2-methacryloxyethylphosphonic acid mono(methacryloxyethyl)ester | 1236199-37-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: 2-methacryloxyethylphosphonic acid mono(methacryloxyethyl)ester
• 英文别名: 2-methacryloxyethylphosphonic mono(methacryloxyethyl) ester；2-(2-Methylprop-2-enoyloxy)ethoxy-[2-(2-methylprop-2-enoyloxy)ethyl]phosphinic acid；2-(2-methylprop-2-enoyloxy)ethoxy-[2-(2-methylprop-2-enoyloxy)ethyl]phosphinic acid
• CAS: 1236199-37-3
• 化学式: C₁₂H₁₉O₇P
• 分子量: 306.252
• InChiKey: NUAQRSNFCMTJLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  双(2-氯乙基)-(2-氯乙基)膦酸酯 、 potassium methacrylate 在 对苯二酚 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 2-methacryloxyethylphosphonic acid mono(methacryloxyethyl)ester 、 ((vinylphosphoryl)bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) 、 (((2-(methacryloyloxy)ethyl)phosphoryl)bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
  参考文献：
  名称：

  Reaction of di-2-chloroethyl 2-chloroethanephosphonate with potassium methacrylate

  摘要：

  Reaction of di-2-chloroethyl 2-chloroethanephosphonate with potassium methacrylate at various component ratios was studied with the aim to prepare products containing methacrylate and vinyl functional groups. The structures of the compounds obtained were examined by (1)H NMR and IR spectroscopy and by gas chromatography-mass spectrometry.

  DOI：

  10.1134/s1070427210040300

文献信息

• Radiation curable powder coating compositions
  申请人：CYTEC SURFACE SPECIALTIES, S.A.

  公开号：EP1645583A1

  公开（公告）日：2006-04-12

  The present invention relates to powder compositions curable by ultraviolet irradiation or by accelerated electron beams. These powder compositions comprise at least one ethylenically unsaturated resin, and lend to the production of paint and varnish coatings exhibiting a unique combination of properties, inter alia good flow and mechanical properties and above all outstanding adhesion to metal substrates, persisting on ageing.

  本发明涉及可通过紫外线照射或加速电子束固化的粉末组合物。这些粉末组合物包含至少一种乙烯不饱和树脂，可用于生产油漆和清漆涂料，具有独特的综合性能，特别是良好的流动性和机械性能，尤其是对金属基材具有出色的附着力，老化后仍能保持。
• ADHESIVE COMPOSITION FOR DENTAL USE
  申请人：Tokuyama Dental Corporation

  公开号：EP2123246A1

  公开（公告）日：2009-11-25

  An adhesive composition for dental use exhibiting acidic property, including a mixture of a polymerizable monomer component (A) containing a phosphoric acid-type polymerizable monomer having an acidic group derived from phosphoric acid, and a multivalent metal ion-releasing component (B), wherein the multivalent metal ion-releasing component (B) is capable of releasing at least earth metal ions, and in the composition, earth metal ions stemming from the component (B) are present together with the phosphoric acid-type polymerizable monomer in such an amount that a total valency ratio (RE) defined by the following formula (1) is in a range of 0.2 to 3.0. The adhesive composition is capable of strongly adhering and fixing a composite resin or a prosthetic material to a tooth for extended periods of time maintaining stability. RE=TVE/TVA wherein TVE is a total valency of the earth metal ions contained in said composition, and TVA is a total valency of the acidic groups of the phosphoric acid-type polymerizable monomer contained in said composition.

  一种具有酸性的牙科用粘合剂组合物，包括含有磷酸型可聚合单体的可聚合单体组分（A）和多价金属离子释放组分（B）的混合物、其中，多价金属离子释放组分（B）至少能释放出土金属离子，在组合物中，由组分（B）产生的土金属离子与磷酸型可聚合单体一起存在，其含量为下式（1）定义的总价比（RE）在 0.2 至 3.0。该粘合剂组合物能够长时间将复合树脂或修复材料牢固地粘附和固定在牙齿上，并保持稳定。RE=TVE/TVA 其中 TVE 为所述组合物中所含土金属离子的总价，而 TVA 是所述组合物所含磷酸型可聚合单体的酸性基团的总价。
• RADIATION CURABLE POWDER COATING COMPOSITIONS
  申请人：CYTEC SURFACE SPECIALTIES, S.A.

  公开号：EP1799741B1

  公开（公告）日：2012-08-15
• JPH11171936A
  申请人：——

  公开号：JPH11171936A

  公开（公告）日：1999-06-29
• Radiation Curable Powder Coating Compositions
  申请人：Moens Luc

  公开号：US20080206480A1

  公开（公告）日：2008-08-28

  The present invention relates to powder compositions curable by ultraviolet irradiation or by accelerated electron beams. These powder compositions comprise at least one ethylenically unsaturated resin, and lend to the production of paint and varnish coatings exhibiting a unique combination of properties, inter alia good flow and mechanical properties and above all outstanding adhesion to metal substrates, persisting on ageing.