2-苯基-1,3-萘二胺 | 16479-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-苯基-1,3-萘二胺
• 英文名称: (+/-)-2-phenyl-naphthalene-1,3-diyldiamine
• 英文别名: (+/-)-2-Phenyl-naphthalin-1,3-diyldiamin；2-phenyl-1,3-naphthalenediamine；1,3-diamino-2-phenyl-naphthalene；2-Phenylnaphthalene-1,3-diamine
• CAS: 16479-17-7
• 化学式: C₁₆H₁₄N₂
• 分子量: 234.301
• InChiKey: IJTBLNVJSBGHPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  2-苯基-1,3-萘二胺 在 盐酸 作用下， 生成 1.3-Dihydroxy-2-phenyl-naphthalin
  参考文献：
  名称：

  Lees; Thorpe, Journal of the Chemical Society, 1907, vol. 91, p. 1287

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙炔基苯甲腈 在 吡啶 、 3-氯苯甲酰乙腈 、 4-二甲氨基吡啶 、 1,1'-双(二苯基膦)二茂铁 、 正丁基锂 、 乙基溴化镁 、 碳酸氢钠 、 copper(l) chloride 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 反应 47.0h， 生成 2-苯基-1,3-萘二胺
  参考文献：
  名称：

  铜催化邻-（氰基）苯基炔丙基碳酸酯的硼化环化反应：功能化的1-萘胺的合成

  摘要：

  铜催化邻-（氰基）苯基炔丙基碳酸酯的硼化环化反应导致3-硼基-1-萘胺的高效和区域选择性合成。对于该反应，提出了一种级联序列，该级联序列涉及通过硼烷基化，脱硼基化，硼烷基化和环化形成硼酸烯丙酯。所得产物已用于通过氧化或金属催化的偶联反应合成各种官能化的1-萘胺。

  DOI：

  10.1021/acs.orglett.8b01457

文献信息

• Polymers prepared from 4,4'-bis-[2-(3,4-(dicarboxyphenyl) hexafluoroisopropyl] diphenyl ether dianhydride
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317943A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(3,4-(dicarboxyphenyl)­hexafluoroisopropyl]diphenyl ether dianhydride.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-(3,4-(二羧基苯基)六氟异丙基]二苯醚二酐。
• Copolyimides prepared from 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoro propane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0361413A1

  公开（公告）日：1990-04-04

  Coolyimides and copolyamide-acids having improved solubility and processing characteristics are provided having incorporated into the polymeric chain as a novel aromatic diamine compound, 2-(3-aminophenyl)-2-­(4-aminophenyl) hexafluoropropane (3,4′-6F Diamine). The copolyamide-acids and copolyimides are prepared by reacting the 3,4′-6F Diamine with a mixture of two or more aromatic tetracarboxylic acids or anhydrides thereof. It has been found that the copolyimides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the diamine, which renders these copolymers more readily melt spinnable for the production of fibers. The copolymers may also be compression molded and fabricated into composites at moderate temperatures and pressures. Solutions of the copolyimides may be cast into films.

  在聚合物链中加入新型芳香族二胺化合物 2-(3-氨基苯基)-2-(4-氨基苯基)六氟丙烷(3,4′-6F 二胺)，可提供具有更好溶解性和加工特性的共聚多酰胺-酰亚胺和共聚多酰胺-酰亚胺。共聚多酰胺酸和共聚多亚胺是通过 3，4′-6F 二胺与两种或两种以上芳香族四羧酸或其酸酐的混合物反应制备的。研究发现，本发明的共聚亚胺具有更好的溶解特性、更低的介电常数和更好的热流特性，这是因为二胺上的氨基具有偏/对位定位，从而使这些共聚物更容易熔融纺丝，用于生产纤维。这些共聚物还可以在中等温度和压力下压缩成型并制成复合材料。共聚亚胺的溶液可浇铸成薄膜。
• Polymers prepared from 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoro propane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0361415A1

  公开（公告）日：1990-04-04

  Polyimides and polyamide-acids having improved solubility and processing characteristics are provided having incorporated into the polymeric chain as a novel aromatic diamine compound, 2-(3-aminophenyl)-2-­(4-aminophenyl) hexafluoropropane (3,4′-6F Diamine). The polyamide-acids and polyimides are prepared by reacting the 3,4′-6F Diamine with aromatic tetracarboxylic acids or anhydrides thereof. It has been.found that the polyimides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the diamine, which renders these polymers more readily melt spinnable for the production of fibers. The polymers may also be compression molded and fabricated into composites at moderate temperatures and pressures. Solutions of the polyimides may be cast into films.

