3,十二甲烷基铵碘化物 | 29710-98-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 3,十二甲烷基铵碘化物
• 中文别名: 甲基三(十二烷基)碘化铵；三十二基甲基碘化铵；三-十二烷基甲基碘化铵；三十二烷基甲基碘化铵
• 英文名称: Tridodecylmethylammonium iodide
• 英文别名: tridodecyl(methyl)azanium;iodide
• CAS: 29710-98-3
• 化学式: C37H78IN
• 分子量: 663.9
• InChiKey: JRLISGAUAJZAGL-UHFFFAOYSA-M

物化性质

• 熔点：
  106-107 °C(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  39
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 安全说明：
  S22,S24/25
• WGK Germany：
  3
• 海关编码：
  2923900090

文献信息

• Process for the synthesis of 9-hydroxy risperidone (paliperidone)
  申请人：Ini Santiago

  公开号：US20080171875A1

  公开（公告）日：2008-07-17

  The present invention relates to a process for preparing paliperidone from its intermediate 3-(2-chloroethyl)-6,7,8,9-tetrahydro-9-hydroxy-2-methyl-4H-pyrrido[1,2-a]-pyrimidin-4-one.

  本发明涉及一种从其中间体3-(2-氯乙基)-6,7,8,9-四氢-9-羟基-2-甲基-4H-吡咯[1,2-a]-嘧啶-4-酮制备帕利哌酮的过程。
• Process for producing 1-hydrocarbyl mercaptans
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0268261A1

  公开（公告）日：1988-05-25

  A process is disclosed for producing 1-hydrocarbyl mercaptans which comprises reacting a 1-hydrocarbyl halide with an alkali hydrogen sulfide or an ammonium hydrogen sulfide in the presence of a quaternary ammonium halide, which serves as a phase transfer catalyst.

  本发明公开了一种生产 1-氢羰基硫醇的工艺，该工艺包括在作为相转移催化剂的季铵盐化物存在下，使 1-氢羰基卤化物与碱硫化氢或硫化氢铵反应。
• Oil soluble iodides as lubricant antioxidants
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0727475A2

  公开（公告）日：1996-08-21

  The present invention provides for the use of certain oil soluble iodides to enhance the oxidation resistance of lubricating oils and fuels, and for the novel formulated compositions containing these iodides. Oil soluble iodides such as C16 to C78 alkyl ammonium as well as oil solubilizable or dispersible iodides such as CoI2, CuI, KI and NaI in combination with a suitable dispersing agent may be used. Typically a minor amount of additive, from about 40 to about 1000 ppm is used. The additive is effective as an antioxidant in a variety of different types of base and formulated oils.

  本发明提供了使用某些油溶性碘化物来增强润滑油和燃料抗氧化性的方法，以及含有这些碘化物的新型配方组合物。油溶性碘化物（如 C16 至 C78 烷基铵）以及油溶性或分散性碘化物（如 CoI2、CuI、KI 和 NaI）与合适的分散剂结合使用。通常使用少量添加剂，约为 40 至 1000 ppm。添加剂在各种不同类型的基础油和配制油中作为抗氧化剂都很有效。
• POLYMERIZABLE COMPOSITION FOR POLYTHIOURETHANE OPTICAL MATERIAL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1988109A1

  公开（公告）日：2008-11-05

  A polymerizable composition for polythiourethane optical materials comprising a compound represented by the general formula (1),         M(L)n     (1) wherein, in the formula, M is Al, Fe, Cu, Zn, Zr or Bi; L is a dithiocarbamic acid group, a sulfonic acid group, a mono- or di-alkyl phosphoric acid ester group, a substituted acetylacetonato group or a halogen; and n is an integer of 1 to 5, one or two or more isocyanates selected from the group consisting of isocyanate compounds and isothiocyanate compounds, and one or two or more active hydrogen compounds each having a mercapto group. The compounds represented by the general formula (1) exhibit catalytic activity equal to or superior to that of organotin catalysts having been employed as catalysts for the production of polythiourethane optical materials from the past, and have high safety. Further, the thus obtained polythiourethane resins satisfactorily meet the property requirements for optical materials, in particular, excelling in weather resistance. Therefore, the proposed catalysts are available as novel catalysts replacing the organotin catalysts.

  一种用于聚硫乙烷光学材料的可聚合组合物，由通式 (1) 所代表的化合物组成、 M(L)n (1) 式中，M 是 Al、Fe、Cu、Zn、Zr 或 Bi；L 是二硫代氨基甲酸基团、磺酸基团、单烷基或二烷基磷酸酯基团、取代的乙酰丙酮基团或卤素；n 是 1 至 5 的整数、 一种或两种或多种异氰酸酯，选自异氰酸酯化合物和异硫氰酸酯化合物组成的组，以及 一种或两种或多种活性氢化合物，每种活性氢化合物都带有一个巯基。通式（1）所代表的化合物的催化活性等同于或优于过去用作生产聚硫乙烷光学材料催化剂的有机锡催化剂，而且安全性高。此外，由此获得的聚硫乙烷树脂还能满足光学材料的性能要求，特别是在耐候性方面表现出色。因此，所提出的催化剂可作为新型催化剂替代有机锡催化剂。
• POLYMERIZABLE COMPOUND FOR OPTICAL MATERIAL, OPTICAL MATERIAL, AND OPTICAL MATERIAL MANUFACTURING METHOD
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2341091A1

  公开（公告）日：2011-07-06

  The polymerizable composition for an optical material of the present invention comprises a phenylene diisocyanate, at least one polythiol compound selected from the group consisting of 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane, 4,8-, 4,7- or 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane, 2,5-bis(mercaptomethyl)-1,4-dithiane, bis(mercaptoethyl)sulfide, 1,1,3,3-tetrakis(mercaptomethylthio)propane, 4,6-bis(mercaptomethylthio)-1,3-dithiane, 2-(2,2-bis(mercaptomethylthio)ethyl)-1,3-dithietane, 1,1,2,2-tetrakis(mercaptomethylthio)ethane 3-mercaptomethyl-1,5-dimercapto-2,4-dithiapentane and tris(mercaptomethylthio)methane.

  用于本发明光学材料的可聚合组合物包括亚苯基二异氰酸酯、至少一种选自以下组别的聚硫醇化合物：4-巯甲基-1,8-二巯基-3,6-二硫代辛烷、4,8-、4,7-或 5,7-二巯甲基-1,11-二巯基-3,6,9-三硫代十一烷、2、5-双（巯甲基）-1,4-二噻烷、双（巯基乙基）硫醚、1,1,3,3-四（巯甲基硫基）丙烷、4,6-双（巯甲基硫基）-1,3-二噻烷、2-（2、1,3-二噻烷、1,1,2,2-四（巯甲基硫基）乙烷、3-巯甲基-1,5-二巯基-2,4-二硫戊烷和三（巯甲基硫基）甲烷。