1-methylbenzo[h]isoquinoline | 110054-58-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 1-methylbenzo[h]isoquinoline
• 英文别名: 1-Methyl-7.8-benzisochinolin；Methyl-benzoisoquinoline
• CAS: 110054-58-5
• 化学式: C₁₄H₁₁N
• 分子量: 193.248
• InChiKey: NFGSOGBQNAGIKC-UHFFFAOYSA-N

物化性质

• 熔点：
  95-96 °C
• 沸点：
  367.8±11.0 °C(Predicted)
• 密度：
  1.155±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙酸乙烯酯 、 1-(naphthalen-1-yl)ethanone O-acetyl oxime 在 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 cesium acetate 作用下， 以 甲醇 为溶剂， 反应 48.0h， 以24%的产率得到1-methylbenzo[h]isoquinoline
  参考文献：
  名称：

  使用乙酸乙烯酯作为乙炔当量通过CH活化/环化合成异喹啉

  摘要：

  乙酸乙烯酯用作铑（III）催化的芳基酮肟酯的CH活化/环化反应中的乙炔当量。延伸至醛肟肟酯可实现简明苯二酚B的简明形式合成。

  DOI：

  10.1016/j.tet.2018.05.063

文献信息

• Organometallic Complex, Luminescent Solid, Organic el Element and Organic el Display
  申请人：Sotoyama Wataru

  公开号：US20070224447A1

  公开（公告）日：2007-09-27

  The present invention aims to provide organic EL elements etc., containing phosphorescent organometallic complexes, that can exhibit longer durability, higher emitting efficiency, superior thermal/electrical stability, significantly longer operating life. The organic EL elements comprise an organic thin layer interposed between a positive hole transport layer and a electron transport layer, the organic thin layer comprises an organometallic complex comprising at least a metal element, a tridentate ligand, and a monodentate ligand, wherein the tridentate ligand bonds with the metal atom through two nitrogen atoms and one carbon atom, and the carbon atom exists between the two nitrogen atoms, and a monodentate ligand bonds with the metal atom through a atom selected from the group consisting of C, N, O, P and S atoms.

  本发明旨在提供含有磷光有机金属配合物的有机EL元件等，其能够展现更长的耐久性、更高的发光效率、优越的热/电稳定性以及显著更长的使用寿命。有机EL元件包括位于正空穴传输层和电子传输层之间的有机薄层，该有机薄层包括至少一种金属元素、一个三齿配体和一个单齿配体的有机金属配合物，其中三齿配体通过两个氮原子和一个碳原子与金属原子结合，碳原子存在于两个氮原子之间，而单齿配体通过来自由C、N、O、P和S原子组成的原子与金属原子结合。
• HETEROCYCLIC COMPOUND FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ITS APPLICATION
  申请人：TOSOH CORPORATION

  公开号：US20160056388A1

  公开（公告）日：2016-02-25

  A novel heterocyclic compound for an organic electroluminescent device excellent in long service life and light-emitting characteristics is provided. A cyclic azine compound has at least one substituent (substituent B) selected from a specific group.

  提供一种新的杂环化合物，用于有机电致发光器件，具有长寿命和发光特性优异。该环状腈化合物至少具有来自特定群组的一个取代基（取代基B）。
• Metal Complex, Luminescent Solid, Organic El Element and Organic El Display
  申请人：Sotoyama Wataru

  公开号：US20070296329A1

  公开（公告）日：2007-12-27

  The present invention aims to provide metal complexes, suited to luminescent materials or color transfer materials in organic EL elements or lighting systems. The metal complexes according to the present invention comprise a metal atom, a tridentate ligand, and one of monodentate ligands and halogen atoms, wherein the tridentate ligand binds to the metal atom at three sites through three nitrogen atoms of a first nitrogen atom, a second nitrogen atom and a third nitrogen atom, and the one of monodentate ligands and halogen atoms binds to the metal atom. The metal complexes are preferably expressed by General Formula (1) shown below.
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND ELECTRONIC APPARATUS INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20200308205A1

  公开（公告）日：2020-10-01

  Provided are an organometallic compound represented by Formula 1, an organic light-emitting device including the same, and an electronic apparatus including the organic light-emitting device: wherein, in Formula 1, Y 2 , ring CY 1 , ring CY 2 , T 1 , T 2 , A 1 to A 7 , a1, and a2 are as defined in the specification.
• US9780310B2
  申请人：——

  公开号：US9780310B2

  公开（公告）日：2017-10-03