2-benzyl-1,4,7-trimethyl-1,4,7-triazacyclononane | 257945-24-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-benzyl-1,4,7-trimethyl-1,4,7-triazacyclononane
• 英文别名: 2-Benzyl-1,4,7-trimethyl-1,4,7-triazonane
• CAS: 257945-24-7
• 化学式: C₁₆H₂₇N₃
• 分子量: 261.41
• InChiKey: YMZSLCSDMHLNPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 2-benzyl-1,4,7-trimethyl-1,4,7-triazacyclononane 、 双氧水 、 manganese(ll) chloride 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 [Mn(IV)2(μ-O)3(2-benzyl-1,4,7-trimethyl-1,4,7-triazacyclononane)2](PF6)2
  参考文献：
  名称：

  Synthesis and properties of hydrophobic [MnIV2(μ-O)3(L)2]2+ complexes, derived from alkyl substituted 1,4,7-triazacyclononane ligands

  摘要：

  A series of manganese complexes of 1,4,7,-trimethyl-1,4,7-triazacyclononane homologues has been prepared. The ligand bears on position 1 or 2, alkyl and/or benzyl substituents resulting in an increase of lipophilicity of the coordination complex measured by the log P values. The lipophilic complexes dissolve well in organic solvents like dichloromethane. This permits them to be used as homogenous catalysts in two phase epoxidation of lipophilic substrate like styrene and dodecene using hydrogen peroxide as oxidant. Also the most lipophilic complexes activate hydrogen peroxide for bactericidal activity. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00378-3

文献信息

• Bleach activation
  申请人：UNILEVER PLC

  公开号：EP0549272A1

  公开（公告）日：1993-06-30

  Bleach catalysts comprising a complex of formula (I)         [L Mn Xp ]z Yq   (I) wherein Mn is manganese in the II, III or IV oxidation state, X represents a coordinating or bridging species; p is an integer from 1 to 3; Y is a counter-ion the type of which is dependent upon the charge z of the complex which can be positive, zero or negative; q = z [charge Y]; and L is a ligand which is a macrocyclic organic molecule.

  由式 (I) 复合物组成的漂白催化剂 [L Mn Xp ]z Yq (I) 其中 Mn 是处于 II、III 或 IV 氧化态的锰，X 代表配位或桥接物种；p 是 1 到 3 的整数；Y 是反离子，其类型取决于络合物的电荷 z，电荷 z 可以是正、零或负；q = z [电荷 Y]；L 是配体，是大环有机分子。
• Detergent bleach compositions
  申请人：UNILEVER PLC

  公开号：EP0544490A1

  公开（公告）日：1993-06-02

  Detergent bleach compositions are disclosed comprising a surface active material, a peroxide bleaching agent and a dinuclear manganese complex as the bleach catalyst, characterised in that the composition comprises from 0-25% by weight of anionic surfactant and from 7.5-55% by weight of nonionic surfactant, the weight ratio of nonionic surfactant to anionic surfactant being at least 0.75 if the composition contains not more than 7.5% by weight of a carbonate, expressed as sodium carbonate, and at least 2.2. if the composition contains more than 7.5% by weight of a carbonate.

  本发明公开了由表面活性材料、过氧化物漂白剂和作为漂白催化剂的二核锰络合物组成的洗涤剂漂白组合物，其特征在于该组合物包括 0-25% （重量）的阴离子表面活性剂和 7.5-55%(重量)的非离子表面活性剂，如果组合物中碳酸盐(以碳酸钠表示)的含量不超过 7.5%(重量)，则非离子表面活性剂与阴离子表面活性剂的重量比至少为 0.75，如果组合物中碳酸盐的含量超过 7.5%(重量)，则非离子表面活性剂与阴离子表面活性剂的重量比至少为 2.2。
• Bleach and detergent compositions
  申请人：UNILEVER N.V.

  公开号：EP0616029A1

  公开（公告）日：1994-09-21

  There is provided a storage-stable and highly potent, particulate bleach composition for laundry use, comprising sodium percarbonate, optionally a bleach activator, and a bleach catalyst including a source of Mn and/or Fe ions and a ligand which is a macrocyclic organic compound of formula I:         [NR³ - (CR¹(R²)u)t]s      (I)    wherein t is an integer from 2 to 3; s is an integer from 3 to 4, u is zero or one; and R¹, R² and R³ are each independently selected from H, alkyl and aryl, both optionally substituted.

  本发明提供了一种贮存稳定、高效的洗衣用微粒漂白剂组合物，该组合物包括过碳酸钠、漂白活化剂和漂白催化剂，其中漂白催化剂包括 Mn 和/或 Fe 离子源和配体，配体为式 I 的大环有机化合物： [NR³ - (CR¹(R²)u)t]s (I) 其中 t 是 2 至 3 的整数；s 是 3 至 4 的整数；u 是 0 或 1；R¹、R² 和 R³ 各自独立地选自 H、烷基和芳基，两者均可选择性地被取代。
• Cyclische Polyaminsalze
  申请人：Clariant GmbH

  公开号：EP0902021A2

  公开（公告）日：1999-03-17

  Gegenstand der Erfindung sind cyclische Polyaminsalze der Formel wobei R1, R2, R3, R4, R5, R6, l, m, n und X die in der Beschreibung genannten Bedeutungen haben. Diese Verbindungen eignen sich als Bleichkatalysatoren in Wasch- und Reinigungsmitteln, die Perverbindungen enthalten.

  本发明的主题是式如下的环状多胺盐 其中 R1、R2、R3、R4、R5、R6、l、m、n 和 X 的含义见说明。这些化合物适用于含有过化合物的洗涤剂和清洁剂中作为漂白催化剂。
• COMPOSITIONS COMPRISING PROTONATED TRIAZACYCLIC COMPOUNDS AND BLEACHING AGENT AND CLEANING AGENT COMPRISING SAME
  申请人：WeylChem Performance Products GmbH

  公开号：EP4008765A1

  公开（公告）日：2022-06-08

  The present invention concerns a composition comprising Mn(II) oxalate, a protonated salt of a cyclic triamine, an absorbent, coated by a water-soluble polymer. In another embodiment the invention concerns a composition comprising a protonated salt of a cyclic triamine and no or very small amounts of Mn. The invention also concerns methods of preparing said compositions comprising Mn(II) oxalate and such salts or comprising such salts and no Mn compound and bleaching formulations comprising the compositions and a peroxy compound or a precursor thereof. Compositions comprising Mn(II) oxalate and the salt or comprising the salt and no Mn compound, and formulations comprising these are suitable for use in catalysing oxidation, for example as a component of a dishwasher bleaching composition. The invention further relates to methods of oxidising with the bleaching formulations described herein.

  本发明涉及一种由草酸锰（II）、环三胺的质子化盐、吸收剂和水溶性聚合物包覆的组合物。在另一个实施方案中，本发明涉及一种由环状三胺的质子化盐和无锰或极少量锰组成的组合物。本发明还涉及由草酸锰（II）和此类盐组成或由此类盐和无锰化合物组成的上述组合物的制备方法，以及由该组合物和过氧化合物或其前体组成的漂白配方。由草酸锰（II）和盐组成的组合物或由盐和无锰化合物组成的组合物，以及由这些组合物组成的配方适用于催化氧化，例如作为洗碗机漂白组合物的成分。本发明还涉及使用本文所述漂白配方进行氧化的方法。