9,9-bis(6-glycidyloxynaphthalene-2-yl)-9H-fluorene | 1238475-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-bis(6-glycidyloxynaphthalene-2-yl)-9H-fluorene
• 英文别名: 9,9-bis(6-glycidyloxynaphthalen-2-yl)-9H-fluorene；9,9-bis(6-glycidyl-oxynaphthalene-2-yl)fluorene；9,9-bis(6-glycidyloxynaphthalen-2-yl)fluorene；9,9-bis(6-glycidyloxy-2-naphthyl)fluorene；9,9-bis(6-glycidoxy-2-naphthyl)fluorene；9,9-Bis[6-(glycidyloxy)-2-naphthyl]-9H-fluorene；2-[[6-[9-[6-(oxiran-2-ylmethoxy)naphthalen-2-yl]fluoren-9-yl]naphthalen-2-yl]oxymethyl]oxirane
• CAS: 1238475-45-0
• 化学式: C₃₉H₃₀O₄
• 分子量: 562.665
• InChiKey: OROZTGFBKXEPSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  43
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-乙烯基苯甲酸 、 9,9-bis(6-glycidyloxynaphthalene-2-yl)-9H-fluorene 、 6-propargyloxy-2-naphthalenecarboxylic acid 在 苄基三乙基氯化铵 作用下， 反应 12.0h， 以25%的产率得到[3-[6-[9-[6-[3-(4-Ethenylbenzoyl)oxy-2-hydroxypropoxy]naphthalen-2-yl]fluoren-9-yl]naphthalen-2-yl]oxy-2-hydroxypropyl] 4-ethenylbenzoate
  参考文献：
  名称：

  有機膜形成用化合物、有機膜形成用組成物、有機膜形成方法、及びパターン形成方法

  摘要：

  提供具有高度嵌入/平坦特性的有机膜形成组合物的有机膜形成化合物。解决方案是一种有机膜形成化合物，其最小复合粘度在50℃至300℃的范围内测量为10Pa·s以下。选择图：无。

  公开号：

  JP2017119670A

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• VINYL-GROUP-CONTAINING FLUORENE COMPOUND
  申请人：DAICEL CORPORATION

  公开号：US20160046551A1

  公开（公告）日：2016-02-18

  A novel vinyl-group-containing fluorene compound and a method for producing the same, a polymerizable monomer and cross-linking agent including this compound, a leaving-group-containing fluorene compound, a monovinyl-group-containing fluorene compound, and methods for producing the same. This vinyl-group-containing fluorene compound is represented by formula (1). In the formula, W 1 and W 2 represent a group represented by formula (2), a group represented by formula (4), a hydroxyl group, or a (meth)acryloyloxy group, R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon, and n1 and n2 are integers of 0-4. In formulas (2) and (4), a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or a group represented by —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer of 0 or greater.

  一种含有乙烯基的萘化合物及其制备方法，包括该化合物的可聚合单体和交联剂，含有离去基的萘化合物，含有单乙烯基的萘化合物，以及其制备方法。该含有乙烯基的萘化合物由式（1）表示。在该式中，W1和W2代表由式（2）表示的基团，由式（4）表示的基团，羟基，或（甲基）丙烯氧基，R3a和R3b代表氰基，卤素原子，或一价碳氢化合物，n1和n2为0-4的整数。在式（2）和（4）中，环（Z）是芳香烃环，X是单键或由—S—表示的基团，R1是单键或C1-4烷基基团，R2是特定取代基团，如一价碳氢化合物，m为0或更大的整数。
• ORGANIC FILM COMPOSITION, PROCESS FOR FORMING ORGANIC FILM, PATTERNING PROCESS, AND COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20160336189A1

  公开（公告）日：2016-11-17

  An organic film composition including a compound represented by the following general formula (1), wherein n1 and n2 each independently represent 0 or 1; “W” represents a single bond or any of structures represented by the following formula (2); R 1 represents any of structures represented by the following general formula (3); m1 and m2 each independently represent an integer of 0 to 7, with the proviso that m1+m2 is 1 to 14. There can be provided an organic film composition for forming an organic film having dry etching resistance as well as advanced filling/planarizing characteristics.

  一种有机薄膜组合物，包括以下通式（1）所表示的化合物，其中n1和n2各自独立地表示0或1；“W”表示单键或以下式（2）所表示的任何结构之一；R1表示以下通式（3）所表示的任何结构之一；m1和m2各自独立地表示0到7的整数，但m1+m2为1到14。可以提供一种有机薄膜组合物，用于形成具有干法蚀刻抗性以及先进的填充/平坦化特性的有机薄膜。
• COMPOUND CONTAINING STRUCTURAL UNIT DERIVED FROM VINYL ETHER COMPOUND
  申请人：Tokyo Ohka Kogyo Co., Ltd.

  公开号：EP2980057A1

  公开（公告）日：2016-02-03

  Provided is a compound containing a structural unit derived from a novel vinyl ether compound. This compound contains a structural unit represented by formula (1), where the rings (Z1, Z2, Y1, Y2) are aromatic hydrocarbon rings; X1 and X2 represent a single bond or -S-; R represents a single bond or a specific divalent group; R1a and R1b represent a single bond or a C1-4 alkylene group; R2a and R2b represent a specific substituent group such as a monovalent hydrocarbon group; R3a and R3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon; m1 and m2 are integers of 0 or greater; n1 and n2 are integers of 0-4; V1 is a group represented by formulas (a1) - (a3) ; and V2 is a group represented by formulas (a1) - (a4) . In formulas (a1)-(a4), * represents a bonding hand, while ** and *** represent a bonding hand with an oxygen atom.

  本发明提供了一种化合物，其结构单元来源于一种新型乙烯基醚化合物。该化合物含有由式（1）表示的结构单元，其中环（Z1、Z2、Y1、Y2）是芳香烃环；X1 和 X2 代表单键或 -S-；R 代表单键或特定的二价基团；R1a 和 R1b 代表单键或 C1-4 亚烷基；R3a和R3b代表氰基、卤素原子或一价烃； m1和m2为0或更大的整数； n1和n2为0-4的整数； V1为式(a1)-(a3)所代表的基团； V2为式(a1)-(a4)所代表的基团。在(a1)-(a4)式中，*代表键手，**和***代表与氧原子的键手。