Di-tert-butyl-nitroxid | 44871-19-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧氮鎓化合物
• 英文名称: Di-tert-butyl-nitroxid
• 英文别名: di-tert-Butyl nitroxyl；ditert-butyl(oxo)azanium
• CAS: 44871-19-4
• 化学式: C₈H₁₈NO
• 分子量: 144.237
• InChiKey: ZYVDOMIPNQUMNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二叔丁基硝基氧 在 hexachloroiridate(IV) 作用下， 生成 Di-tert-butyl-nitroxid
  参考文献：
  名称：

  涉及叠氮基的电子转移反应

  摘要：

  DOI：

  10.1021/j100407a042

文献信息

• Method for the functionalization of conjugated or conjugatable derivatives assisted by a tempo-type electrophoric mediator
  申请人：Belgsir El Mustapha

  公开号：US20070197790A1

  公开（公告）日：2007-08-23

  The invention relates to a method for the functionalization of a chemical molecule having at least two double bonds or containing a double bond which is conjugated with a structure that is rich in electrons in the presence of a TEMPO-type electrophoric mediator and a nucleophilic agent. The functionalization method can also include a system for electrochemical regeneration of the electrophoric mediator.
• Alpha-Hydrogen Substituted Nitroxyls And Derivatives Thereof As Catalysts
  申请人：Technion Research and Development Foundation Ltd.

  公开号：US20140350258A1

  公开（公告）日：2014-11-27

  Novel alpha-hydrogen substituted nitroxyl compounds and their corresponding oxidized (oxoammonium cations) and reduced (hydroxylamine) forms, and the use of such compounds, inter alia, for oxidation of primary and secondary alcohols to aldehydes and ketones, respectively; resolution of racemic alcohols; desymmetrization of meso-alcohol; as radicals and spin trapping reagents; and as polymerization agents. Processes for preparing the novel nitroxyl/oxoammonium/hydroxylamine compounds from the corresponding amines, and certain novel amine derivatives and their uses. The compounds and amine precursors are useful as ligands for transition metals and as organocatalysts in e.g., aldol reactions.
• US9475774B2
  申请人：——

  公开号：US9475774B2

  公开（公告）日：2016-10-25
• Electron-transfer reactions involving the azidyl radical
  作者：M. S. Ram、David M. Stanbury

  DOI：10.1021/j100407a042

  日期：1986.7