  本发明提供的聚酰亚胺和聚酰胺-酸具有更好的溶解性和加工特性，在聚合物链中加入了新型芳香族二胺化合物 2-(3-氨基苯基)-2-(4-氨基苯基)六氟丙烷(3,4′-6F 二胺)。聚酰胺酸和聚酰亚胺是通过 3，4′-6F 二胺与芳香族四羧酸或其酸酐反应制备的。研究发现，本发明的聚酰亚胺具有更好的溶解特性、更低的介电常数和更好的热流特性，这是因为二胺上的氨基具有偏/对位定位，从而使这些聚合物更容易熔融纺丝以生产纤维。这些聚合物还可以在中等温度和压力下压缩成型并制成复合材料。聚酰亚胺的溶液可浇铸成薄膜。
• Polyamides prepared from 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoro propane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0361416A1

  公开（公告）日：1990-04-04

  Polyamides having improved solubility and processing characteristics are provided having incorporated into the polymeric chain a novel aromatic diamine compound, 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoropropane (3,4′-6F Diamine). The polyamides are prepared by reacting the 3,4′-6F Diamine with an aliphatic or aromatic di-acid or acid halide. It has been found that the polyamides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the diamine, which renders these polymers more readily melt spinnable for the production of fibers. The polymers may also be compression molded and fabricated into composites at moderate temperatures and pressures.

  在聚合物链中加入新型芳香族二胺化合物 2-(3-氨基苯基)-2-(4-氨基苯基)六氟丙烷（3,4′-6F 二胺），可提高聚酰胺的溶解性和加工特性。聚酰胺是通过 3,4′-6F二胺与脂肪族或芳香族二酸或酸卤化物反应制备的。研究发现，本发明的聚酰胺具有更好的溶解特性、较低的介电常数和更好的热流特性，这是因为二胺上的氨基基团具有偏/对位定位，从而使这些聚合物更容易熔融纺丝，用于生产纤维。这些聚合物还可在中等温度和压力下压缩成型并制成复合材料。
• Shaped articles from polyamide-imide polymers having fluorine-containing linking groups
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0385303A1

  公开（公告）日：1990-09-05

  The present invention provides for shaped articles made from novel heat stable polyamide-imide polymers having excellent flow properties which render them more readily processible into fibers, films, sheets and other molded articles. The polymers are prepared by forming the polycondensation product of one or more aromatic diamines, one or more trifunctional acid anhydride monomers, and one or more tetrafunctional aromatic dianhydrides, at least one of said monomers containing the groups CF₃ - - R linking two aromatic moieties, wherein R is CF₃ or phenyl. In addition to improved flow properties, the polyamide-imide polymers of this invention also exhibit improved solubility properties in most organic solvents, improved resistance to attack by chlorinated solvents such as trichloroethylene as compared with polyimides, improved hydrophobic properties as well as excellent thermal properties including resistance to thermooxidative degredation.

  本发明提供了由新型热稳定聚酰胺-酰亚胺聚合物制成的成型制品，这些聚合物具有极佳的流动性能，使其更易于加工成纤维、薄膜、片材和其他成型制品。这种聚合物是由一种或多种芳香族二胺、一种或多种三官能团酸酐单体和一种或多种四官能团芳香族二酐的缩聚产物制备而成，其中至少一种单体含有连接两个芳香族分子的基团 CF₃ - R，其中 R 是 CF₃ 或苯基。与聚酰亚胺相比，本发明的聚酰胺-酰亚胺聚合物除了具有更好的流动性能外，在大多数有机溶剂中还具有更好的溶解性能，更强的抗氯化溶剂（如三氯乙烯）侵蚀的能力，更好的疏水性能以及优异的热性能，包括抗热氧化降解的能力。