Cyclohexyl sulfate | 3233-51-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: Cyclohexyl sulfate
• 英文别名: sulfuric acid monocyclohexyl ester；Schwefelsaeure-monocyclohexylester；Cyclohexyl-hydrogensulfat；Cyclohexanol-O-sulfonsaeure；Cyclohexylhydrogensulfat；Cyclohexylschwefelsaeure；Cyclohexyl hydrogen sulfate
• CAS: 3233-51-0
• 化学式: C₆H₁₂O₄S
• 分子量: 180.225
• InChiKey: UCZUCGRGTXIWLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  72
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2906199090

反应信息

• 作为反应物：
  描述：

  Cyclohexyl sulfate 、 苯 在 硫酸 作用下， 生成 环己基苯
  参考文献：
  名称：

  DE515177

  摘要：

  公开号：
• 作为产物：
  描述：

  环己烯 在 硫酸 作用下， 生成 Cyclohexyl sulfate
  参考文献：
  名称：

  Two- and Three-Dimensional Photonic Crystals Built with VLSI Tools

  摘要：

  朝向微型光子器件的发展受到了我们无法紧密控制和操作光线的限制。此外，光子技术通常不基于硅，直到最近才间接受益于硅处理技术的迅速进步。本文的第一部分将讨论使用硅处理成功制造三维（3D）光子晶体的进展。这一进展得益于集成电路（IC）制造技术（例如，大规模集成，VLSI）的应用，可能使硅处理渗透到光子学中。在第二部分中，我们描述了在λ = 1.55 μm通信波长下运行的2D光子晶体板的创建。这类2D光子晶体对于平面芯片引导、困禁和光开关非常有前景。

  DOI：

  10.1557/mrs2001.157

文献信息

• PHARMACEUTICAL COMPOUNDS FOR USE IN THE THERAPY OF CLOSTRIDIUM DIFFICILE INFECTION
  申请人：ETH ZURICH

  公开号：US20140235590A1

  公开（公告）日：2014-08-21

  The invention relates to a compound described by a general formula (1), wherein each X independently can be OPO 3 2− , OPSO 2 2− or OSO 3 − ; R 1 comprises a solubility function such as a polyethylene glycol moiety and each X independently can be OPO 3 2− , OPSO 2 2− , − or OSO 3 − ; and Z is an alkyl chain comprising 1 to 3 carbon and/or hetero atoms. The invention further relates to polysulfate derivatives or mixed polyphosphate/sulphate derivatives of six-membered cyclic polyols for use in the therapy of infection by Clostridium difficile.

  本发明涉及一种由一般式（1）描述的化合物，其中每个X可以独立地是OPO32−、OPSO22−或OSO3−；R1包括诸如聚乙二醇基团之类的溶解度功能，每个X可以独立地是OPO32−、OPSO22−或OSO3−；Z是由1到3个碳和/或杂原子组成的烷基链。本发明还涉及六元环多醇的聚硫酸盐衍生物或混合聚磷酸盐/硫酸盐衍生物，用于治疗Clostridium difficile感染。
• Method for the preparation of cyclohexanol and/or cyclohexanone
  申请人：STAMICARBON B.V.

  公开号：EP0023379A2

  公开（公告）日：1981-02-04

  The invention relates to a method for the preparation of cyclohexanol and/or cyclohexanone by hydrogenating benzene to cyclohexene, hydrating the cyclohexene to cyclohexanol and/or oxidating it to cyclohexanone, recovering the cyclohexanol and/or cyclohexanone, and returning unconverted benzene and/or cyclohexene to the hydrogenating step. The method according to the invention is characterized in that the mixture of cyclohexane with benzene and/or cyclohexene, which has also been obtained during the separation of cyclohexanol from the reaction mixture of the hydration step and,or of cyclohexanone from the reaction mixture of the oxidation step, is subjected to a dehydrogenation reaction, and the benzene thus obtained is returned to the hydrogenation step. The method according to the invention has the great advantage that the difficult separation of cyclohexane from mixtures with benzene and/or cyclohexene can be dispensed with. Losses of expensive extractive distillation agent are avoided. Neither is any cyclohexane left as by-product for wich a use will have to be found. In the hydrogenation step a higher degree of benzene conversion can be applied, so that economic process operation has become possible.

