1,1-bis((4-methoxyphenyl)ethynyl)-2,3,4,5-tetraphenylgermole | 1310709-99-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,1-bis((4-methoxyphenyl)ethynyl)-2,3,4,5-tetraphenylgermole
• 英文别名: 1,1-Bis[2-(4-methoxyphenyl)ethynyl]-2,3,4,5-tetraphenylgermole；1,1-bis[2-(4-methoxyphenyl)ethynyl]-2,3,4,5-tetraphenylgermole
• CAS: 1310709-99-9
• 化学式: C₄₆H₃₄GeO₂
• 分子量: 691.365
• InChiKey: VUMHKAQQXWOFER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.95
• 重原子数：
  49
• 可旋转键数：
  10
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene 、 4-乙炔基苯甲醚 在 n-butyl lithium 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以58%的产率得到1,1-bis((4-methoxyphenyl)ethynyl)-2,3,4,5-tetraphenylgermole
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structures of 1,1-Disubstituted-2,3,4,5-tetraphenylgermoles That Exhibit Aggregation-Induced Emission

  摘要：

  A series of 2,3,4,5-tetraphenylgermoles with different 1,1-substituents have been prepared, and their UV-vis absorption and fluorescence spectral profiles in solution were determined. A thin-layer chromatography based method was used to measure their solid-state luminescence. Nine of the 11 new germoles have been characterized crystallographically. The aggregation-induced emission effect in these germoles was studied, and significant enhancement of the photoluminescence and quantum yield in mixed solvent-water systems was determined. Scanning and transmission electron microscopy analysis revealed the formation of nanocrystalline aggregates in the mixed solvent-water systems and after exposure of the germoles to acetone, a volatile organic chemical.

  DOI：

  10.1021/om200259n