(3-dimethylamino-propyl)-propyl-carbodiimide | 639517-64-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (3-dimethylamino-propyl)-propyl-carbodiimide
• 英文别名: (3-Dimethylamino-propyl)-propyl-carbodiimid
• CAS: 639517-64-9
• 化学式: C₉H₁₉N₃
• 分子量: 169.27
• InChiKey: QRIAHZBQBDMKGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  28
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (3-dimethylamino-propyl)-propyl-carbodiimide 、 碘甲烷 在 乙酸乙酯 作用下， 生成 1-Propanaminium, N,N,N-trimethyl-3-[(propylcarbonimidoyl)amino]-,iodide
  参考文献：
  名称：

  Schmidt; Striewsky, Chemische Berichte, 1941, vol. 74, p. 1288 Anm.10

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 mercury(II) oxide 、 苯 作用下， 生成 (3-dimethylamino-propyl)-propyl-carbodiimide
  参考文献：
  名称：

  Schmidt; Striewsky, Chemische Berichte, 1941, vol. 74, p. 1288 Anm.10

  摘要：

  DOI：

文献信息

• Domino condensation/aza-Michael/O→N acyl migration of carbodiimides with activated α,β-unsaturated carboxylic acids to form hydantoins
  作者：Alessandro Volonterio、Matteo Zanda

  DOI：10.1016/j.tetlet.2003.09.134

  日期：2003.11

  Activated α,β-unsaturated carboxylic acids undergo an unexpected domino condensation/aza-Michael/O→N acyl migration with carbodiimides, producing N,N-disubstituted hydantoins in good yields. An array of structurally varied aspartic acid-derived hydantoins, including some fluorinated derivatives, have been synthesized by this method, whose scope and limits are discussed.

  活化的α，β-不饱和羧酸与碳二亚胺发生意想不到的多米诺骨牌缩合/氮杂-迈克尔/ O→N酰基迁移，以高收率生产N，N-二取代的乙内酰脲。通过该方法合成了一系列结构变化的天冬氨酸衍生的乙内酰脲，包括一些氟化衍生物，并讨论了其范围和限制。
• Esters and amides of substituted indenyl acetic acids
  申请人：FGN, INC.

  公开号：EP0485172A2

  公开（公告）日：1992-05-13

  Esters and amides of substituted indenyl acetic acids of the formula : n is an integer of at least 2 ; Q is a deprotonated residue of polymer or macromolecular structure having a molecular weight of at least about 1000 containing at least two primary and/or secondary amino groups and/or hydroxy groups ; R1 is selected from hydrogen, lower alkyl, or haloalkyl ; R2 is selected from hydrogen or alkyl ; R3 and R4 are one or more members each independently chosen from hydrogen, alkyl, acyloxy, alkoxy, nitro, amino, acylamino, alkylamino, diakylamino, dialkylaminoalkyl, sulfamyl, alkythio, mercapto, hydroxy, hydroxyalkyl, alkylsulfonyl, halogen, cyano, carboxyl, carbalkoxy, carbamido, haloalkyl or cycloalkoxy ; and R5 is selected from alkylsulfenyl, alkylsulfinyl or alkylsulfonyl. are useful in the treatment of colonic polyps.

  式中的取代茚基乙酸的酯和酰胺： n 至少为 2 的整数； Q 是聚合物或大分子结构的去质子化残基，分子量至少约为 1000，含有至少两个伯氨基和/或仲氨基和/或羟基； R1 选自氢、低级烷基或卤代烷基； R2 选自氢或烷基； R3 和 R4 是各自独立选自氢、烷基、酰氧基、烷氧基、硝基、氨基、酰氨基、烷基氨基、二烷基氨基、二烷基氨基烷基、氨基磺酰基、烷硫基、巯基、羟基、羟烷基、烷基磺酰基、卤素、氰基、羧基、羰基烷氧基、氨基甲酰基、卤代烷基或环烷氧基的一个或多个成员；和 R5 选自烷基亚磺酰基、烷基亚磺酰基或烷基磺酰基。
• Solar cell protective sheet and its production method, backsheet for solar cell, and solar cell module
  申请人：Fujifilm Corporation

  公开号：EP2450397A1

  公开（公告）日：2012-05-09

  A solar cell protective sheet comprising a polymer substrate and a polymer layer, which satisfies at least one of the following conditions [1] and [2]: [1] the polymer substrate is a surface-treated polymer substrate, and the polymer layer has a thickness of from 0.8 molecule: wherein R1 and R2 represent hydrogen, halogen or monovalent organic group; n indicates 1 or more; and [2] the sheet contains a first polymer layer containing an ultraviolet absorbent and a binder polymer on the polymer substrate, and a second polymer layer containing a binder polymer, in which the content of the ultraviolet absorbent is at most 1.0% by mass relative to the total amount of the binder.

  一种太阳能电池保护片，包括聚合物基底和聚合物层，至少满足以下条件之一[1]和[2]： [1]聚合物基底是表面处理过的聚合物基底，聚合物层的厚度为 0.8 摩尔： 其中 R1 和 R2 代表氢、卤素或一价有机基团；n 表示 1 或更多；以及 [2]片材在聚合物基材上包含含有紫外线吸收剂和粘结剂聚合物的第一聚合物层，以及含有粘结剂聚合物的第二聚合物层，其中紫外线吸收剂的含量相对于粘结剂的总量最多为 1.0%（质量百分比）。
• BACK SHEET FOR SOLAR CELLS AND PROCESS FOR PRODUCTION THEREOF, AND SOLAR CELL MODULE
  申请人：FUJIFILM Corporation

  公开号：EP2639836A1

  公开（公告）日：2013-09-18

  A solar cell backsheet including: a support which has a thickness of 120 µm to 350 µm; a first polymer layer which is formed on one surface of the support by coating, which includes a polymer, and which has a thickness of 0.5 µm to 12.0 µm: and a second polymer layer which is formed, by coating, on the opposite side of the side of the support provided with the first polymer layer, which includes a fluorinated resin or a silicone-based resin, and which has a thickness of 0.2 µm to 15.0

  一种太阳能电池背板，包括：厚度为 120 微米至 350 微米的支架；通过涂层在支架的一个表面形成的第一聚合物层，该层包括聚合物，厚度为 0.5 微米至 12.0 微米：以及通过涂层在支架上提供第一聚合物层的一侧的另一侧形成的第二聚合物层，该层包括氟化树脂或硅基树脂，厚度为 0.2 微米至 15.0 微米。
• SOLAR CELL PROTECTIVE SHEET AND ITS PRODUCTION METHOD, BACKSHEET FOR SOLAR CELL, AND SOLAR CELL MODULE
  申请人：ARITOSHI Yohei

  公开号：US20120048348A1

  公开（公告）日：2012-03-01

  A solar cell protective sheet comprising a polymer substrate and a polymer layer, which satisfies at least one of the following conditions [1] and [2]: [1] the polymer substrate is a surface-treated polymer substrate, and the polymer layer has a thickness of from 0.8 μm to 12 μm and contains a composite polymer containing a polysiloxane structural unit represented by the following formula (1) and a non-polysiloxane structural unit in the molecule: wherein R 1 and R 2 represent hydrogen, halogen or monovalent organic group; n indicates 1 or more; and [2] the sheet contains a first polymer layer containing an ultraviolet absorbent and a binder polymer on the polymer substrate, and a second polymer layer containing a binder polymer, in which the content of the ultraviolet absorbent is at most 1.0% by mass relative to the total amount of the binder.