N,N'-bis {4-(benzothiazol-2-yl)phenyl}-N,N'-diphenyl-4,4'-diamino-1,1'-biphenyl | 1011534-41-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis {4-(benzothiazol-2-yl)phenyl}-N,N'-diphenyl-4,4'-diamino-1,1'-biphenyl
• 英文别名: N-[4-(1,3-benzothiazol-2-yl)phenyl]-4-[4-(N-[4-(1,3-benzothiazol-2-yl)phenyl]anilino)phenyl]-N-phenylaniline
• CAS: 1011534-41-0
• 化学式: C₅₀H₃₄N₄S₂
• 分子量: 754.979
• InChiKey: XOXWPXVEJBGBKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.3
• 重原子数：
  56
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N,N'-二苯基联苯二胺 、 2-(4-溴苯基)苯并噻唑 在 叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 5.5h， 以62%的产率得到N,N'-bis {4-(benzothiazol-2-yl)phenyl}-N,N'-diphenyl-4,4'-diamino-1,1'-biphenyl
  参考文献：
  名称：

  ARYLAMINE COMPOUND HAVING BENZOAZOLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT

  摘要：

  本发明的目标是提供一种有机EL器件，该器件结合了器件的各种材料和由吸收400nm至410nm波长范围内太阳光的材料组成的盖层，以防止对有机EL器件内部材料的影响，具有高光吸收系数和高折射率，显著提高光提取效率，在薄膜中具有优异的稳定性、耐久性和耐光性，并且在蓝色、绿色和红色波长范围内没有吸收，从而有效地实现器件的各种材料特性。本发明是一种具有苯唑结构的芳胺化合物，也是一种包含芳胺化合物的盖层和包含主体和磷光掺杂剂的发光层的有机EL器件。

  公开号：

  US20220119360A1

文献信息

• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：MORISHITA Hironobu

  公开号：US20080091025A1

  公开（公告）日：2008-04-17

  The present invention provides an organic electroluminescence device which can be driven at a reduced voltage, hardly causes the crystallization of a molecule, can be produced in improved yield, and has a long lifetime because of difficulty of molecular crystallization, and aromatic amine derivatives for realizing the device. The aromatic amine derivatives are novel aromatic amine derivatives having a specific structure. The organic electroluminescence device includes an organic thin film layer formed of one or more layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode. In the organic electroluminescence device, at least one layer of the organic thin film layer, especially a hole transporting layer, contains the aromatic amine derivative alone or as a component of a mixture.

  本发明提供了一种有机电致发光器件，可以在降低电压的情况下驱动，几乎不会导致分子结晶，可以提高产量生产，并且由于分子结晶困难，具有长寿命，以及用于实现该器件的芳香胺衍生物。这些芳香胺衍生物是具有特定结构的新型芳香胺衍生物。该有机电致发光器件包括由一个或多个层组成的有机薄膜层，至少包括一个发光层，该有机薄膜层位于阴极和阳极之间。在该有机电致发光器件中，至少有一个有机薄膜层的层，特别是一个传输孔层，单独或作为混合物的组分包含该芳香胺衍生物。
• ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP3432688A1

  公开（公告）日：2019-01-23

  [Object] To provide an organic electroluminescence device including, in order to improve the device characteristics of the organic electroluminescence device, particularly, to absorb light having the wavelengths of from 400 nm to 410 nm from sunlight, not to affect a material inside the device, and to significantly improve the light extraction efficiency, a capping layer formed of a material that has a high absorption coefficient, a high refractive index, and an excellent stability, durability, and light resistance of a thin film, and does not absorb light in the blue, green, and red wavelength range. [Solving Means] An organic electroluminescence device including at least an anode electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode electrode, and a capping layer in the stated order, in which the capping layer includes a material having an extinction coefficient of not less than 0.3 at wavelengths of from 400 nm to 410 nm and an absorbance of not less than 0.2 at wavelengths of from 400 nm to 410 nm in an absorption spectrum of a concentration of 10-5 mol/l.

