半导体器件。