13H,15H-bisbenzimidazo<1,2-a:1',2'-d>benzo<1,2-c:4',5'-c'>dipyrrol-13,15-dion | 4506-63-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 13H,15H-bisbenzimidazo<1,2-a:1',2'-d>benzo<1,2-c:4',5'-c'>dipyrrol-13,15-dion
• 英文别名: Terephthaloylen-bis-benzimidazol；13H,15H-bisbenzimidazo[1,2-a:1',2'-a']benzo[1,2-c:5,4-c']dipyrrole-13,15-dione；benzo[4,5]imidazo[2,1-a]benzo[4',5']imidazo[1',2':1,2]pyrrolo[4,3-f]isoindole-13,15-dione；5,12,18,25-Tetrazaheptacyclo[14.10.0.03,14.04,12.06,11.018,26.019,24]hexacosa-1(16),2,4,6,8,10,14,19,21,23,25-undecaene-13,17-dione
• CAS: 4506-63-2
• 化学式: C₂₂H₁₀N₄O₂
• 分子量: 362.347
• InChiKey: VHFKBDCAWGJYJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2.5-Bis(methoxycarbonyl)-N.N'-bis(o-aminophenyl)terephthalamid 生成 13H,15H-bisbenzimidazo<1,2-a:1',2'-d>benzo<1,2-c:4',5'-c'>dipyrrol-13,15-dion
  参考文献：
  名称：

  KORSHAK V. V.; BERESTNEVA G. L.; DOROSHENKO YU. E.; POSTNIKOVA L. V.; XOM+, IZV. AN CCCP. CEP. XIM., 1978, HO 2, 422-426

  摘要：

  DOI：

文献信息

• Green Synthesis of Polycyclic Benzimidazole Derivatives and Organic Semiconductors
  作者：Masashi Mamada、César Pérez-Bolívar、Pavel Anzenbacher

  DOI：10.1021/ol201973w

  日期：2011.9.16

  Polycyclic benzimidazole derivatives, an important class of compounds in organic electronics and photovoltaics, were prepared using a solvent-free “green” process based on heating carboxylic acid anhydrides and arylene diamines in the presence of zinc acetate in the solid state. Products were isolated and purified directly by train sublimation of the crude reaction mixtures. The reaction conditions

  多环苯并咪唑衍生物是有机电子产品和光伏产品中的一类重要化合物，是使用无溶剂的“绿色”工艺制备的，该工艺基于在固态乙酸锌存在下加热羧酸酐和亚芳基二胺的方法。产物的分离和纯化是通过将粗反应混合物直接升华进行的。使用各种羧酸酐优化反应条件。还描述了这些材料的光学和电化学性质。
• Benzimidazole-Substituted Polybezimidazoles as Initial Material For Producing Proton-Conducting Membranes
  申请人：Likhachev Dmitry Yurevich

  公开号：US20080171798A1

  公开（公告）日：2008-07-17

  The invention relates to application of benzimidazole-substituted polybenizimidazole polymers as initial material for preparing proton-conductive membranes, preferably used in high-temperature fuel cells. Detail methods are provided, comprising the steps of obtaining the polymers, preparing film containing the polymer, doping the film with predetermined acid, thereby forming a proton-conductive membrane with improved proton conductivity. Particularly, a group consisting of three types of the polymers is described. In a preferred embodiment, the predetermined acid is being phosphoric acid.
• KORSHAK V. V.; BERESTNEVA G. L.; DOROSHENKO YU. E.; POSTNIKOVA L. V.; XOM+, IZV. AN CCCP. CEP. XIM., 1978, HO 2, 422-426
  作者：KORSHAK V. V.、 BERESTNEVA G. L.、 DOROSHENKO YU. E.、 POSTNIKOVA L. V.、 XOM+

  DOI：——

  日期：——