1,2-epoxy-bicyclohexyl | 7583-76-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 1,2-epoxy-bicyclohexyl
• 英文别名: 1-Cyclohexyl-1,2-epoxy-cyclohexan；1-Cyclohexyl-7-oxabicyclo[4.1.0]heptane
• CAS: 7583-76-8
• 化学式: C₁₂H₂₀O
• 分子量: 180.29
• InChiKey: FOLUGZFOOWTZBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,2-epoxy-bicyclohexyl 、 硫酸 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Boeeseken, Chemische Berichte, 1923, vol. 56, p. 2410

  摘要：

  DOI：

文献信息

• Composition and method for corrosion inhibition
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0176991A1

  公开（公告）日：1986-04-09

  A corrosion-inhibiting composition and method of inhibiting corrosion on metal surfaces are described. The composition comprises a reaction product of (a) a first '6onstituent selected from an epoxide having an average of at least about one vicinal epoxide per molecule and a halogenated aliphatic compound having at least one displaceable halogen and (b) a second constituent comprising a dimercaptan. The reaction product in a hydrocarbon diluent is an effective corrosion inhibitor when applied to metal surfaces in highly corrosive environments, and is designed particularly for downhole metal surfaces of oil drilling_ equipment.

  描述了一种缓蚀组合物和抑制金属表面腐蚀的方法。该组合物包括以下两种成分的反应产物：(a) 第一种'6-取代基，选自平均每个分子至少有一个左右邻位环氧化物的环氧化物和至少有一个可置换卤素的卤代脂肪族化合物；(b) 第二种成分，包括二硫醇。在烃稀释剂中的反应产物是一种有效的腐蚀抑制剂，可用于高腐蚀性环境中的金属表面，尤其适用于石油钻探设备的井下金属表面。
• HIGH-PURITY ALICYCLIC DIEPOXY COMPOUND AND PROCESS FOR PRODUCING THE SAME
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1834949A1

  公开（公告）日：2007-09-19

  A high-purity cycloaliphatic diepoxy compound of General Formula (II) is an epoxidized product of a cycloaliphatic diolefinic compound of General Formula (I) having an isomer content as detected in gas chromatography (GC) of 15% or less: wherein X represents a bivalent group selected from the group consisting of, for example, O, S, -SO-, -SO2-, -CH2-, and -C(CH3)2-; and R1 to R18 may be the same as or different from each other and each represent hydrogen atom, a halogen atom, a hydrocarbon group which may contain oxygen atom or a halogen atom, or an alkoxy group which may be substituted. Such a high-purity cycloaliphatic diepoxy compound is prepared by producing the cycloaliphatic diolefinic compound through distillation, epoxidizing the compound with an aliphatic percarboxylic acid containing substantially no water, carrying out desolvation, and further purifying the epoxidized compound through distillation.

  通式（II）的高纯度环脂族二环氧化合物是通式（I）的环脂族二烯烃化合物的环氧化产物，其气相色谱法（GC）检测到的异构体含量不超过 15%： 其中 X 代表选自例如 O、S、-SO-、-SO2-、-CH2- 和-C(CH3)2- 所组成的组的二价基团；R1 至 R18 可以彼此相同或不同，并且各自代表氢原子、卤素原子、可能含有氧原子或卤素原子的烃基或可能被取代的烷氧基。这种高纯度环脂族二环氧化合物的制备方法是：通过蒸馏生产环脂族二烯烃化合物，用基本上不含水的脂肪族过羧酸环氧化该化合物，进行脱溶剂，并通过蒸馏进一步纯化环氧化化合物。
• High-Purity Cycloaliphatic Diepoxy Compound and Preparation Process Thereof
  申请人：Takai Hideyuki

  公开号：US20080045729A1

  公开（公告）日：2008-02-21

  A high-purity cycloaliphatic diepoxy compound of General Formula (II) is an epoxidized product of a cycloaliphatic diolefinic compound of General Formula (I) having an isomer content as detected in gas chromatography (GC) of 15% or less: wherein X represents a bivalent group selected from the group consisting of, for example, O, S, —SO—, —SO 2 —, —CH 2 —, and —C(CH 3 ) 2 —; and R 1 to R 18 may be the same as or different from each other and each represent hydrogen atom, a halogen atom, a hydrocarbon group which may contain oxygen atom or a halogen atom, or an alkoxy group which may be substituted. Such a high-purity cycloaliphatic diepoxy compound is prepared by producing the cycloaliphatic diolefinic compound through distillation, epoxidizing the compound with an aliphatic percarboxylic acid containing substantially no water, carrying out desolvation, and further purifying the epoxidized compound through distillation.
• US4650594A
  申请人：——

  公开号：US4650594A

  公开（公告）日：1987-03-17
• US4664193A
  申请人：——

  公开号：US4664193A

  公开（公告）日：1987-05-12