A non-aqueous laminate adhesive comprising a tertiary amino group-containing polyurethane resin (A) or a tertiary amino group- and carboxyl group-containing polyurethane resin (B) and a polyisocyanate curing agent. The resin (A) is obtained from (1) an active hydrogen group-containing compound comprising at least a tertiary amino group- and hydroxyl group-containing compound and (3) an organic polyisocyanate; and the resin (B) is obtained from (2) an active hydrogen group-containing compound comprising at least a tertiary amino group- and hydroxyl group-containing compound and a carboxyl group- and hydroxyl group-containing compound and (3) an organic polyisocyanate. The content of the tertiary amino group in the resin (A), the content of the tertiary amino group in the resin (B), and the carboxyl group in the resin (B) are each 0.001 to 1 mmol/g.
The non-aqueous laminate adhesive has a short aging time, a long pot life and good storage stability, all of which have been unachievable with conventional laminate adhesives.
一种非
水性层压板粘合剂,由含叔
氨基的聚
氨酯
树脂(A)或含叔
氨基和羧基的聚
氨酯
树脂(B)和多
异氰酸酯固化剂组成。
树脂(A)由(1)一种含活性氢基的化合物(至少包括一种含叔
氨基和羟基的化合物)和(3)一种有机多
异氰酸酯制成;
树脂(B)由(2)一种含活性氢基的化合物(至少包括一种含叔
氨基和羟基的化合物、一种含羧基和羟基的化合物)和(3)一种有机多
异氰酸酯制成。
树脂(A)中叔
氨基的含量、
树脂(B)中叔
氨基的含量和
树脂(B)中羧基的含量各为 0.001 至 1 毫摩尔/克。
这种非
水性层压板粘合剂具有老化时间短、罐内寿命长和良好的储存稳定性,所有这些都是传统层压板粘合剂无法达到的。