3-hydroxy-acenaphthene | 74449-61-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-hydroxy-acenaphthene
• 英文别名: 3-Hydroxy-acenaphthen；1,2-Dihydroacenaphthylen-3-OL
• CAS: 74449-61-9
• 化学式: C₁₂H₁₀O
• 分子量: 170.211
• InChiKey: YFCHDVXZAXAVHJ-UHFFFAOYSA-N

物化性质

• 沸点：
  346.9±21.0 °C(Predicted)
• 密度：
  1.276±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-氨基苊 在 硫酸 、 溶剂黄146 、 sodium nitrite 作用下， 生成 3-hydroxy-acenaphthene
  参考文献：
  名称：

  Morgan; Harrison, Journal of the Society of Chemical Industry, 1930, vol. 49, p. 413 T, 421 T

  摘要：

  DOI：

文献信息

• POLYMERIZABLE MONOMER, POLYMER COMPOUND FOR CONDUCTIVE POLYMER, AND METHOD FOR PRODUCING THE POLYMER COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20200247926A1

  公开（公告）日：2020-08-06

  Polymerization reaction is performed using a polymerizable monomer shown by the following general formula (1) and at least one monomer selected from monomers each having a structure of a salt among a lithium salt, a sodium salt, a potassium salt, and a nitrogen compound salt of a fluorosulfonic acid or the like; then, the structure of the salt of the repeating unit of a polymer obtained by the polymerization reaction is changed to the fluorosulfonic acid or the like by ion exchange. Thus, the present invention provides a polymer compound for a conductive polymer and a method for producing the polymer compound which is suitably used as a dopant for a fuel cell and a conductive material, and which is a copolymer containing a repeating unit of styrene having a 3,3,3-trifluoro-2-hydroxy-2-trifluoromethylisobutyl ether group, and a repeating unit having any of a fluorosulfonic acid, a fluorosulfonimide group, and a n-carbonyl-fluoro-sulfonamide group.

  聚合反应使用以下一般式（1）所示的可聚合单体和至少一种选择自锂盐、钠盐、钾盐和氟磺酸盐等盐结构的单体中的单体进行；然后，通过离子交换将聚合反应得到的聚合物的重复单元的盐结构改变为氟磺酸盐或类似物。因此，本发明提供了一种用作导电聚合物的聚合物化合物以及用作燃料电池和导电材料的掺杂剂的聚合物化合物的生产方法，该聚合物是含有3,3,3-三氟-2-羟基-2-三氟甲基异丁基醚基的苯乙烯重复单元和具有氟磺酸、氟磺酰亚胺基团和n-羰基-氟磺酰胺基团中的任何一种的重复单元的共聚物。
• Conductive polymer composite and substrate
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10020089B2

  公开（公告）日：2018-07-10

  The present invention provides a conductive polymer composite including (A) a π-conjugated polymer and (B) a dopant polymer which contains a repeating unit “a” represented by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000, wherein R1 represents a hydrogen atom or a methyl group; R2 represents a fluorine atom or a trifluoromethyl group; Z represents a single bond or —C(═O)—O—; “m” is an integer of 1 to 4; and “a” is a number satisfying 0

  本发明提供了一种导电聚合物复合材料，包括(A)π-共轭聚合物和(B)掺杂聚合物，其中掺杂聚合物含有由以下通式(1)表示的重复单元 "a"，其重量平均分子量在 1,000 至 500,000 之间、 其中 R1 代表氢原子或甲基；R2 代表氟原子或三氟甲基；Z 代表单键或-C(═O)-O-；"m "是 1 至 4 的整数；"a "是满足 0＜a≤1.0 的数字。本发明可提供一种导电聚合物复合材料，该复合材料通过旋涂具有优异的过滤性和成膜性，并且在由该复合材料形成薄膜时，可形成具有高透明度和平整度的导电薄膜。
• Conductive material and substrate
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10023752B2

  公开（公告）日：2018-07-17

  The present invention provides a conductive material including: (A) a π-conjugated polymer, (B) a dopant polymer which contains one or more repeating units selected from “a1” to “a4” respectively shown by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000, and (C) one or more salts selected from the group consisting of a monovalent copper salt of carboxylic acid, a monovalent copper salt of β-diketone, and a monovalent copper salt of β-ketoester. There can be provided a conductive material that has excellent film-formability and also can form a conductive film having high transparency and conductivity, superior flexibility and flatness when the film is formed from the material.

