1-ethoxy-1H-indene | 93271-82-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1-ethoxy-1H-indene
• CAS: 93271-82-0
• 化学式: C₁₁H₁₂O
• 分子量: 160.216
• InChiKey: GMOXCUVJJFXHHE-UHFFFAOYSA-N

物化性质

• 沸点：
  263.0±19.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙醇 、 茚 在 HgO*HBF₄ 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 1-ethoxy-1H-indene 、 1,2-Diethoxy-2,3-dihydro-1H-indene 、 2-茚酮
  参考文献：
  名称：

  Mercury(II) oxide/tetrafluoroboric acid-promoted vicinal hydroxy- and alkoxylation of alkenes

  摘要：

  DOI：

  10.1016/s0040-4020(01)83510-9

文献信息

• Curable resin composition
  申请人：Kawabe Masanao

  公开号：US20070129502A1

  公开（公告）日：2007-06-07

  Provided is curable resin composition which gives a cured article excellent in chemical resistance, dielectric properties, low water-absorption, heat resistance, flame retardance, and mechanical properties and which is usable in applications such as dielectric materials, insulating materials, heat-resistant materials, and structural materials. The curable resin composition includes a component (A) which is a polyphenylene ether oligomer having a number-average molecular weight of 700 to 4,000 and having a vinyl group at both end and a component (B) which is a solvent-soluble polyfunctional vinylaromatic copolymer which has structural units derived from monomers including a divinylaromatic compound (a) and an ethylvinylaromatic compound (b) and in which the content of repeating units derived from the divinylaromatic compound (a) is 20 mol % or higher, the ratio of the amount (wt. %) of the component (A) to that (wt. %) of the component (B) being (20 to 98):(2 to 80). The composition can further contain a layered silicate, a halogenated flame retardant, etc.

  提供了一种可治愈的树脂组合物，其使得固化后的制品具有出色的化学耐性、介电性能、低吸水性、耐热性、阻燃性和机械性能，并可用于介电材料、绝缘材料、耐热材料和结构材料等应用。该可治愈的树脂组合物包括以下组分：(A)是一种聚苯醚寡聚体，其具有700至4,000的数量平均分子量，并在两端具有乙烯基；(B)是一种可溶于溶剂的多功能乙烯基芳香族共聚物，其具有从单体中衍生出的结构单元，包括一种二乙烯基芳香族化合物(a)和一种乙基乙烯基芳香族化合物(b)，其中重复单元中来自二乙烯基芳香族化合物(a)的含量为20摩尔%或更高，组分(A)与组分(B)的重量比为(20至98)∶(2至80)。该组合物还可以进一步包含层状硅酸盐、卤素阻燃剂等。
• Resin composition, prepreg, resin-added film, resin-added metal foil, metal-clad layered plate, and wiring plate
  申请人：PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.

  公开号：US11242425B2

  公开（公告）日：2022-02-08

  A resin composition is provided and contains a compound (A) having at least one group represented by the following Formula (1) in a molecule, a crosslinking type curing agent (B), and an azo compound (C) that has an azo group in a molecule and has no heteroatom other than a nitrogen atom constituting the azo group. In Formula (1), n represents 0 to 10, Z represents an arylene group, and R1 to R3 each independently represent a hydrogen atom or an alkyl group.

  本发明提供了一种树脂组合物，其中包含分子中至少含有一个下式 (1) 所代表基团的化合物 (A)、交联型固化剂 (B) 以及分子中含有偶氮基团且除构成偶氮基团的氮原子外没有杂原子的偶氮化合物 (C)。 式（1）中，n 代表 0 至 10，Z 代表芳烯基，R1 至 R3 各自独立地代表氢原子或烷基。
• Curable resin compositions
  申请人：Kawabe Masanao

  公开号：US20060177666A1

  公开（公告）日：2006-08-10

  This invention relates to a curable resin composition which shows excellent chemical resistance, dielectric characteristics, heat resistance, flame retardancy and mechanical properties and low water absorption and is suitable for dielectric materials, insulating materials, heat-resistant materials, structural materials and the like. This curable resin composition comprises component (A) or polyphenylene ether resin and component (B) or a solvent-soluble polyfunctional vinyl aromatic copolymer having constitutional units derived from monomers composed of divinyl aromatic compound (a) and monovinyl aromatic compound (b) or, more particularly, having 20 mol % or more of a repeating unit derived from divinyl aromatic compound (a) and constitutional units represented by the following formulas (2) and (3) wherein R 5 represents an aromatic hydrocarbon group containing 6-30 carbon atoms, Y represents an aliphatic hydrocarbon group, an aromatic hydrocarbon group or an unsubstituted or substituted aromatic ring condensed with the benzene ring of the indane ring and n is an integer of 0-4.

  本发明涉及一种可固化树脂组合物，该组合物具有优异的耐化学性、绝缘性、耐热性、阻燃性和机械性能，且吸水性低，适用于绝缘材料、绝缘材料、耐热材料、结构材料等。这种可固化树脂组合物由组分（A）或聚苯醚树脂和组分（B）或溶剂可溶的多官能度乙烯基芳香族共聚物组成，该共聚物具有由二乙烯基芳香族化合物（a）和单乙烯基芳香族化合物（b）组成的单体衍生出的构型单元，或者更具体地说，具有 20 摩尔%或更多的由二乙烯基芳香族化合物（a）衍生出的重复单元和由以下公式（2）和（3）表示的构型单元 其中 R 5 代表含有 6-30 个碳原子的芳香烃基团，Y 代表脂肪烃基团、芳香烃基团或与茚环的苯环缩合的未取代或取代的芳香环，n 为 0-4 的整数。
• BARLUENGA, J.;ALONSO-CIRES, L.;CAMPOS, P. J.;ASENSIO, G., TETRAHEDRON, 1984, 40, N 13, 2563-2568
  作者：BARLUENGA, J.、ALONSO-CIRES, L.、CAMPOS, P. J.、ASENSIO, G.

  DOI：——

  日期：——
• Soluble polyfunctional vinyl aromatic polymer and method of producing the same
  申请人：Kawabe Masanao

  公开号：US20070155923A1

  公开（公告）日：2007-07-05

  The present invention relates to a soluble polyfunctional vinylaromatic copolymer improved in heat resistance, resistance to thermal decomposition, solvent solubility, and processability. The soluble polyfunctional vinylaromatic polymer is obtained by cationically polymerizing, at a temperature of 20 to 120° C., one or more monomer ingredients including 20 to 100 mol % divinylaromatic compound (a) in the presence of a donor ingredient, e.g., a quaternary ammonium salt, with the aid of a Lewis acid catalyst and an initiator represented by the following general formula (1) wherein R 1 represents hydrogen or a monovalent C 1-6 hydrocarbon group; R 2 represents an aromatic or aliphatic hydrocarbon group having a valence of p; Z represents halogen or C 1-6 alkoxy or acyloxy; and p is an integer of 1 to 6; provided that when two or more R 1 's and Z's are present per molecule, they may be identical to different from each other.