4-(7-oxo-7H-benz[de]anthracen-3-yl)-naphthalene-1,8-dicarboxylic acid-anhydride | 189440-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-(7-oxo-7H-benz[de]anthracen-3-yl)-naphthalene-1,8-dicarboxylic acid-anhydride
• 英文别名: 4-(7-Oxo-7H-benz[de]anthracen-3-yl)-naphthalin-1,8-dicarbonsaeure-anhydrid；8-(7-Oxobenzo[a]phenalen-3-yl)-3-oxatricyclo[7.3.1.05,13]trideca-1(12),5(13),6,8,10-pentaene-2,4-dione
• CAS: 189440-67-3
• 化学式: C₂₉H₁₄O₄
• 分子量: 426.428
• InChiKey: OASKPLMYKZKIBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  33
• 可旋转键数：
  1
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  60.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  辛胺 、 4-(7-oxo-7H-benz[de]anthracen-3-yl)-naphthalene-1,8-dicarboxylic acid-anhydride 以 异丙醇 为溶剂， 反应 6.0h， 以79%的产率得到2-Octyl-6-(7-oxo-7H-benzo[de]anthracen-3-yl)-benzo[de]isoquinoline-1,3-dione
  参考文献：
  名称：

  Benzoylperylenedicarboximides: Functional dyes with attractive optical and electronic properties

  摘要：

  Little is known about benzoylperleneimides 3. Two new syntheses of 3 have been worked out. based on boronic acid and organotin intermediates. respectively. These mild methods allow the isolation of the uncyclized precursor 10 and the introduction of various groups R. The purple benzoylperyleneimides 3 are fluorescent dyes and exhibit a high thermal and photochemical stability. The electrochemical properties have been investigated showing that 3 can take up 2 electrons while 10 accepts 4 electrons due to the existence of two weakly interacting anyl units. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00381-5
• 作为产物：
  描述：

  在 氢氧化钾 、 硫酸 、 氧气 作用下， 以 丙醇 、 水 为溶剂， 反应 100.0h， 生成 4-(7-oxo-7H-benz[de]anthracen-3-yl)-naphthalene-1,8-dicarboxylic acid-anhydride
  参考文献：
  名称：

  Benzoylperylenedicarboximides: Functional dyes with attractive optical and electronic properties

  摘要：

  Little is known about benzoylperleneimides 3. Two new syntheses of 3 have been worked out. based on boronic acid and organotin intermediates. respectively. These mild methods allow the isolation of the uncyclized precursor 10 and the introduction of various groups R. The purple benzoylperyleneimides 3 are fluorescent dyes and exhibit a high thermal and photochemical stability. The electrochemical properties have been investigated showing that 3 can take up 2 electrons while 10 accepts 4 electrons due to the existence of two weakly interacting anyl units. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00381-5

文献信息

• DE638602
  申请人：——

  公开号：——

  公开（公告）日：——
• Benzoylperylenedicarboximides: Functional dyes with attractive optical and electronic properties
  作者：Frank O. Holtrup、Gert R.J. Müller、Jochen Uebe、Klaus Müllen

  DOI：10.1016/s0040-4020(97)00381-5

  日期：1997.5

  Little is known about benzoylperleneimides 3. Two new syntheses of 3 have been worked out. based on boronic acid and organotin intermediates. respectively. These mild methods allow the isolation of the uncyclized precursor 10 and the introduction of various groups R. The purple benzoylperyleneimides 3 are fluorescent dyes and exhibit a high thermal and photochemical stability. The electrochemical properties have been investigated showing that 3 can take up 2 electrons while 10 accepts 4 electrons due to the existence of two weakly interacting anyl units. (C) 1997 Elsevier Science Ltd.