  [目的] 提供一种有机电致发光器件，包括：为了改善有机电致发光器件的器件特性，特别是吸收来自太阳光的波长为400 nm至410 nm的光，而不影响器件内部的材料、为了显著提高光萃取效率，需要一种由具有高吸收系数、高折射率、优异的薄膜稳定性、耐久性和耐光性，并且不吸收蓝色、绿色和红色波长范围内的光的材料形成的封盖层。 [解决手段】一种有机电致发光器件，至少包括按所述顺序排列的阳极电极、空穴传输层、发光层、电子传输层、阴极电极和封盖层，其中，封盖层包括一种材料，该材料在波长为 400 纳米至 410 纳米的吸收光谱中，消光系数不小于 0.3，在波长为 400 纳米至 410 纳米的吸收光谱中，吸光度不小于 0.2，浓度为 10-5 摩尔/升。
• Organic electroluminescence device
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US11056653B2

  公开（公告）日：2021-07-06

  Object To provide an organic electroluminescence device including, in order to improve the device characteristics of the organic electroluminescence device, particularly, to absorb light having the wavelengths of from 400 nm to 410 nm from sunlight, not to affect a material inside the device, and to significantly improve the light extraction efficiency, a capping layer formed of a material that has a high absorption coefficient, a high refractive index, and an excellent stability, durability, and light resistance of a thin film, and does not absorb light in the blue, green, and red wavelength range. Solving Means An organic electroluminescence device including at least an anode electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode electrode, and a capping layer in the stated order, in which the capping layer includes a material having an extinction coefficient of not less than 0.3 at wavelengths of from 400 nm to 410 nm and an absorbance of not less than 0.2 at wavelengths of from 400 nm to 410 nm in an absorption spectrum of a concentration of 10−5 mol/l.

  目的 提供一种有机电致发光器件，为了改善该有机电致发光器件的器件特性，特别是吸收来自太阳光的波长为 400 nm 至 410 nm 的光，不影响器件内部的材料，并显著提高光提取效率，该器件包括由具有高吸收系数、高折射率和出色的薄膜稳定性、耐久性和耐光性的材料形成的封盖层，该封盖层不吸收蓝、绿和红波长范围内的光。 解决方法 一种有机电致发光器件，至少包括按所述顺序排列的阳极电极、空穴传输层、发光层、电子传输层、阴极电极和封盖层，其中封盖层包括一种材料，该材料在浓度为 10-5 摩尔/升的吸收光谱中，在波长为 400 纳米至 410 纳米时的消光系数不小于 0.3，在波长为 400 纳米至 410 纳米时的吸光度不小于 0.2。
• Organic Electroluminescence Device
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US20200328353A1

  公开（公告）日：2020-10-15

  Object To provide an organic electroluminescence device including, in order to improve the device characteristics of the organic electroluminescence device, particularly, to absorb light having the wavelengths of from 400 nm to 410 nm from sunlight, not to affect a material inside the device, and to significantly improve the light extraction efficiency, a capping layer formed of a material that has a high absorption coefficient, a high refractive index, and an excellent stability, durability, and light resistance of a thin film, and does not absorb light in the blue, green, and red wavelength range. Solving Means An organic electroluminescence device including at least an anode electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode electrode, and a capping layer in the stated order, in which the capping layer includes a material having an extinction coefficient of not less than 0.3 at wavelengths of from 400 nm to 410 nm and an absorbance of not less than 0.2 at wavelengths of from 400 nm to 410 nm in an absorption spectrum of a concentration of 10 −5 mol/l.
• [EN] ORGANIC ELECTROLUMINESCENT ELEMENT<br/>[FR] ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE<br/>[JA] 有機エレクトロルミネッセンス素子
  申请人：HODOGAYA CHEMICAL CO LTD

  公开号：WO2020137724A1

  公开（公告）日：2020-07-02

  本発明は、薄膜の安定性や耐久性に優れているアリールアミン系材料、特に屈折率が高い特定のアミン化合物を濃度１０－５ｍｏｌ／Ｌの吸収スペクトルにおいて波長４００ｎｍから４１０ｎｍにおける吸光度が高い材料を選別してキャッピング層の材料とし、及び特定の縮合環構造を有する複素環化合物を有する化合物を選択して発光層の材料とし、前記のキャッピング層と発光層の材料を組み合わせた種々の有機エレクトロルミネッセンス素子である。