3,2':3',3"-terthiophene | 106032-17-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 3,2':3',3"-terthiophene
• 英文别名: 3,2':3',3"-terthienyl；3,2':3',3''-terthiophene；2,3-di(thiophen-3-yl)thiophene
• CAS: 106032-17-1
• 化学式: C₁₂H₈S₃
• 分子量: 248.394
• InChiKey: NVKLSOLRWOMZLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,2':3',3"-terthiophene 在 碘 作用下， 以 甲苯 为溶剂， 生成 苯并[1,2-b:3,4-b':5,6-b'']三噻吩 、 benzo<1,2-b:3,4-b':6,5-b''>trithiophene
  参考文献：
  名称：

  Photocyclization of terthiophenes

  摘要：

  DOI：

  10.1021/jo00278a039
• 作为产物：
  描述：

  2,3-二溴噻吩 、 magnesium,3H-thiophen-3-ide,bromide 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 作用下， 以 乙醚 为溶剂， 反应 48.0h， 以77%的产率得到3,2':3',3"-terthiophene
  参考文献：
  名称：

  Jayasuriya, Nimal; Kagan, Jacques, Heterocycles, 1986, vol. 24, # 8, p. 2261 - 2264

  摘要：

  DOI：

文献信息

• Organic compound having functional groups different in elimination reactivity at both terminals, organic thin film, organic device and method of producing the same
  申请人：Imada Hiroshi

  公开号：US20070195576A1

  公开（公告）日：2007-08-23

  Provided are a single monomolecular film uniform in film thickness and highly ordered in molecule alignment and its multilayer film, an organic compound allowing production of such films at high reproducibility, an organic device superior in electroconductive properties and a method of producing the same. An organic compound represented by Formula: Si(A 1 )(A 2 )(A 3 )-B—Si(A 4 )(A 5 )(A 6 ) (A 1 to A 6 each represent a hydrogen atom, a halogen atom, an alkoxy group or an alkyl group and satisfy the relationship in elimination reactivity of: A 1 to A 3 >A 4 to A 6 ; and B represents a bivalent organic group), an organic thin film using the compound, and an organic device having the thin film; A method of producing an organic thin film and organic device, comprising a step of forming a single monomolecular film by allowing the silyl group having A 1 to A 3 in the organic compound to react with the substrate surface; a step of removing unreacted organic compounds by using a non-aqueous solvent; and a step of forming an additional monomolecular film of the organic compound by using the unreacted silyl groups present on the film surface side of the monomolecular film obtained as the sites for adsorption reaction.

  提供了一种在薄膜厚度上均匀且分子排列高度有序的单分子膜以及其多层膜，一种有机化合物可在高可重复性下制备这种膜，一种优越于导电性能的有机器件以及其生产方法。一种由化学式表示的有机化合物：Si(A1)(A2)(A3)-B—Si(A4)(A5)(A6)（其中A1到A6分别表示氢原子、卤素原子、烷氧基或烷基，并满足消除反应性的关系：A1到A3>A4到A6；B表示二价有机基），使用该化合物的有机薄膜，以及具有该薄膜的有机器件；一种制备有机薄膜和有机器件的方法，包括以下步骤：通过使具有A1到A3的硅基团与基底表面反应形成单分子膜；使用非水溶剂去除未反应的有机化合物；通过利用单分子膜表面上存在的未反应硅基团作为吸附反应位点形成有机化合物的额外单分子膜。
• FUSED POLYCYCLIC COMPOUNDS AND ORGANIC LIGHT-EMITTING DEVICE USING THE SAME
  申请人：Yamada Naoki

  公开号：US20090189518A1

  公开（公告）日：2009-07-30

  A fused polycyclic compounds is represented by the general formula (I): wherein X 1 to X 18 each represent, independently of one another, a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted amino group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group.

  一个融合的多环化合物由通式(I)表示：其中X1到X18分别独立地表示氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基烷基、取代氨基、取代或未取代的芳基或取代或未取代的杂环基。
• [EN] MONOAMINO COMPOUND AND ORGANIC LUMINESCENCE DEVICE USING THE SAME<br/>[FR] COMPOSE MONOAMINO ET DISPOSITIF LUMINESCENT ORGANIQUE COMPRENANT CE DERNIER
  申请人：CANON KK

  公开号：WO2004020388A1

  公开（公告）日：2004-03-11

  A novel monoamino compound is provided. Using the monoamino compound, an organic luminescence device is provided, which exhibits a luminescence hue with extremely high purity, and having an optical output of a high luminance with a high efficiency and a long life time. The monoamino compound is represented by the following general formula [1].

  提供了一种新型的单氨基化合物。利用这种单氨基化合物，提供了一种有机发光器件，其显示出极高纯度的发光色调，并具有高亮度、高效率和长寿命的光学输出。该单氨基化合物由以下一般式[1]表示。
• HOLE TRANSPORT COMPOSITIONS AND RELATED DEVICES AND METHODS (I)
  申请人：Brown Christopher T.

  公开号：US20120001127A1

  公开（公告）日：2012-01-05

  A composition comprising: at least one compound comprising a hole transporting core, wherein the core is covalently bonded to a first arylamine group and also covalently bonded to a second arylamine group different from the first, and wherein the compound is covalently bonded to at least one intractability group, wherein the intractability group is covalently bonded to the hole transporting core, the first arylamine group, the second arylamine group, or a combination thereof, and wherein the compound has a molecular weight of about 5,000 g/mole or less. Blended mixtures of arylamine compounds, including fluorene core compounds, can provide good film formation and stability when coated onto hole injection layers. Solution processing of OLEDs is a particularly important application.

  一种组分，包括：至少一种包含传输空穴核的化合物，其中该核与第一芳胺基团和与第一芳胺基团不同的第二芳胺基团共价键合，且该化合物与至少一种难溶性基团共价键合，其中该难溶性基团与传输空穴核、第一芳胺基团、第二芳胺基团或其组合之一共价键合，且该化合物的分子量约为5,000克/摩尔或更低。芳胺化合物的混合物，包括芴核化合物，当涂覆到空穴注入层时，可以提供良好的膜形成和稳定性。 OLEDs的溶液处理是一个特别重要的应用。
• [EN] FLUORENE COMPOUND AND ORGANIC LUMINESCENT DEVICE USING THE SAME<br/>[FR] COMPOSE DE FLUORENE ET DISPOSITIF ELECTROLUMINESCENT ORGANIQUE UTILISANT UN TEL COMPOSE
  申请人：CANON KK

  公开号：WO2004020372A1

  公开（公告）日：2004-03-11

  A fluorene compound represented by the following general formula [I]: is used to provide an organic luminescent device. Such a device has an optical output exhibiting a high luminance with an extremely high efficiency, and has an extremely high durability.

  由以下一般公式[I]表示的萘化合物被用于制造有机发光器件。这样的器件具有高亮度的光学输出，效率极高，并且具有极高的耐久性。