bis(cyclohexylammonium) phosphate | 36011-98-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(cyclohexylammonium) phosphate
• 英文别名: Cyclohexylazanium;dihydrogen phosphate
• CAS: 36011-98-0
• 化学式: 2C₆H₁₃N*H₃O₄P
• 分子量: 296.347
• InChiKey: GLDSGGKXZDXGST-UHFFFAOYSA-N

物化性质

• 熔点：
  230-235 °C(Solv: water (7732-18-5))

计算性质

• 辛醇/水分配系数(LogP)：
  1.17
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  bis(cyclohexylammonium) phosphate 、 7-甲基鸟苷碘化物 在 purine nucleoside phosphorylase 作用下， 以 水 为溶剂， 反应 5.0h， 以82%的产率得到α-D-ribofuranosyl 1-phosphate dicyclohexylammonium salt
  参考文献：
  名称：

  酶法合成2-脱氧核糖1-磷酸和核糖1磷酸及随后的核苷制备

  摘要：

  我们提供了一种从7-Me-Guo和7-Me-dGuo制备Rib-p和dRib-p的新型酶促方法。在存在PNP的情况下，7-Me-Guo和7-Me-dGuo的几乎不可逆的磷酸分解可确保起始核苷定量转化为异构纯α-Rib-p和α-dRib-p。分离和纯化后，Rib-p和dRib-p的收率为74–96％。

  DOI：

  10.1002/ejoc.201901454
• 作为产物：
  描述：

  环己胺 在 磷酸 、 titanium phosphate monohydrate 作用下， 反应 3.33h， 生成 bis(cyclohexylammonium) phosphate
  参考文献：
  名称：

  阴离子控制的阳离子交换过程：通过与烷基铵盐直接离子交换嵌入α-钛磷酸盐

  摘要：

  几种烷基铵盐用于研究α-磷酸钛（α-TiP）插层化学。表征结果表明，无需添加任何额外的胺类物质就可以成功实现通过直接离子交换实现的预期插入。我们的发现与当前的观点不同，即通过离子交换方法，在没有碱的辅助下，由于层间距离小，大阳离子难以直接交换到α-四价金属磷酸盐的狭窄层间空间中。研究发现，烷基铵阳离子，例如n仅通过选择与适当阴离子的盐，例如磷酸根，亚磷酸根，亚硫酸根，柠檬酸根和苹果酸根离子，就可以将丁基丁基铵阳离子直接交换到层间空间中。对于磷酸盐，除正丁基铵外，还研究并成功完成了正己基铵，环己基铵和吡啶鎓与层间质子的交换。这四种阳离子的吸收值分别为0.420、0.595、0.571和0.335 g / g。一项机理研究表明，尽管相关的交换反应似乎只涉及α-TiP的质子和盐的烷基铵阳离子，但事实证明，盐中阴离子（反离子）的共轭酸的强度是关键在这个过程中的因素。

  DOI：

  10.1021/acs.inorgchem.7b03030

文献信息

• Alkylation of Ammonium Salts Catalyzed by Imidazolium-Based Ionic Liquid Catalysts
  作者：Zhuo Qun Zheng、Jie Wang、Ting Hua Wu、Xiao Ping Zhou

  DOI：10.1002/adsc.200600451

  日期：2007.5.7

  Quaternary ammonium salts were synthesized from ammonium salts and dialkyl carbonates over imidazolium ionic liquid catalysts. The reaction gave almost stoichiometric amounts of the quaternary ammonium salts for halides and nitrates. It was found that the electron-donating property of the alkyl moieties of ammonium cations, the electrophilic nature of the alkyl group of the carbonate, the acidity of

  在咪唑鎓离子液体催化剂上由铵盐和碳酸二烷基酯合成季铵盐。该反应产生了几乎化学计量的用于卤化物和硝酸盐的季铵盐。发现铵阳离子的烷基部分的供电子性，碳酸盐烷基的亲电子性质，铵盐的阴离子所对应的酸的酸度以及铵的空间位阻。盐和碳酸二烷基酯是影响季铵盐收率的关键因素。铵盐氮原子上的强供电子烷基，碳酸二烷基酯的亚甲基碳上的吸电子基团，
• Polyolefin base resin composition for metal product wrapping material
  申请人：AICELLO CHEMICAL COMPANY LIMITED

  公开号：EP0202771A2

  公开（公告）日：1986-11-26

  Disclosed herein is a resin composition obtained by mixing an olefin-base resin, which has in turn been obtained by partially neutralizing a free carboxyl group in a random copolymer of an a-olefin and an α,β-ethylenically-unsaturated monocarboxylic or dicarboxylic acid, with a volatile rust preventive in a specific amount or more. The resin composition has excellent rust preventive properties and can hence be used advantageously as a wrapping material for metal products.

  本文公开了一种树脂组合物，它是通过将烯烃基树脂（该树脂又是通过部分中和 a-烯烃与 α，β-乙烯基不饱和单羧酸或二羧酸的无规共聚物中的游离羧基而获得）与一定量或更多的挥发性防锈剂混合而得。这种树脂组合物具有优异的防锈性能，因此可用作金属产品的包覆材料。
• Cyclohexylamine-based compounds and uses thereof
  申请人：BOARD OF SUPERVISORS OF LOUISIANA STATE UNIVERSITY AND AGRICULTURAL AND MECHANICAL COLLEGE

  公开号：US10575520B2

  公开（公告）日：2020-03-03

  Compositions are described comprising an amount of a toxicant comprising a compound of the formula HNR1R2, or a salt thereof, wherein R1 and R2 are independently hydrogen, a substituted or unsubstituted C4-C6-cycloalkyl group or a substituted or unsubstituted C6-C12-aryl group; wherein the amount of the toxicant is sufficient to control termites. Methods for controlling termites using such compositions are also described.

  描述了含有一定量毒物的组合物，该毒物包括式 HNR1R2 的化合物或其盐，其中 R1 和 R2 独立地为氢、取代或未取代的 C4-C6 环烷基或取代或未取代的 C6-C12 芳基；其中毒物的量足以控制白蚁。还描述了使用此类组合物控制白蚁的方法。
• SLURRY COMPOSITIONS FOR MAKING ENVIRONMENTAL BARRIER COATINGS AND ENVIRONMENTAL BARRIER COATINGS COMPRISING THE SAME
  申请人：KIRBY GLEN HAROLD

  公开号：US20110027556A1

  公开（公告）日：2011-02-03

  Slurry compositions for making an environmental barrier coating including from about 9 wt % to about 81 wt % water; from about 3 wt % to about 72 wt % primary material; and from about 0.1 wt % to about 18 wt % slurry sintering aid, and environmental barrier coatings including such compositions.
• Auto-emulsifying cleaning systems and methods for use
  申请人：Sehgal Amit

  公开号：US20110088728A1

  公开（公告）日：2011-04-21

  An auto-emulsifying cleaning composition capable of emulsifying upon contact with water, the composition in one typical embodiment comprising, based on the total weight of the composition, (a) from about 1% to about 99% by weight a blend of dibasic esters; (b) from about 1% to about 40% by weight of a blend of surfactants consisting of an organic anion neutralized with an organic cation, where either or both of the anion and the cation have surfactant properties, and the complex of which is soluble in the dibasic ester solvent blend. The blend of surfactants is typically a cationic surfactant and an anionic surfactant, which may or may not be used in conjunction with non-ionic surfactants. The dibasic esters are be derived from a blend of adipic, glutaric, and succinic diacids, and, in one particular embodiment, the blend comprises dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C 1 -C 12 hydrocarbon group.