Di(propan-2-yl)phosphanylphosphanyl-di(propan-2-yl)phosphane | 158093-09-5

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Di(propan-2-yl)phosphanylphosphanyl-di(propan-2-yl)phosphane
• 英文别名: di(propan-2-yl)phosphanylphosphanyl-di(propan-2-yl)phosphane
• CAS: 158093-09-5
• 化学式: C₁₂H₂₉P₃
• 分子量: 266.284
• InChiKey: JSYSTNFPMPDATC-UHFFFAOYSA-N

物化性质

• 沸点：
  309.5±25.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  二氯二茂铪 、 i-Pr₂P-P(SiMe₃)Li*3THF 以 四氢呋喃 为溶剂， 以0.028 g的产率得到
  参考文献：
  名称：

  Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes

  摘要：

  The reactions of R2P-P(SiMe3)Li (R = (t)3u, Pr-i, (Pr2N)-Pr-i) with [Cp2MCl2] (M = Zr, Hf), [Cp*CpaCl(2)] and [CpZrCl3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R2P-P(SiMe3)Li can act as a building block for the formation of the P-2 ligand and the R2P-P(P-2) and R2P-P(P-2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P-P-2(P-2) and R2P-P(P-2)P-PR2 ligands were established by X-ray studies. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.02.046

文献信息

• Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes
  作者：Aleksandra Wiśniewska、Agnieszka Łapczuk-Krygier、Katarzyna Baranowska、Jarosław Chojnacki、Eberhard Matern、Jerzy Pikies、Rafał Grubba

  DOI：10.1016/j.poly.2013.02.046

  日期：2013.5

  The reactions of R2P-P(SiMe3)Li (R = (t)3u, Pr-i, (Pr2N)-Pr-i) with [Cp2MCl2] (M = Zr, Hf), [Cp*CpaCl(2)] and [CpZrCl3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R2P-P(SiMe3)Li can act as a building block for the formation of the P-2 ligand and the R2P-P(P-2) and R2P-P(P-2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P-P-2(P-2) and R2P-P(P-2)P-PR2 ligands were established by X-ray studies. (C) 2013 Elsevier Ltd. All rights reserved.