  本发明提供了一种导电材料，包括(A) π-共轭聚合物；(B) 掺杂聚合物，其含有一个或多个如下通式(1)所示分别选自 "a1 "至 "a4 "的重复单元，且其重量平均分子量在 1,000 至 500,000 之间；以及 (C) 一种或多种盐，其选自由羧酸的一价铜盐、β-二酮的一价铜盐和β-酮酯的一价铜盐组成的组。本发明可提供一种导电材料，该材料具有优异的成膜性，并可形成具有高透明度和导电性的导电薄膜，在由该材料形成薄膜时，还具有优异的柔韧性和平整度。
• Conductive polymer composition, coated article, and patterning process
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10295906B2

  公开（公告）日：2019-05-21

  A conductive polymer composition including: (A) π-conjugated conductive polymer having at least one repeating unit shown by the following general formulae (1-1), (1-2), and (1-3); (B) a dopant polymer which contains a repeating unit “a” shown by the following general formula (2) and has a weight-average molecular weight in a range of 1,000 to 500,000; and (C) an amphoteric ion compound shown by the following general formula (3). This provides a conductive polymer composition having good filterability, coating property and film-formability onto a substrate to form a conductive film with good film quality and peelability with H2O or an alkaline developer; and forming a conductive film which reveals antistatic performance with high charge discharging ability and does not affect an influence of acid on the adjoined layer to be contact with.

  一种导电聚合物组合物，包括：(A)π-共轭导电聚合物，该聚合物具有至少一个重复单元，如下文通式(1-1)、(1-2)和(1-3)所示；(B)掺杂聚合物，该聚合物含有如下文通式(2)所示的重复单元 "a"，其重量平均分子量在 1,000 至 500,000 之间；以及(C)两性离子化合物，如下文通式(3)所示。本发明提供了一种导电聚合物组合物，它具有良好的过滤性、涂覆性和在基材上成膜性，可在 H2O 或碱性显影剂的作用下形成具有良好成膜质量和可剥离性的导电膜；并可形成具有高电荷放电能力的抗静电性能的导电膜，且不会影响酸对与之接触的毗邻层的影响。
• Polymer compound for conductive polymer and method for producing same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10851188B2

  公开（公告）日：2020-12-01

  A polymer compound for a conductive polymer contains one or more kinds of repeating units “a” represented by the following general formula (1) and has a weight average molecular weight in the range of 1,000 to 500,000, R1 represents a hydrogen atom or a methyl group; Rf1 represents a linear or branched alkyl group having 1 to 4 carbon atoms or a phenyl group, and has at least one fluorine atom or a trifluoromethyl group in Rf1; Z1 represents a single bond, an arylene group having 6 to 12 carbon atoms or —C(═O)—O—R2—; R2 represents a linear, branched or cyclic alkylene group having 1 to 12 carbon atoms, an arylene group having 6 to 10 carbon atoms or an alkenylene group having 2 to 10 carbon atoms, and may have an ether group, a carbonyl group or an ester group in R2; and “a” is 0

  一种用于导电聚合物的高分子化合物含有一种或多种由以下通式（1）表示的重复单元 "a"，其重量平均分子量在 1 000 至 500 000 之间、 R1 代表氢原子或甲基；Rf1 代表具有 1 至 4 个碳原子的直链或支链烷基或苯基，且在 Rf1 中至少有一个氟原子或三氟甲基；Z1 代表单键、具有 6 至 12 个碳原子的芳基或-C(═O)-O-R2-；R2 代表具有 1 至 12 个碳原子的直链、支链或环状亚烷基、具有 6 至 10 个碳原子的芳烯基或具有 2 至 10 个碳原子的烯基，R2 中可能具有醚基、羰基或酯基；"a "为 0