  本发明涉及一种制备环己醇和/或环己酮的方法，该方法通过将苯加氢为环己烯，将环己烯水合为环己醇和/或氧化为环己酮，回收环己醇和/或环己酮，并将未转化的苯和/或环己烯返回加氢步骤。 根据本发明的方法，其特征在于环己烷与苯和/或环己烯的混合物（该混合物也是在从水合步骤的反应混合物中分离环己醇，或从氧化步骤的反应混合物中分离环己酮的过程中得到的）要进行脱氢反应，由此得到的苯要返回加氢步骤。 根据本发明的方法有一个很大的优点，即可以省去从含有苯和/或环己烯的混合物中分离环己烷的困难过程。避免了昂贵的萃取蒸馏剂的损失。也不会留下任何环己烷作为副产品，而这些副产品还需要寻找用途。在加氢步骤中，可以采用更高的苯转化率，从而实现经济的工艺操作。
• Process for the preparation of cyclohexanol and/or cyclohexanone
  申请人：STAMICARBON B.V.

  公开号：EP0053847A1

  公开（公告）日：1982-06-16

  The invention relates to a process for the preparation of cyclohexanol and/or cyclohexanone from cyclohexane, in which process the cyclohexane is dehydrogenated to cyclohexene preferably at a temperature of 200 to 700°C and a pressure of 0.01 to 10 Mpa, the cyclohexene hydrated to cyclohexanol preferably at a temperature of -50 to 150°C and a pressure of 0.01 to 10 MPa, and/or oxidized to cyclohexanone preferably at a temperature of 0 to 350°C and a pressure of 0.01 to 200 MPa, the cyclohexanol and/or the cyclohexanone separated, and the unconverted cyclohexane and/or cyclohexene returned to the dehydrogenation step.

  本发明涉及一种从环己烷制备环己醇和/或环己酮的工艺，在该工艺中，环己烷最好在200至700℃的温度和0.01至10兆帕的压力下脱氢为环己烯，环己烯最好在-50至150℃的温度和0.01至10兆帕，和/或最好在0至350℃温度和0.01至200兆帕压力下氧化成环己酮，分离环己醇和/或环己酮，未转化的环己烷和/或环己烯返回脱氢步骤。
• NONAQUEOUS ELECTROLYTE SOLUTION FOR BATTERIES AND LITHIUM SECONDARY BATTERY
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3051619A1

  公开（公告）日：2016-08-03

  Anon-aqueous electrolyte solution for a battery includes: an additive A which is a compound represented by formula (I); and an additive B which is at least one selected from the group consisting of an aromatic compound having at least one of a halogen atom or an alkyl group and a carbamate, and which is a compound other than carbonates or a cyclic sulfates. In formula (I), R1 represents a group represented by formula (II) or a group represented by formula (III) and R2 represents H, a C1-6 alkyl group, a group represented by formula (II), or a group represented by formula (III); or R1 and R2 represent groups which combine to form a benzene ring or cyclohexyl ring. In formula (II), R3 represents a halogen atom, a C1-6 alkyl group, a C1-6 alkyl halide group, a C1-6 alkoxy group, or a group represented by formula (IV).

  用于电池的非水电解质溶液包括：添加剂 A，它是一种由式（I）表示的化合物；添加剂 B，它是至少一种选自具有卤素原子或烷基中至少一个的芳香族化合物和氨基甲酸酯组成的组的化合物，它是碳酸盐或环硫酸盐以外的化合物。在式 (I) 中，R1 代表式 (II) 所代表的基团或式 (III) 所代表的基团，R2 代表 H、C1-6 烷基、式 (II) 所代表的基团或式 (III) 所代表的基团；或 R1 和 R2 代表结合形成苯环或环己基环的基团。在式 (II) 中，R3 代表卤原子、C1-6 烷基、C1-6 烷基卤化物基团、C1-6 烷氧基或式 (IV) 所代表的基团。
• LITHIUM BORATE COMPOUND, ADDITIVE FOR LITHIUM SECONDARY BATTERY, NONAQUEOUS ELECTROLYTIC SOLUTION FOR LITHIUM SECONDARY BATTERY, PRECURSOR FOR LITHIUM SECONDARY BATTERY, AND PRODUCTION METHOD FOR LITHIUM SECONDARY BATTERY
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3939982A1

  公开（公告）日：2022-01-19

  A lithium borate compound represented by the following Formula (I). In Formula (I), each of R1, R2, and R3 independently represents a hydrocarbon group having from 1 to 20 carbon atoms, which may have a substituent. R10 represents a fluorine atom, a hydrocarbon-oxy group having from 1 to 10 carbon atoms, a hydrocarbon group having from 1 to 10 carbon atoms, or a fluorinated hydrocarbon group having from 1 to 10 carbon atoms.

  由下式（I）代表的硼酸锂化合物。在式（I）中，R1、R2 和 R3 各自独立地代表一个具有 1 至 20 个碳原子的烃基，该烃基可能具有一个取代基。R10 代表氟原子、具有 1 至 10 个碳原子的烃氧基、具有 1 至 10 个碳原子的烃基或具有 1 至 10 个碳原子的氟化烃基。