N,N-bis[4-[dimethyl(trimethylsilyloxy)silyl]oxyphenyl]-3,4-dimethylaniline | 1259383-68-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-bis[4-[dimethyl(trimethylsilyloxy)silyl]oxyphenyl]-3,4-dimethylaniline
• CAS: 1259383-68-0
• 化学式: C₃₀H₄₇NO₄Si₄
• 分子量: 598.049
• InChiKey: GZCXUQWVEAAPGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.64
• 重原子数：
  39
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  五甲基二硅氧烷 、 N,N-bis(4-methoxyphenyl)-3,4-dimethylaniline 在 三(五氟苯基)硼烷 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以92%的产率得到N,N-bis[4-[dimethyl(trimethylsilyloxy)silyl]oxyphenyl]-3,4-dimethylaniline
  参考文献：
  名称：

  Siloxane−Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers−Rubinsztajn Reaction

  摘要：

  A series of room temperature liquid siloxane triarylamine hybrids were synthesized using the Piers-Rubinsztajn reaction. These materials displayed well behaved electrochemical oxidation and low T(g)'s and were free-flowing liquids. The interaction between the Lewis acidic tris(pentafluorophenyl)borane catalyst and the Lewis basic starting triarylamine substrate was also investigated by steady state UV-vis spectroscopy and (19)F NMR.

  DOI：

  10.1021/ol102607v

文献信息

• Siloxane−Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers−Rubinsztajn Reaction
  作者：Brett A. Kamino、John B. Grande、Michael A. Brook、Timothy P. Bender

  DOI：10.1021/ol102607v

  日期：2011.1.7

  A series of room temperature liquid siloxane triarylamine hybrids were synthesized using the Piers-Rubinsztajn reaction. These materials displayed well behaved electrochemical oxidation and low T(g)'s and were free-flowing liquids. The interaction between the Lewis acidic tris(pentafluorophenyl)borane catalyst and the Lewis basic starting triarylamine substrate was also investigated by steady state UV-vis spectroscopy and (19)F NMR.