9-[3-[4-[1-[4-[3-(6-Aminopurin-9-yl)propoxy]phenyl]-2,2-diphenylethenyl]phenoxy]propyl]purin-6-amine | 1067211-25-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 9-[3-[4-[1-[4-[3-(6-Aminopurin-9-yl)propoxy]phenyl]-2,2-diphenylethenyl]phenoxy]propyl]purin-6-amine
• 英文别名: 9-[3-[4-[1-[4-[3-(6-aminopurin-9-yl)propoxy]phenyl]-2,2-diphenylethenyl]phenoxy]propyl]purin-6-amine
• CAS: 1067211-25-9
• 化学式: C₄₂H₃₈N₁₀O₂
• 分子量: 714.83
• InChiKey: LZUFFRQGFZJFBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  54
• 可旋转键数：
  14
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  158
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1-(3-Bromopropoxy)-4-[1-[4-(3-bromopropoxy)phenyl]-2,2-diphenylethenyl]benzene 、 腺嘌呤 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 36.0h， 以67.2%的产率得到9-[3-[4-[1-[4-[3-(6-Aminopurin-9-yl)propoxy]phenyl]-2,2-diphenylethenyl]phenoxy]propyl]purin-6-amine
  参考文献：
  名称：

  Fluorescence “Turn On” Chemosensors for Ag⁺ and Hg²⁺ Based on Tetraphenylethylene Motif Featuring Adenine and Thymine Moieties

  摘要：

  Two new tetraphenylethylene (TPE) compounds 1 and 2 bearing adenine and thymine moieties, respectively, were found to be fluorescence "turn on" chemosensors for Ag+ and Hg2+ by making use of the AIE feature of TPE motif and the specific binding of adenine/thymine with Ag+/Hg2+.

  DOI：

  10.1021/ol801855s

文献信息

• System and method for detection of silver
  申请人：ALVEO Technologies Inc.

  公开号：US10352899B2

  公开（公告）日：2019-07-16

  Embodiments provide silver detection systems and methods for detecting the presence of silver ions in one or more samples. In a detection method, a sample and TPEA2 molecules are introduced into a channel. A first potential difference is applied across the length of the channel in a first direction, and a first electrical property value is detected. Subsequently, a second potential difference is applied across the length of the channel in a second opposite direction, and a second electrical property value is detected. Presence or absence of silver ions in the channel is determined based on a comparison between the first and second electrical property values.

  本发明实施例提供了用于检测一个或多个样品中是否存在银离子的银检测系统和方法。在一种检测方法中，样品和 TPEA2 分子被引入通道。在通道长度上沿第一方向施加第一电位差，检测第一电特性值。随后，在通道长度上沿第二个相反方向施加第二个电位差，检测第二个电特性值。根据第一和第二电特性值之间的比较，确定通道中是否存在银离子。
• System and Method for Detection of Silver
  申请人：ALVEO Technologies Inc.

  公开号：US20160097741A1

  公开（公告）日：2016-04-07

  Embodiments provide silver detection systems and methods for detecting the presence of silver ions in one or more samples. In a detection method, a sample and TPEA2 molecules are introduced into a channel. A first potential difference is applied across the length of the channel in a first direction, and a first electrical property value is detected. Subsequently, a second potential difference is applied across the length of the channel in a second opposite direction, and a second electrical property value is detected. Presence or absence of silver ions in the channel is determined based on a comparison between the first and second electrical property values.
• Fluorescence “Turn On” Chemosensors for Ag⁺ and Hg²⁺ Based on Tetraphenylethylene Motif Featuring Adenine and Thymine Moieties
  作者：Lei Liu、Guanxin Zhang、Junfeng Xiang、Deqing Zhang、Daoben Zhu

  DOI：10.1021/ol801855s

  日期：2008.10.16

  Two new tetraphenylethylene (TPE) compounds 1 and 2 bearing adenine and thymine moieties, respectively, were found to be fluorescence "turn on" chemosensors for Ag+ and Hg2+ by making use of the AIE feature of TPE motif and the specific binding of adenine/thymine with Ag+/Hg2+.