UndPipdA | 61797-73-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: UndPipdA
• 英文别名: 1,4-di-undec-10-enoyl-piperazine；1,4-Di-undec-10-enoyl-piperazin；1,1'-(Piperazine-1,4-diyl)di(undec-10-en-1-one)；1-(4-undec-10-enoylpiperazin-1-yl)undec-10-en-1-one
• CAS: 61797-73-7
• 化学式: C₂₆H₄₆N₂O₂
• 分子量: 418.663
• InChiKey: JWMDZSPVSWYGIZ-UHFFFAOYSA-N

物化性质

• 沸点：
  576.9±50.0 °C(Predicted)
• 密度：
  0.954±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  30
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  UndPipdA 在 四丁基溴化铵 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 20.0~80.0 ℃ 、5.0 MPa 条件下， 反应 48.0h， 生成 UndPipdA-b5CC
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a
• 作为产物：
  描述：

  哌嗪 、 10-烯酸甲酯 在 1,5,7-三氮杂双环[4.4.0]癸-5-烯 作用下， 反应 8.0h， 以68.2%的产率得到UndPipdA
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a

文献信息

• Five-membered cyclic biscarbonates bearing amide linkages, their preparation and their uses for the preparation of polyhydroxyurethanes
  申请人：UNIVERSITE DE BORDEAUX I

  公开号：EP2883872A1

  公开（公告）日：2015-06-17

  The invention relates to a compound of formula (I): wherein A1 and A1' are independently from each other a linear or branched alkylene radical comprising from 1 to 20 carbon atom(s); A2 is in particular a linear or branched alkylene radical comprising from 1 to 200 carbon atom(s); A3 is H or a linear or branched alkyl radical comprising from 1 to 15 carbon atom(s) and R1 and R1' are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The present invention concerns the compounds of formula (I), their preparation and their uses, in particular for the preparation of poly(hydroxyurethane)s.

  本发明涉及一种公式（I）的化合物： 其中A1和A1'独立地彼此为含有1至20个碳原子的线性或支链烷基；A2特别是含有1至200个碳原子的线性或支链烷基；A3是H或含有1至15个碳原子的线性或支链烷基，而R1和R1'独立地彼此为H或含有1至20个碳原子的线性或支链烷基。 本发明涉及公式（I）的化合物，它们的制备以及它们的使用，特别是用于制备聚（羟基聚氨酯）。
• [EN] FIVE-MEMBERED CYCLIC BISCARBONATES BEARING AMIDE LINKAGES, THEIR PREPARATION AND THEIR USES FOR THE PREPARATION OF POLYMERS<br/>[FR] BICARBONATES CYCLIQUES À CINQ CHAÎNONS PORTANT DES LIAISONS AMIDE, LEUR PRÉPARATION ET LEURS UTILISATIONS EN VUE DE LA PRÉPARATION DE POLYMÈRES
  申请人：UNIV BORDEAUX

  公开号：WO2015091494A1

  公开（公告）日：2015-06-25

  The invention relates to a compound of formula (I) wherein and A1 and A1' are independently from each other a linear or branched alkylene radical comprising from 1 to 20 carbon atom(s); A2 is in particular a linear or branched alkylene radical comprising from 1 to 200 carbon atom(s); A3 is H or a linear or branched alkyl radical comprising from 1 to 15 carbon atom(s) and R1 and R1' are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The present invention concerns the compounds of formula (I), their preparation and their uses, in particular for the preparation of poly(hydroxyurethane)s and epoxy resins.

  本发明涉及一种公式（I）的化合物，其中A1和A1'独立地彼此为含有1至20个碳原子的线性或支链烷基自由基；A2特别是含有1至200个碳原子的线性或支链烷基自由基；A3是H或含有1至15个碳原子的线性或支链烷基自由基，以及R1和R1'独立地彼此为H或含有1至20个碳原子的线性或支链烷基自由基。本发明涉及公式（I）的化合物、它们的制备及其用途，特别是用于制备聚（羟基聚氨酯）和环氧树脂。
• Sziki, 1936, vol. 54, p. 807,818
  作者：Sziki

  DOI：——

  日期：——
• FIVE-MEMBERED CYCLIC BISCARBONATES BEARING AMIDE LINKAGES, THEIR PREPARATION AND THEIR USES FOR THE PREPARATION OF POLYMERS
  申请人：UNIVERSITÉ DE BORDEAUX

  公开号：US20160326132A1

  公开（公告）日：2016-11-10

  A compound is of formula (I): in which A 1 and A 1 ′ are independently from each other a linear or branched alkylene radical including from 1 to 20 carbon atom(s); A 2 is in particular a linear or branched alkylene radical including from 1 to 200 carbon atom(s); A 3 is H or a linear or branched alkyl radical including from 1 to 15 carbon atom(s) and R 1 and R 1 ′ are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The compounds of formula (I) can be used in particular for the preparation of poly(hydroxyurethane)s and epoxy resins.
• US9926288B2
  申请人：——

  公开号：US9926288B2

  公开（公告）日：2018-03-27