N,N,N',N'-tetrakis(biphenyl-4-yl)-3,3'-dimethyl-4,4'-diaminobiphenyl | 167218-55-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetrakis(biphenyl-4-yl)-3,3'-dimethyl-4,4'-diaminobiphenyl
• 英文别名: 2-methyl-4-[3-methyl-4-(4-phenyl-N-(4-phenylphenyl)anilino)phenyl]-N,N-bis(4-phenylphenyl)aniline
• CAS: 167218-55-5
• 化学式: C₆₂H₄₈N₂
• 分子量: 821.077
• InChiKey: QWHZGTYHJMNKTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.3
• 重原子数：
  64
• 可旋转键数：
  11
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4'-二碘-3,3'-二甲基联苯 、 二(4-联苯基)胺 在 铜 3,5-二叔丁基水杨酸 、 potassium carbonate 、 sodium hydrogensulfite 作用下， 以 正十二烷基苯 、 xylene 为溶剂， 反应 13.5h， 生成 N,N,N',N'-tetrakis(biphenyl-4-yl)-3,3'-dimethyl-4,4'-diaminobiphenyl
  参考文献：
  名称：

  METHOD OF PRODUCING AROMATIC AMINO COMPOUNDS

  摘要：

  提供一种通过使用一种主要或次要胺化合物和一种卤代芳香化合物作为起始原料，依靠乌尔曼反应来生产芳香氨基化合物的方法，该方法能够以高产率和低成本获得高纯度的芳香氨基化合物。 通过使用具有芳香环基团的主要或次要胺化合物和一种卤代芳香化合物作为起始原料，在铜催化剂和碱的存在下将胺化合物与卤代芳香化合物反应，从而产生具有芳香环基团从卤代芳香化合物衍生的结构的芳香氨基化合物，其中胺化合物和卤代芳香化合物在存在具有羟基和羟基羰基团结合到相邻碳原子的芳香氧羧酸的条件下与铜催化剂和碱一起反应。

  公开号：

  US20110257404A1

文献信息

• ORGANIC ELECTROLUMINESCENT ELEMENT AND ARYLENEDIAMINE DERIVATIVE
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0721935A1

  公开（公告）日：1996-07-17

  Organic electroluminescence devices having the life of light emission superior to those of conventional electroluminescence devices, and novel arylenediamine derivatives which can remarkably improve the life of light emission of an organic electroluminescence device when the derivatives are used as a component of the device, are disclosed. The organic electroluminescence devices of the present invention at least contain a p-phenylenediamine derivative having 6 or more benzene ring skeletons, or at least a 4,4'-biphenylenediamine derivative having 5 biphenyl groups. The arylenediamine derivatives of the present invention include p-phenylenediamine derivatives having 4 biphenyl groups and 4,4'-biphenylenediamine derivatives having 5 biphenyl groups.

  本发明公开了发光寿命优于传统电致发光器件的有机电致发光器件，以及新型芳基二胺衍生物，当该衍生物用作有机电致发光器件的组件时，可显著提高该器件的发光寿命。 本发明的有机电致发光器件至少含有一种具有 6 个或更多苯环骨架的对苯二胺衍生物，或至少含有一种具有 5 个联苯基团的 4,4'-联苯二胺衍生物。 本发明的芳基二胺衍生物包括具有 4 个联苯基团的对苯二胺衍生物和具有 5 个联苯基团的 4,4'-联苯二胺衍生物。
• Acrylenediamine derivatives and organic electroluminescence device containing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP1162193A1

  公开（公告）日：2001-12-12

  Organic electroluminescence devices having the life of light emission superior to those of conventional electroluminescence devices, and novel arylenediamine derivatives which can remarkably improve the life of light emission of an organic electroluminescence device when the derivatives are used as a component of the device, are disclosed. The organic electroluminescence devices of the present invention at least contain a 4,4'-biphenylenediamine derivative having 5 biphenyl groups. The arylenediamine derivatives of the present invention include 4,4'-biphenylenediamine derivatives having 5 biphenyl groups.

  本发明公开了发光寿命优于传统电致发光器件的有机电致发光器件，以及新型芳基二胺衍生物，当该衍生物用作有机电致发光器件的组成部分时，可显著提高该器件的发光寿命。 本发明的有机电致发光器件至少含有一种具有 5 个联苯基团的 4,4'-联苯二胺衍生物。 本发明的芳基二胺衍生物包括具有 5 个联苯基团的 4,4'-联苯二胺衍生物。
• AROMATIC AMINO COMPOUND MANUFACTURING METHOD
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2394980B1

  公开（公告）日：2016-12-21
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20140225100A1

  公开（公告）日：2014-08-14

  An organic electroluminescent device having a capping layer composed of material having a high refractive index, excelling in thin film stability and durability and having no absorption in the respective wavelength ranges of blue, green, and red is provided to improve device characteristics of the organic electroluminescent device, particularly to greatly improve light extraction efficiency. The organic electroluminescent device has at least an anode electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode electrode, and the capping layer in this order, wherein the capping layer contains an arylamine compound (X) having a structure in which two triphenylamine structures are joined within a molecule via a single bond or a divalent group that does not contain a heteroatom.
• ORGANIC LIGHT-EMITTING DIODE DISPLAY PANEL, FABRICATION METHOD, AND ELECTRONIC APPARATUS
  申请人：Shanghai Tianma AM-OLED Co., Ltd.

  公开号：US20170263884A1

  公开（公告）日：2017-09-14

  An organic light-emitting diode (OLED) display panel, a fabrication method thereof, and an electronic apparatus including the OLED display panel are provided. The OLED display panel comprises: a substrate, an organic light-emitting device, and a capping layer. A material of the capping layer includes a compound of a chemical formula (I), L1, L2, L3, and L4 are independently selected from a hydrogen atom, a substituted or -unsubstituted alkyl, a substituted or unsubstituted alkenyl, a substituted or unsubstituted alkynyl, and a substituted or unsubstituted phenyl. A total quantity of benzene rings included in L1, L2, L3, and L4 is from 0 to 6. Y1, Y2, Y3, Y4, Y5, and Y6 are independently selected from a hydrogen atom, a substituted or unsubstituted alkyl, a substituted of unsubstituted alkenyl, and a substituted or unsubstituted alkynyl.