3,3'-Dimethyl-2,3,2',3'-tetrahydro-[2,2']bibenzothiazolyl | 124855-91-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 3,3'-Dimethyl-2,3,2',3'-tetrahydro-[2,2']bibenzothiazolyl
• 英文别名: 3-methyl-2-(3-methyl-2H-1,3-benzothiazol-2-yl)-2H-1,3-benzothiazole
• CAS: 124855-91-0
• 化学式: C₁₆H₁₆N₂S₂
• 分子量: 300.448
• InChiKey: HYUVMMBOEOCDFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,3'-Dimethyl-2,3,2',3'-tetrahydro-[2,2']bibenzothiazolyl 以 环己烷 为溶剂， 反应 144.0h， 以8.4%的产率得到5a,6,11a,12-Tetrahydro-6,12-dimethyl<1,4>benzothiazino<3,2-b><1,4>benzothiazine
  参考文献：
  名称：

  Tauer, Erich; Grellmann, Karl-Heinz, Chemische Berichte, 1990, vol. 123, # 5, p. 1149 - 1154

  摘要：

  DOI：
• 作为产物：
  描述：

  3-甲基-2(3H)-苯并噻唑酮 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以20%的产率得到3,3'-Dimethyl-2,3,2',3'-tetrahydro-[2,2']bibenzothiazolyl
  参考文献：
  名称：

  Tauer, Erich; Grellmann, Karl-Heinz, Chemische Berichte, 1990, vol. 123, # 5, p. 1149 - 1154

  摘要：

  DOI：

文献信息

• Reactions of Electron-Rich Olefins with Proton-Active Compounds
  作者：Hasan Küçükbay、Engin Çetinkaya、Bekir Çetinkaya、Michael F. Lappert

  DOI：10.1080/00397919708005451

  日期：1997.12

  Abstract: From the reaction of electron-rich olefins, bis(1,3-dimethylbenzimidazolidine-2-ylidene), I, or bis(3-methylbenzothiazolidine-2-ylidene), II with proton active compounds, such as dimethyl phosphite, diethyl phosphite, acetonitrile and benzaldehyde were obtained 2-substituted benzimidazole or benzothiazole derivatives. The compounds synthesized were identified by 1H, 13 C, 31P-NMR, mass, FT-IR

  摘要：由富电子烯烃双(1,3-二甲基苯并咪唑烷-2-ylidene), I 或双(3-甲基苯并噻唑烷-2-ylidene), II 与质子活性化合物如亚磷酸二甲酯、二乙基亚磷酸酯、乙腈和苯甲醛分别得到2-取代苯并咪唑或苯并噻唑衍生物。合成的化合物通过1H、13C、31P-NMR、质谱、FT-IR光谱技术和微量分析进行鉴定。
• Kucukbay; Cetinkaya; Durmaz, Arzneimittel-Forschung/Drug Research, 1995, vol. 45, # 12, p. 1331 - 1334
  作者：Kucukbay、Cetinkaya、Durmaz

  DOI：——

  日期：——
• US9671392B2
  申请人：——

  公开号：US9671392B2

  公开（公告）日：2017-06-06
• [EN] MULTISENSOR ARRAY FOR DETECTION OF ANALYTES OR MIXTURES THEREOF IN GAS OR LIQUID PHASE<br/>[FR] RÉSEAU MULTICAPTEUR POUR LA DÉTECTION D'ANALYTES OU DE MÉLANGES DE CEUX-CI EN PHASE GAZEUSE OU LIQUIDE
  申请人：UNIV DANMARKS TEKNISKE

  公开号：WO2011121077A1

  公开（公告）日：2011-10-06

  The present invention relates to a multisensor array for detection of analytes in the gas phase or in the liquid phase, comprising at least two different chemo-selective compounds represented by the general formula (I) wherein the hetero atoms X1-X4 and the substituents R1-R4 are defined in the specification and the dashed bonds represent independently of each other either a single bond or a double bond. Said chemo-selective compounds are capable of individually changing physicochemical properties when exposed to analytes or analyte mixtures and these changes can be detected by a transducer or an array of transducers. The present invention does also relate to the use of at least two different chemo-selective compounds in a sensor array, a method for preparation of such sensor arrays and the use of said sensor arrays. Furthermore the present invention relates to methods for detecting and identifying analytes or mixtures thereof in the gas phase or in the liquid phase.